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Positive relation

The diEFerent activation and deactivation influences are seen in 4,5-bromo-2-phenylpyridazin-3-one (209) which reacts with methoxide, hydrazine, or secondary amines at the 6-position. Related N—H and iV -alkyl halopyridazinones behave similarly. [Pg.249]

Halopyridines undergo self-quaternization on standing while the less reactive 2-halo isomers do not. However, more is involved here than the relative reactivity at the ring-positions. The reaction rate will depend on the relative riucleophilicity of the attack-ing pyridine-nitrogens (4-chloropyridine is more basic) and on the much lower steric hindrance at the 4-position. Related to this self-quatemization are the reactions of pyridine and picolines as nucleophiles with 4-chloro- and 2-chloro-3-nitropyridines. The 4-isomer (289) is. again the more reactive by 10-30-fold (Table VII, p. 276). [Pg.287]

What was the initial y-position of the a-particle How is this position related to the y-direction distance between the a-particle and the nucleus ... [Pg.27]

The mathematical-statistical methods reviewed here have proven to be powerful tools for the extraction of the most relevant information on the separation sample complexity, separation performance, overlapping extent, and identification of ordered patterns present in spot positions related to chemical composition of the complex sample. [Pg.88]

Spirooxyphosphoranes 166 were obtained by the cyclodehydration of ortho-carboxyarylmethyl phosphine oxides under acidic conditions (Equation 15) to give 166 (X = Y = 0) in which the oxygens occupy the axial positions. Related spirocyclic azoxyphosphoranes 166 (X = NH, NMe) were synthesized from amidoarylmethyl phosphine oxides and trifluoracetic acid <1996PS241>. [Pg.1095]

Finally, a third route considers the possibility of removing the steric hindrance prior to desulfurization by including an acid (isomerizing/dealkylating) function on the catalyst so that the bulky substituents can be moved to a different, less harmless, position related to the S atom site. [Pg.32]

James M. Meyer retired in 2001 as Vice President of DuPont Central Research and Development. He joined DuPont in 1969 and held a variety of research and management positions related to elastomers and polymers. He moved to Central Research and Development in 1992 as director of materials science and engineering, and he assumed his current position in 1996. Dr. Meyer received his B.S. degree in chemistry from Indiana University and his Ph.D. degree in inorganic chemistry from Northwestern University. [Pg.199]

Juveniles fed diets containing 16 PCBs for 30 days individual PCBs had high accumulation potential and high persistence in tissues Fathead minnow, Pimephales promeias] fry Half-time persistence of individual PCBs ranged between 24 and 224 days. Increasing persistence was positively related to increasing Log < , in the range 5-8, with a peak at 7 19... [Pg.1305]

Salt marsh, New Positive relation Soil extractable P (acetic Theodose... [Pg.156]

And since high uric acid levels were associated with migraine as well, there appeared to be a positive relation between acid in the blood and blood pressure. Finally, Haig had already observed that test tube solutions of urates could be chemically manipulated to form gelatinous colloids, and supposed it was "quite possible" a like phenomenon might occur in the blood. [Pg.161]

Begin by drawing and labelling the axes as shown. Draw a vertical line from 1 on the x axis. This is the line of no effect. The results of the individual trials are shown as boxes with the size of the box relating to the size of the trial and its position relating to the result of the trial. The lines are usually the 95% confidence intervals. The combined result is shown at the bottom of all the trials as a diamond, the size of which represents the combined numbers from all the trials. The result can be considered statistically significant if the confidence intervals of the combined result do not cross the line of no effect. [Pg.221]

Such recent developments show how science can also positively relate to ethics, thanks to green chemistry. Green chemistry represents a strategic challenge for the present and the future of the chemical industry, its development being... [Pg.328]

The repetitive cycle to identify a sequence of N-terminal amino acids has been automated. In practice, it is limited to about 20-30 amino acids, since impurities build up and the reaction mixture becomes too complex to yield unequivocal results. The usual approach is to break the polypeptide chain into smaller fragments by partial hydrolysis, preferably at positions relating to specific amino acid residues in the peptide chain. There are ways of doing this chemically, and the enzymes chymotrypsin... [Pg.546]

Intake may be negatively correlated with residues due to repellency or avoidance positive relation between insect abundance and decision to use insecticide negative relation between use of insecticide and subsequent insect abundance positive relation between insect abundance and bird foraging behavior... [Pg.22]

Perfectly positive relation (maximal correlation) Opposite relation (minimal correlation)... [Pg.102]

Barger-Lux, M., and Heaney, R. P. (2005). Calcium absorptive efficiency is positively related to body size. J. Clin. Endocrinol. Metab. 90,5118-5120. [Pg.330]

One reason is that firms who want to employ the new technology cannot merely invest in basic research. Cockburn and Henderson (1998) emphasize that it is also important for the firm to be actively connected to the wider scientific community (p. 158). They developed the concept of connectedness, as measured by the extent of collaboration in writing scientific papers across institutional boundaries, and conclude that firms wishing to public sector research must do more than simply invest in in-house basic research they must also actively collaborate with their public sector colleagues. The extent of this collaboration... is positively related to private sector research productivity (p. 180). The process by which firms acquire this new technology is not simple or direct, nor obtained without cost. [Pg.56]

For convective crystal dissolution, the dissolution rate is u = (p/p )bD/8. For diffusive crystal dissolution, the dissolution rate is u = diffusive boundary layer thickness as 5 = (Df), the diffusive crystal dissolution rate can be written as u = aD/5, where a is positively related to b through Equation 4-100. Therefore, mass-transfer-controlled crystal dissolution rates (and crystal growth rates, discussed below) are controlled by three parameters the diffusion coefficient D, the boundary layer thickness 5, and the compositional parameter b. The variation and magnitude of these parameters are summarized below. [Pg.403]


See other pages where Positive relation is mentioned: [Pg.823]    [Pg.401]    [Pg.79]    [Pg.353]    [Pg.97]    [Pg.651]    [Pg.84]    [Pg.37]    [Pg.39]    [Pg.167]    [Pg.241]    [Pg.244]    [Pg.656]    [Pg.808]    [Pg.839]    [Pg.1284]    [Pg.1360]    [Pg.1586]    [Pg.1661]    [Pg.576]    [Pg.241]    [Pg.162]    [Pg.343]    [Pg.58]    [Pg.66]    [Pg.46]    [Pg.212]    [Pg.10]    [Pg.58]    [Pg.79]    [Pg.141]    [Pg.146]    [Pg.160]   
See also in sourсe #XX -- [ Pg.38 ]




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