Marine pore water

Nipper M, Carr RS, Biedenbach JM, Hooten RL, and Miller K (2002) Toxicological and chemical assessment of ordinance compounds in marine sediments and pore-waters. Marine Pollution Bulletin 44 789-806. 

This removal may also include diffusion of soluble U(VI) from seawater into the sediment via pore water. Uranium-organic matter complexes are also prevalent in the marine environment. Organically bound uranium was found to make up to 20% of the dissolved U concentration in the open ocean." ° Uranium may also be enriched in estuarine colloids and in suspended organic matter within the surface ocean. " Scott" and Maeda and Windom" have suggested the possibility that humic acids can efficiently scavenge uranium in low salinity regions of some estuaries. Finally, sedimentary organic matter can also efficiently complex or adsorb uranium and other radionuclides. 

Nozaki Y, Yamada M, Nikaido H (1990) The marine geochemistry of actinium-227 evidence for its migration through sediment pore water. Geophys Res Lett 17 1933-1936 Nozaki Y (1993) Actinium-227 a steady state tracer for the deep-se basin wide circulation and mixing studes. In Deep Ocean Circulation, Physical and Chemical Aspects. Teramoto T (ed) Elsevier p 139-155... 

Cochran JK (1984) The fates of U and Th decay series nuclides in the estuarine environment. In The Estuary as a Filter. Kennedy VS (ed) Academic Press, London, p 179-220 Cochran JK (1992) The oceanic chemistry of the uranium - and thorium - series nuclides. In Uranium-series Disequilibrium Applications to Earth, Marine and Environmental Sciences. Ivanovich M, Harmon RS (eds) Clarendon Press, Oxford, p 334-395 Cochran JK, Masque P (2003) Short-lived U/Th-series radionuclides in the ocean tracers for scavenging rates, export fluxes and particle dynamics. Rev Mineral Geochem 52 461-492 Cochran JK, Carey AE, Sholkovitz ER, Surprenant LD (1986) The geochemistry of uranium and thorium in coastal marine-sediments and sediment pore waters. Geochim Cosmochim Acta 50 663-680 Corbett DR, Chanton J, Burnett W, Dillon K, Rutkowski C. (1999) Patterns of groundwater discharge into Florida Bay. Linrnol Oceanogr 44 1045-1055... 

Marquis and Lebel [534] precipitated potassium from seawater or marine sediment pore water using sodium tetraphenylborate, after first removing halogen ions with silver nitrate. Excess tetraphenylborate was then determined by silver nitrate titration using a silver electrode for endpoint detection. The content of potassium in the sample was obtained from the difference between the amount of tetraphenyl boron measured and the amount initially added. 

Shea and MacCrehan [322] and Duane and Stock [323] determined hydrophilic thiols in marine sediment pore waters using ion-pair chromatography coupled to electrochemical detection. 

Copper concentrations in sediment interstitial pore waters correlate positively with concentrations of dissolved copper in the overlying water column and are now used to predict the toxicity of test sediments to freshwater amphipods (Ankley et al. 1993). Sediment-bound copper is available to deposit-feeding clams, especially from relatively uncontaminated anoxic sediments of low pH (Bryan and Langston 1992). The bioavailability of copper from marine sediments, as judged by increased copper in sediment interstitial waters, is altered by increased acid volatile sulfide (AYS)... 

The presence of surfactants and their biodegradation products in different environmental compartments can invoke a negative effect on the biota. The ecotoxicity of surfactants to aquatic life has been summarised in the scientific literature [1—5]. Nevertheless, some information is still lacking in relation to the aquatic toxicity of surfactants, especially knowledge regarding the toxicity of the degradation products, the effect of surfactants on marine species, the ecotoxicity of mixtures of chemical compounds with surfactants, the relationship between toxicity and chemical residue and the effect of surfactant presence in specific environmental compartments (water, particulate matter, pore-water, sediment). 

Figure 16. Depth profiles from three ODP Sites, showing Li isotopic composition variations in pore waters (open symbols) and associated sediments (filled symbols), (a) Site 918, Irminger Basin, north Atlantic (Zhang et al. 1998) (b) Site 1038, Escanaba Trough, northeastern Pacific (James et al. 1999) (c) site 1039, Middle American Trench off of Costa Rica (Chan and Kastner 2000). The average composition of seawater is noted on each profile with dashed line (note different scales). Whereas sediments have relatively monotonous compositions, pore waters have compositions reflecting different origins and processes in each site. Interpretations of the data are summarized in the text under, Marine pore fluid-mineral processes. ...

Figure 2. Histogram of stable-chlorine isotopic measurements in marine pore waters reported as 5""C1 relative to CE Cl in SMOC represented by the vertical dashed line at 0%o. Data from Ransom et al. (1995), and Godon et al. (2004).

Zheng Y, Anderson RF, van Geen A, Kuwabara J (2000a) Authigenic molybdenum formation in marine sediments A link to pore water sulfide in the Santa Barbara Basin. Geochim Cosmochim Acta 64 4165-4178... 

In seawater, physical processes that transport water can also cause mass fluxes and, hence, are another means by which the salinity of seawater can be conservatively altered. The physical processes responsible for water movement within the ocean are turbulent mixing and water-mass advection. Turbulent mixing has been observed to follow Pick s first law and, hence, is also known as eddy diffusion. The rate at which solutes are transported by turbulent mixing and advection is usually much faster than that of molecular diffusion. Exceptions to this occur in locations where water motion is relatively slow, such as the pore waters of marine sediments. The effects of advection and turbulent mixing on the transport of chemicals are discussed further in Chapter 4. 

A significant amount of seawater is trapped in the open spaces that exist between the particles in marine sediments. This fluid is termed pore water or interstitial water. Marine sediments are the site of many chemical reactions, such as sulfate reduction, as well as mineral precipitation and dissolution. These sedimentary reactions can alter the major ion ratios. As a result, the chemical composition of pore water is usually quite different from that of seawater. The chemistry of marine sediments is the subject of Part 111. 

Most of our understanding of the marine chemistry of trace metals rests on research done since 1970. Prior to this, the accuracy of concentration measurements was limited by lack of instrumental sensitivity and contamination problems. The latter is a consequence of the ubiquitous presence of metal in the hulls of research vessels, paint, hydrowires, sampling bottles, and laboratories. To surmount these problems, ultra-clean sampling and analysis techniques have been developed. New methods such as anodic stripping voltammetry are providing a means by which concentration measurements can be made directly in seawater and pore waters. Most other methods require the laborious isolation of the trace metals from the sample prior to analysis to eliminate interferences caused by the highly concentrated major ions. 

Reaction rates of nonconservative chemicals in marine sediments can be estimated from porewater concentration profiles using a mathematical model similar to the onedimensional advection-diffusion model for the water column presented in Section 4.3.4. As with the water column, horizontal concentration gradients are assumed to be negligible as compared to the vertical gradients. In contrast to the water column, solute transport in the pore waters is controlled by molecular diffusion and advection, with the effects of turbulent mixing being negligible. 

The actual density of clay minerals is 2.7g/cm. but these solids are surrounded by pore waters as they accumulate in the sediments. An average wet density of marine sediments is estimated at 1.6g/cm ... 

A conceptual model of sedimentary nitrogen cycling. Dashed arrows represent pore water diffusion and advection. Dotted arrows represent sedimentation. Source-. After Burdige, D.J. (2006). Geochemistry of Marine Sediments. Princeton University Press, p. 453. 

The tendency of a marine organism to bioaccumulate a toxic metal depends in part on its lifestyle, as this determines the degree to which it is exposed to elevated concentrations in seawater or the sediments. For example, benthic animals that burrow will be exposed to sediment pore waters rather than to the overlying seawater. Animals that use mucous feeding nets, such as larvaceans, will be more prone to sorb metals because of the large surfece area of their nets. 

In the marine environment oxygen and hydrogen isotope compositions of pore waters may be inherited from ocean water or inflnenced by diagenetic reactions in the sediment or nnderlying basement. Knowledge of the chemical composition of sedimentary pore waters has increased considerably since the beginning of the Deep-Sea-Drilling-Project. From numerous drill sites, similar depth-dependent trends in the isotopic composition have been observed. 

Of special interest in recent years has been the analysis of natural gas hydrates that form in marine sediments and polar rocks when saline pore waters are saturated with gas at high pressure and low temperature. Large and 5D-variations of hydrate bound methane, summarized by Kvenvolden (1995) and Milkov (2005), suggest that gas hydrates represent complex mixtures of gases of both microbial and thermogenic origin. The proportions of both gas types can vary significantly even between proximal sites. 

McConnaughey T (1989b) C and 0 disequilibrium in biological carbonates. II. In vitro simulation of kinetic isotope effects. Geochim Cosmochim Acta 53 163-171 McCorkle DC, Emerson SR (1988) The relationship between pore water isotopic composition and bottom water oxygen concentration. Geochim Cosmochim Acta 52 1169-1178 McCorkle DC, Emerson SR, Quay P (1985) Carbon isotopes in marine porewaters. Earth Planet Sci Lett 74 13-26... 

---