Plastics titanium dioxide

Plastics. Titanium dioxide is used to color durable and non durable goods like toys, appliances, automobiles, furniture and packaging films. Furthermore, Ti02 pigments absorb UV radiation with a wavelength <415 nm and thus protect the pigmented goods from these harmful rays. 

Titanium dioxide pigment coated with pentaerythritol, trimethylolpropane, or trim ethyl ol eth an e exhibits improved dispersion characteristics when used in paint or plastics formulations. The polyol is generally added at levels of 0.1—0.5% (96). 

Titanium Tetrachloride. The major use for titanium tetrachloride [7550 5-0] is in titanium dioxide production, and titanium dioxide [13463-67-7] is enjoying strong growth for use as a filler in pulp and paper manufacture and as a pigment in paint and plastic manufacture. Annual growth for this product is forecasted at between 2.5 and 3.0% through 1992. 

Use. Titanium dioxide is mainly used in the production of paints and lacquers (55—60%), plastics (15—20%), and paper ( 15%). Other apphcations include the pigmentation of printing inks, mbber, textiles (qv), leather, synthetic fibers, ceramics, white cement, and cosmetics. 

Wavelength dispersive x-ray fluorescence spectrometric (xrf) methods using the titanium line at 0.2570 nm may be employed for the determination of significant levels of titanium only by carefiil matrix-matching. However, xrf methods can also be used for semiquantitative determination of titanium in a variety of products, eg, plastics. Xrf is also widely used for the determination of minor components, such as those present in the surface coating, in titanium dioxide pigments. 

W. Kampfer, and E. Stieg, Jr., Color Eng. 44, 35—40, 44 (1967). A description of the manufacture, properties, and uses of titanium dioxide as a colorant for paint, food, plastics, and other materials. 

The initial uses of colorants in plastics were as extenders and additives. Carbon black and titanium dioxide were and are stiU used as fillers (qv) because of their low cost. Almost from plastics inception the limitation of black and white did not offer sufficient color choices for end users looking to differentiate their products. The increase in aesthetic requirements along with different performance requirements and resin compatibiUties led to a great expansion in the number of different chemical classes of colorants and forms in which these colorants are available in today s market. 

Various additives and fillers may be employed. Calcium carbonate, talc, carbon black, titanium dioxide, and wollastonite are commonly used as fillers. Plasticizers are often utilized also. Plasticizers may reduce viscosity and may help adhesion to certain substrates. Thixotropes such as fumed silica, structured clays, precipitated silica, PVC powder, etc. can be added. Adhesion promoters, such as silane coupling agents, may also be used in the formulation [69]. 

R.D. Gould, Combustion Instability of Solid Propellants Effect of Oxidizer Particle Size, Oxidizer/Fuel Ratio and Addition of Titanium Dioxide to Plastic Pro pell ants , Rept No RPE-TR-68/1, Westcott (Engl)... 

Titanium dioxide (E171, Cl white 6) is a white, opaque mineral occurring naturally in three main forms rutile, anatase, and brookite. More than 4 million tons of titanium dioxide are produced per year and it is widely used for industrial applications (paints, inks, plastics, textiles) and in small amounts as a food colorant. ° "° Production and properties — Titanium oxide is mainly produced from ilmenite, a titaniferous ore (FeTiOj). Rutile and anatase are relatively pure titanium dioxide (Ti02) forms. Titanium oxide pigment is produced via chloride or sulfate processes via the treatment of the titanium oxide ore with chlorine gas or sulfuric acid, followed by a series of purification steps. High-purity anatase is preferred for utilization in the food industry. It may be coated with small amounts of alumina or silica to improve technological properties. 

All commercial materials are based on calcium hydroxide and liquid alkyl salicylates (Prosser, Grolfman Wilson, 1982) and are supplied as a two-paste pack. Zinc oxide is sometimes added to the calcium hydroxide, as are neutral fillers. A paste is formed from this powder by the addition of a plasticizer examples include A-ethyl toluenesulphonamide (o- orp-) and paraffin oil, with sometimes minor additions of polypropylene glycol. The other paste is based on an alkyl salicylate as the active constituent containing an inorganic filler such as titanium dioxide, calcium sulphate, calcium tungstate or barium sulphate. Alkyl salicylates used include methyl salicylate, isobutyl salicylate, and 1-methyl trimethylene disalicylate. An example of one commercial material, Dycal, is given in Table 9.7, but its composition has been subjected to change over the years. 

Pearlescent pigments give rise to a white pearl effect often accompanied by a coloured iridescence. The most important pearlescent pigments consist of thin platelets of mica coated with titanium dioxide which partly reflect and partly transmit incident light. Simultaneous reflection from many layers of oriented platelets creates the sense of depth which is characteristic of pearlescent lustre and, where the particles are of an appropriate thickness, colours are produced by interference phenomena. Pearlescent pigments are used in automotive finishes, plastics and cosmetics. 

A white pigment for rubbers and plastics characterised by high tinctorial power, fastness to light, and chemical stability. Titanium dioxide pigments are made in two crystal forms, mtile and anatase, which differ in crystal structure and crystal size. 

Plastics Compounding Redbook, 19 543 Plastics fabrication 20 222-223 microwave technology in, 16 530 Plastic sheet specifications, 16 291 Plastic sheet thermoforming, 23 399 Plastics industry, titanium dioxide in, 25 25-26... 

The refractive index of these pigments is about 1.5, which means that they give a transparent blue when used in paints and clear plastics. Opacity can be increased by adding small amounts of titanium dioxide. The principal failing of ultramarine is its lack of resistance to acid, which can even decompose the pigment if there is sufficient available. Coated grades are made with substantially improved acid resistance. 

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