Plastering

CaSO4-0-5HiO, prepared by heating gypsum at 130 "C, is used as plaster of Paris. Gypsum and anhydrite are used for H2SO4 production and gypsum is used as a soil additive and as an inert additive to pharmaceuticals and insecticides. 

Used as a light-weight aggregate in heat and sound insulating plasters, as a loose fill and in... 

Qualitative examples abound. Perfect crystals of sodium carbonate, sulfate, or phosphate may be kept for years without efflorescing, although if scratched, they begin to do so immediately. Too strongly heated or burned lime or plaster of Paris takes up the first traces of water only with difficulty. Reactions of this type tend to be autocat-alytic. The initial rate is slow, due to the absence of the necessary linear interface, but the rate accelerates as more and more product is formed. See Refs. 147-153 for other examples. Ruckenstein [154] has discussed a kinetic model based on nucleation theory. There is certainly evidence that patches of product may be present, as in the oxidation of Mo(lOO) surfaces [155], and that surface defects are important [156]. There may be catalysis thus reaction VII-27 is catalyzed by water vapor [157]. A topotactic reaction is one where the product or products retain the external crystalline shape of the reactant crystal [158]. More often, however, there is a complicated morphology with pitting, cracking, and pore formation, as with calcium carbonate [159]. 

Bandages (several sizes), gauze, lint, cotton wool, adhesive plaster, Elasto-plast Or equivalent, and a sling. 

Mixed with sand it hardens as mortar and plaster by taking up carbon dioxide from the air. Calcium from limestone is an important element in Portland cement. 

Gypsum [7778-18-9] Gypsum board Gypsum plaster board Gypsy... 

Wagner equation Wagner number Wakamatsu reaction Waldhof fermentor Walkman Wallace plasticity Wallach procedure Wall baffles Wallboard Wall geometries Wallpaper paste Wallpaper pastes Wallpapers Wall plaster Walnut oil... 

Although the use of simple diluents and adulterants almost certainly predates recorded history, the use of fillers to modify the properties of a composition can be traced as far back as eady Roman times, when artisans used ground marble in lime plaster, frescoes, and po22olanic mortar. The use of fillers in paper and paper coatings made its appearance in the mid-nineteenth century. Functional fillers, which introduce new properties into a composition rather than modify pre-existing properties, were commercially developed eady in the twentieth century when Goodrich added carbon black to mbber and Baekeland formulated phenol— formaldehyde plastics with wood dour. 

In the eadiest known paintings, the primitive cave paintings, paint was appHed directly onto the cave wall, with tittle or no preparation. As early as the Old Kingdom in ancient Egypt, however, wall surfaces were specially prepared using a coating of plaster. In time, the refinement and complexity of the preparation layers increased until in the Renaissance several layers of different composition and fineness were superimposed. Other preparations used, especially in the Far East, consisted of a clay layer. 

The medium is the binder which provides for the adhesion of pigments. The most important types are the temper media (glue, egg, and gum), the oils, and wax. In addition, for wall painting there is the tme fresco technique, where the pigments are laid down in a fresh, wet plaster preparation layer. Several other media have been used, but much less frequendy, eg, casein temper. In modem paints, a number of synthetic resins are used for this purpose. Contemporary artist paints are often based on acryhc polymers (see Acrylic ester polymers Paints). 

Technological History. Archaeologists often divide the neolithic period, the latter part of what used to be called the Stone Age, into pre- and post ceramic, with reference to when ceramics came into production (88—92). Actually, there are occasions of pre-ceramic pyrotechnology, such as in the case of the fifth millenium BC mideastem plaster production (93). So far the eadiest occurrence of ceramics is in the 28th millenium BC in Eastern Europe, although here the technique was not used for the production of vessels but of figurines (94). 

Residential Construction. Owing to rising energy costs, the cost and low thermal conductivity are of prime importance in wall and ceiling insulation of residential buildings. The combination of insulation efficiency, desirable stmctural properties, ease of appHcation, abiHty to reduce air infiltration, and moisture resistance has led to use of extmded polymeric foam in residential constmction as sheathing, as perimeter and floor insulation under concrete, and as a combined plaster base and insulation for walls. 

Finishing lime is a refined hydrated lime, milled to make it suitable for plastering, particularly the finish coat. Putty derived from this hydrate possesses unusually high plasticity. 

Umestone Sand. A discrete gradation of substantially 2.38—0.225 mm (8—65 mesh) size provides a versatile fine aggregate or sand for road mixtures, concrete, plaster, or any constmcfion use suppHed by siHca sand. The only disadvantage is that in many areas conventional sand is less cosdy. 

Any of these mortars can be used for unit masonry or for stucco (exterior plaster). The finish coat in conventional interior plastering is composed of either neat time putty or a sanded putty, gauged with Keene s cement or gypsum-gauging plaster. The former is called a whitecoat finish the latter a sandfloat finish. 

Slip casting of metal powders closely follows ceramic slip casting techniques (see Ceramics). SHp, which is a viscous Hquid containing finely divided metal particles in a stable suspension, is poured into a plaster-of-Paris mold of the shape desired. As the Hquid is absorbed by the mold, the metal particles are carried to the wall and deposited there. This occurs equally in all directions and equally for metal particles of all sizes which gives a uniformly thick layer of powder deposited at the mold wall. 

Potassium alum, which also occurs naturally as the mineral kalinite [7784-24-9], KAl(SO 2 12H20, sp gr 1.75, is used ia tanning skins, as a mordant ia dyeiag, and ia the pharmaceutical and cosmetic iadustries (see Pharmaceuticals Cosmetics). It is used as a styptic pencil and as a hardening agent and set accelerator for cement and plaster. The ACGIH threshold limit value TWA is 2 mgAl/m (1 ). 

Treatments used for various types of fractures are cast immobilization, traction, and internal fixation. A plaster or fiber glass cast is the most commonly used device for fracture treatment. Most broken bones heal successfiiUy once properly repositioned, ie, fixed in place via a cast. This type of cast or brace is known as an orthosis. It allows limited or controlled movement of nearby joints. This treatment is desirable for certain fractures. 

Forming. Most refractory shapes are formed by mechanical equipment, but some very large or intricate shapes requke hand mol ding ki wooden, steel-lined molds with loose liners to permit easy removal of plaster of Paris molds. 

Large and small shapes may be sUp cast from both plastic and nonplastic mixes by the usual techniques. Precise shapes, such as glass feeder parts, are made in this way as well as large flux blocks. The process requkes the formulation of a sUp of suitably stable character to be poured into a plaster mold to be dewatered. After it solidifies, the mold is removed and dried further before firing. 

The use of porous formers ia the dippiag process, or porous molds prepared from plaster of Paris or uaglazed porcelaia with a surface pore size smaller than the majority of mbber particles, has been widely adopted ia the latex iadustry. With the porous porcelaia formers, the mbber particles are filtered oa the surface of the formers. The mbber latex coagulates because of its high coaceatratioa to form a film of increa sing thickness as more water is absorbed iato the ceramic. Its rate of iacrease diminishes sharply beyoad an optimum period of time, however, depending on the various characteristics of the ceramic. 

Those made of plaster of Paris have a finite life for that reason, but residues can be removed from ceramic molds, by use of an inorganic acid to clean the surface, and a chelating agent such as EDTA for deeper cleansing. 

Pa.ints, Paints (qv) prepared from poly(vinyl acetate) and its copolymers form flexible, durable films with good adhesion to clean surfaces, including wood, plaster, concrete, stone, brick, cinder blocks, asbestos board, asphalt, tar paper, wahboards, aluminum, and galvani2ed iron (147). Adherence is also good on painted surfaces if the surfaces are free from dirt, grease, and mst. Developments in emulsion polymeri2ation for paint latices have been reviewed (148). 

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