Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Parameters to Be Studied

If a metal specimen is subjected to alternating stresses the generation of dislocations occurs. There is a threshold stress Vs at which this process begins [81] [Pg.281]

The number of newly generated dislocation loops is directly proportional to the mobile dislocation density and also to the dislocation velocity. Hence the multiplication rate of mobile dislocations is given by [Pg.281]

Substituting (18.5) to (18.4) we obtain the first differential equation of the system  [Pg.281]

Since p increases during deformation, the threshold stress increases also with time. [Pg.281]

The velocity of dislocations may be expressed as the velocity of a thermally activated process  [Pg.281]


Eddy-current non-destructive evaluation is widely used in the aerospace and nuclear power industries for the detection and characterisation of defects in metal components. The ability to predict the probe response to various types of defect is highly valuable since it enables the influence of particular parameters to be studied without recourse to costly and time consuming experiments. The solution of forward problems is also essential in the process of inverting experimental data. [Pg.140]

Other features of an analytical method that should be borne in mind are its linear range, which should be as large as possible to allow samples containing a wide range of analyte concentrations to be analysed without further manipulation, and its precision and accuracy. Method development and validation require all of these parameters to be studied and assessed quantitatively. [Pg.269]

Having said this, it was felt therefore that there is a need for a book addressing analysis and characterisation of polymers from the point of view of what we wish to call the primary analytical question. Many excellent textbooks and reference works exist which address one or more individual analytical techniques, see, for example, references [1-10]. These books form the basis of the knowledge of the technique expert. They also contain many excellent and varied examples on successful applications of analytical techniques to polymer analysis and characterisation. There are also books which address the multitude of analytical techniques applied in polymer analysis, see, for example, references [11-24], However, a synthetic chemist may wish to know the constitution of his/her polymer chain, a material scientist may want to find out the reasons why a fabricated sample had failed. What technique is best or optimal to study chain constitution will depend on the situation. Polymer failure may result from morphological features, which needs to be avoided, a contaminant, a surface property degradation, etc. When a sample has been processed, e.g., a film blown, molecular orientation may be the key parameter to be studied. A formulation scientist may wish to know why an additive from a different supplier performs differently. It is from such points of view that polymer analysis and characterisation is addressed in this book. [Pg.5]

The structure of quaternary onium ion active sites was one of the first parameters to be studied 53-89>. Valid comparisons of active site structure can be made only if all other variables are kept constant. Ideally mass transfer and intraparticle diffusion should not be rate limiting factors. With 7-10% RS, 2% CL polystyrenes the tri-n-butyl and tri-n-octylammonium ions 7 and 8... [Pg.66]

A first parameter to be studied is the applied potential difference between anode and cathode. This potential is not necessarily equal to the actual potential difference between the electrodes because ohmic drop contributions decrease the tension applied between the electrodes. Examples are anode polarisation, tension failure, IR-drop or ohmic-drop effects of the electrolyte solution and the specific electrical resistance of the fibres and yarns. This means that relatively high potential differences should be applied (a few volts) in order to obtain an optimal potential difference over the anode and cathode. Figure 11.6 shows the evolution of the measured electrical current between anode and cathode as a function of time for several applied potential differences in three electrolyte solutions. It can be seen that for applied potential differences of less than 6V, an increase in the electrical current is detected for potentials great than 6-8 V, first an increase, followed by a decrease, is observed. The increase in current at low applied potentials (<6V) is caused by the electrodeposition of Ni(II) at the fibre surface, resulting in an increase of its conductive properties therefore more electrical current can pass the cable per time unit. After approximately 15 min, it reaches a constant value at that moment, the surface is fully covered (confirmed with X-ray photo/electron spectroscopy (XPS) analysis) with Ni. Further deposition continues but no longer affects the conductive properties of the deposited layer. [Pg.303]

The dissociation of acetic acid in aqueous solution is an example of the simplest type of protolytic process. The dissociation constant was one of the first chemical parameters to be studied as a function of isotopic composition of the solvent (La Mer and Chittum, 1936 Homel and Butler, 1936), and the determinations have been repeated by several groups of workers. Conductivity measurements (La Mer and Chittum, 1936), potentiometry using the quinhydrone electrode (Korman and La Mer, 1936) or glass electrodes (Salomaa et al., 1964a Gold and Lowe, 1968), and measurements of the rate of a hydrogen-ion... [Pg.297]

Depending on the parameters to be studied and the method to be used, 37-185 MBq (1-5 mCi) are used in adults (70 kg). Studies of renal blood flow or transport through the ureters generally require a larger dose than do studies of intrarenal transport whereas renography requires smaller activities than dynamic sequential scintigraphy. [Pg.310]

Although solvent exposure gets the most attention as a driving force in protein evolution, it is not the only physical parameter to be studied in this context. Multiple studies have considered the role of protein sequence length in evolution (which corresponds to the final size of the folded protein) [7,56]. Simple organisms... [Pg.14]

The protocol defines how the study will be done (the process, equipment, critical steps, and parameters), and who is responsible for its design, execution, analysis, and approval. The sampling activity is also well defined, describing the locations to be sampled, the sampling devices to be used, the quantities required and time point during processing when they should be taken. The protocol defines all the important process parameters to be studied and analyzed in order to demonstrate each significant step performs reliably in terms of quality and yield. The final approval is reserved for the quality function. [Pg.267]

The primary process parameters to be studied are (1) reactor residence time, (2) energetic feed rate, (3) reaction temperature, (4) caustic concentration, and (5) agitation speed. [Pg.39]

The last parameter to be studied in respect of its effect on water partial pressure and ultimately on catalyst performance was gas feed rate or GHSV. It was thought that the faster the gas flow though the bed during reduction the more easily any water produced would be removed, hence keeping the partial pressure of water low throughout the catalyst bed. Two reductions using the... [Pg.284]

The present paper will use the very fast and accurate method of calculating the pressure and film thickness in eiastohydrodynamic lubricated conjunctions developed by Houpert and Hamrock (1986) and investigate the effects of a complete operating range of load, speed and materials parameters. The performance parameters to be studied are the details of the pressure spike including the amplitude, width and location of the spike, the mass flow rate, the center of pressure the minimum film thickness. Formulas will be developed to describe the performance parameters as a function of the operating parameters. The results to be presented are only applicable for idealized situations of smooth surfaces, Newtonian fluid behavior, isothermal and fully flooded lubrication conditions. [Pg.199]

Further improvement on the system to cater for rehabilitation purposes could also be made whereby the system could be modified to capture various important parameters to be studied for continuous rehabilitation monitoring. [Pg.141]

For years, large discussions have been devoted to the question if economical criteria should be considered to determine success in the pilot tests. It is the opinion of the authors of this paper that a pilot test primarily collects data and generates technical information, particularly in early execution phase, such as Stage 1. However, economical analysis helps in determining the main technical parameters to be studied. [Pg.288]

After tuning and calibration, the proper functioning of the interface can further be investigated by the injection of a number of standard compounds, e.g. adenosine and tertiary amines, as well as the com-pound(s) of interest. Subsequently, the system can be optimized to achieve the highest response or the best signaTto-noise ratio. Parameters to be studied are the ammonium acetate concentration, the concentrations of the organic modifier and possible other mobile phase additives, the flow-rate, the optimum compound-dependent vaporizer temperature, the source block temperature, the repeller potential, as... [Pg.1190]

Robustness— This is a measure of the ability of an analytical procedure to not be affected by minor modifications of factors associated with the procedure. The estimation of the robustness of a method is a subjective process, depending on the context and choice of parameters to be studied determined by the person in charge of the validation. The legitimacy of the choice must be justified during the procedure. One can, for example, study the influence of the pH of the matrix (e.g., urine) during the preparation of the sample on the extraction yield of the analyte. The aim is to verify that a minor modification of pH does not significantly alter the extraction yield. If the room where the samples are prepared is not air conditioned, one can also check that a modification in temperature does not alter the dosage results. [Pg.132]

The final design parameter to be studied in this chapter is the locations of the two fresh feed-streams. Up to this point we have assumed that the lighter reactant fresh feed Fqa is introduced on the bottom tray of the reactive zone (Ns +1) and the heavier reactant fresh feed Fob is introduced on the top tray of the reactive zone (Ns -I- 1 -I- Nrx)- This configuration seems like a logical choice. However, the fresh feeds could be introduced on trays inside the reactive zone. The question is how this affects the design, primarily in terms of energy consumption because this is our major economic performance criterion. [Pg.33]

The progress made with H-NMR allows a wide range of materials and mix parameters to be studied regarding hydrate s water and the surrounding capillary pores. These possibilities open up perspectives to improve our understanding of the fundamental hydration mechanisms. [Pg.345]


See other pages where Parameters to Be Studied is mentioned: [Pg.256]    [Pg.257]    [Pg.430]    [Pg.390]    [Pg.321]    [Pg.3728]    [Pg.49]    [Pg.360]    [Pg.246]    [Pg.34]    [Pg.30]    [Pg.115]    [Pg.281]    [Pg.281]    [Pg.305]    [Pg.5]    [Pg.117]   


SEARCH



Parameters studied

TO parameter

© 2024 chempedia.info