Chlorinated rubber paints

Uses Defoamer for solv.-based paints, esp. long-oil and med.-oil airdrying alkyd resins systems, wood preservatives, vinyl resin paints, acrylic resin paints, nitrocellulose paints, chlorinated rubber paints Features Highly effective... 

Uses Detoamer tor polar org. coating systems, esp. two-part polyurethane paints and furniture finishes, aciyilc paints, chlorinated rubber paints... 

Fifth Resin paint Long oil alkyd System MIO paint Chlorinated rubber System paint Chlorinated rubber... 

For special applications, however, such as for normally humid areas, and contaminated or chemically aggressive locutions, epoxy paints tne con.sidered to be more appropriate. They provide a protective coating which is resistant to chemical fumes, corrosion and temperature. Chlorinated rubber paints, which also fall into the same category of protective paints, may also be used for these areas but, not being temperature resistant, are not preferred to epoxy paints. 

Chlorinated rubber paints and vinyl paints have excellent resistance to high concentrations of acids and alkalis at temperatures up to 80°C. High-build chlorinated rubber paints, which give a thickness of 0.12 mm per coat are commonly used for process plant equipment. 

Epoxy resin paints, inferior to chlorinated rubber for resistance to strong acids, are excellent for dilute acids and strong alkalis. They produce a harder, more abrasion-resistant coating than does chlorinated rubber and are much better for resistance to fats, oils and many organic solvents. Table 3.50 gives data on the chemical resistance of epoxy resin coatings to different materials. 

Chlorinated rubber floor paints are probably the most common of the lower-cost floor paints on the market. They produce tough and chemically resistant coatings, but their adhesion to concrete is not always good. They tend to wear off in patches and cannot be considered as a durable floor treatment except under light traffic conditions. However, re-coating is a simple job and floors can easily be repainted over weekend shutdowns, for example. Similar paints based on other resins such as acrylics, vinyls and styrene butadiene are also used. 

Vinyls Vinyl chloride co-polymer resins were developed in the USA in the late 1930s. They have better weather and slightly more chemical resistance than chlorinated rubber paints. They are generally resistant to crude oil but application is more critical. For example, they are particularly sensitive to moisture present on a surface during painting and this can lead to adhesion failure. They are also more prone to solvent entrapment than chlorinated rubber paints. 

Thin coatings These pigmented materials, commonly known as floor paints, are often based on chlorinated rubber (see Section 12.3.2) or epoxy ester (see Section 12.3.1). They have limited life in heavy traffic but are easy to apply. 

Road paints These are normally chlorinated rubber alkyds and are easy to apply but are inherently less durable than the thermoplastic materials. 

Paints are complex formulations of polymeric binders with additives including anti-corrosion pigments, colors, plasticizers, ultraviolet absorbers, flame-retardant chemicals, etc. Almost all binders are organic materials such as resins based on epoxy, polyurethanes, alkyds, esters, chlorinated rubber and acrylics. The common inorganic binder is the silicate used in inorganic zinc silicate primer for steel. Specific formulations are available for application to aluminum and for galvanized steel substrates. 

Solvent resistance This varies from very poor (for chlorinated rubbers) to good (for polyurethanes). All paint binders have specific susceptibilities and the presence of small quantities of the appropriate solvent in the atmosphere in the region of an item of plant can cause rapid failure. 

Chlorinated rubber is soluble in aromatic solvents, and paints made from it dry by solvent evaporation alone. In contrast to the vinyls, there is less difficulty in formulating systems that are suitable for brush application. It has excellent resistance to a wide range of chemicals and to water, but as it is extremely brittle it needs to be plasticised. To preserve chemical resistance it is necessary to use inert plasticisers such as chlorinated paraffin wax. Due to the presence of ozone depleting solvents, chlorinated rubber coatings are being phased out and largely replaced by vinyl acrylic coatings which have very similar performance and can be formulated from lower aromatic or aliphatic solvents. 

Where fumes or deposits which act as anti-oxidants are present, no orthodox paint which dries by oxidation can give satisfactory service. Instead, a coating which dries either by evaporation (e.g. a selected chlorinated rubber paint), or by a cross-linking reaction (e.g. a catalysed epoxy or two-component polyurethane paint) must be used. 

Oil-base (including oil-modified alkyd resin) paint films should not be used in alkaline environments as the paint will deteriorate owing to saponification alkali-resistant coatings are provided by some cellulose ethers, e.g. ethyl cellulose, certain polyurethane, chlorinated rubber, epoxy, p.v.c./ p.v.a. copolymer, or acrylic-resin-based paints. In particular, aluminium and its alloys should be protected by alkali-resistant coatings owing to the detrimental effects of alkali on these metals. 

Lifting may also occur if a paint containing strong solvents (xylol or solvent naphtha, not to mention such active solvents as esters and ketones) is applied (not necessarily by brushing) over a paint which is not resistant to them. The older an oxidising paint film becomes, the more solvent-resistant it will be. Short-oil media and pigment-rich paints are not so prone to lifting. This type of failure is not restricted to oil-base materials it can, for example, also occur with chlorinated rubber paints. 

A wide range of paints and other organic coatings is used for the protection of mild steel structures. Paints are used mainly for protection from atmospheric corrosion. Special chemically resistant paints have been developed for use on chemical process equipment. Chlorinated rubber paints and epoxy-based paints are used. In the application of paints and other coatings, good surface preparation is essential to ensure good adhesion of the paint film or coating. 

Figure 1 indicates a typical nitroglycerin facility "inside out" wood frame construction at a concrete floor slab. Note that the exterior cant strip, the lead conductive floor cant and the wood cap are all sloped to discourage product build-up and facilitate cleaning. This assembly also indicates spray-on foam insulation as an optional construction item. At Radford AAP this is a safety approved insulation system. The insulation at Radford AAP received a chlorinated rubber paint coating for weathering. 

Uses Solvent for chlorinated rubber insecticide and bleach manufacturing paint, varnish and rust remover manufacturing degreasing, cleansing, and drying of metals denaturant for ethyl alcohol preparation of 1,1-dichloroethylene extractant and solvent for oils and fats insecticides weed killer fumigant intermediate in the manufacturing of other chlorinated hydrocarbons herbicide. 

Substrates, Paints and Coatings. Both flash rusting and underfilm darkening studies exployed a white, pH 4.5, primer formulation (see Appendix), designated as Standard, based upon Haloflex 202, a chlorine-containing vinyl acrylic latex. A zinc phosphate free formulation, designated as Non-Standard, of pH6 was prepared by substitution of zinc phosphate for barytes. The comparison paints were a commercial butyl acrylate-methyl methacrylate water borne primer, formulated at pH 9, and a solvent based chlorinated rubber primer. 

To study the effect of contaminants (chlorides and sulphates) at the interface metal/coating, a set of panels (surface A Sa 3) was prepared and dosed with solutions of NaCl and FeSO in distilled water and methanol. Subsequently, two paint systems (chlorinated rubber and polyurethane) were applied on these contaminated surfaces. 

Figure 4. Effect of interface contamination by chlorides. Paint System Chlorinated Rubber.

Chlorination of natural rubber (NR) is carried out with chlorine in carbon tetrachloride solution at 60-90°C to yield a chlorinated rubber containing about 65% chlorine, which corresponds to 3.5 chlorine atoms per repeat unit. The process is complex and includes chlorine addition to the double bond, substitution at allylic positions, and cyclization. Chlorinated rubber has high moisture resistance and is resistant to most aqueous reagents (including mineral acids and bases). It is used in chemical- and corrosion-resistant paints, printing inks, and textile coatings. Bromination of butyl rubber is also practiced [Parent et al., 2002]. 

Fire Retardent Paints. Fire retardant paints are based on chlorinated rubber and chlorinated plasticizers with added SbO. These reduce the rate of spread of flames. Addn of NH4H2PO4, PE, or dicyandiamide produces an intumescent or swelling paint that forms a thick insulating layer over the surface to which it is applied when exposed to flames Fire retardant paints do not control fires and are no substitute for an automatic sprinkler system. They are best used where the only hazard is exposed, combustible, interior finish materials or in isolated buildings where sprinklers will not be installed. The paint must be applied at the rate specified on the container if spread thinner the proper... 

Hercules Powder Co chlorinated rubber, supplied as a white granular powder intended for use in corrosive resistance paints as a film former (Ref 7)... 

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