Multilayered components

Many models have been developed that deal with the sorption properties of wood in the presence of moisture these have been discussed in a number of works (e.g. Skaar, 1972 Siau, 1984). They can be approximately divided into sorption models, such as the Brunauer-Emmett-Teller (BET) model, or solution models (such as the Hailwood-Horrobin, H-H, model). The sigmoidal shapes of sorption or desorption isotherms can be deconvoluted into two components. These are often taken to represent a monomolecular water layer (associated with the primary sorption sites, OH groups), and a multilayer component where the cell wall bound water molecules are less intimately associated with the fixed cell wall OH groups. 

Popper and Bariska (1972) studied the moisture sorption properties of wood chemically modified with acetic (or phthalic) anhydride and analysed the results using Brunauer-Emmett-Teller (BET) theory and the H-H model. Acetylation was found to reduce the number of sorption sites, whereas little effect was noted with phthaloylation. By dividing the sorption isotherm into a monolayer component and a multilayer component using the H-H model, it was shown that there was a large reduction in the... 

U.S. Pat. No. 6,958,185 [59] (by Crane Plastics Co., TimbeiTech) describes a wood-plastic composition comprised of a layer of a first composition that is secured to a layer of a second composition, with the resulting multilayer component having an improved combination of appearance, strength, durability, weight, weatherability, and other characteristics. 

One increasingly important property for interior components in automotive applications, where natural fiber-reinforced composites have performance advantages, is the acoustic absorption. Natural fiber-reinforced composite materials in an interior component have an open cell structure. It will therefore contribute to sound absorption and may result in a reduced need for absorbers. Multilayer components further offer many possibilities to tailoring the acoustic absorption of the system. 

Several other concept have been developed since then few of them have found industrial applications. The motor from Elliptec is using a multilayer component, encased in a structure to couple two flexural modes of the beam (Fig. 6.22a) [13]. The stator includes a play recovering mechanism in the form of a spring that ... 

It is evident that the second term on the right-hand side of Eq. (323) represents the multilayer (second and other layers) adsorption therefore, the BET relationship can be regarded as the sum of a Langmuir monolayer adsorption and of a pure multiplayer adsorption. In Fig. 31 are shown both the monolayer and the multilayer components of a BET relationship with a value of c = 50. The usual uniform interpretation of the BET equation can be seen in Fig. 32. 

Equation (331) can also be separated into monolayer and multilayer components ... 

The final applications discussed here are electrodes and metallizations for fine ceramics. This includes ohmic contact pastes for varistors and thermistors as well as materials for complex multilayer components. Figure 8.105 illustrates a cross-sectional view of a ceramic chip capacitor. The internal electrode can be Pt, Pd, or Ag-Pd depending on the type of ceramic formulation and its respective firing temperature. The end termination may be Ag or Ag-Pd and is typically required to be platable. The technical requirements of these materials are extremely challenging. 

FIG. 23 Component isotherms of ethane isoflierm measured on BPL-activated carbon at -60.5°C. The monolayer isotherm (O) is calculated from the T equation (116) the multilayer component ( ) is calculated from Eq. (143) when P P q (For parameters see Table 2.)... 

Most LB-forming amphiphiles have hydrophobic tails, leaving a very hydrophobic surface. In order to introduce polarity to the final surface, one needs to incorporate bipolar components that would not normally form LB films on their own. Berg and co-workers have partly surmounted this problem with two- and three-component mixtures of fatty acids, amines, and bipolar alcohols [175, 176]. Interestingly, the type of deposition depends on the contact angle of the substrate, and, thus, when relatively polar monolayers are formed, they are deposited as Z-type multilayers. Phase-separated LB films of hydrocarbon-fluorocarbon mixtures provide selective adsorption sites for macromolecules, due to the formation of a step site at the domain boundary [177]. 

Ellipsometry measurements can provide infomiation about the thickness, microroughness and dielectric ftinction of thin films. It can also provide infomiation on the depth profile of multilayer stmctiires non-destmctively, including the thickness, the composition and the degree of crystallinity of each layer [39]. The measurement of the various components of a complex multilayered film is illustrated m figure Bl.26.17 [40]. 

If these materials are deposited as LB multilayers, polymerization can be induced either by thennal or optical means. This subject has been intensively studied [95, 96, 92, 98 and 99]- Since parameters such as m, subphase components, pH and polymerization before and after dipping, as well as temperature and wavelength employed for polymerization can be varied, the literature on diacetylenes is extensive and the reader is referred for example to the book of Tredgold [1001. 

Bisphenol A. One mole of acetone condenses with two moles of phenol to form bisphenol A [80-05-07] which is used mainly in the production of polycarbonate and epoxy resins. Polycarbonates (qv) are high strength plastics used widely in automotive appHcations and appHances, multilayer containers, and housing appHcations. Epoxy resins (qv) are used in fiber-reinforced larninates, for encapsulating electronic components, and in advanced composites for aircraft—aerospace and automotive appHcations. Bisphenol A is also used for the production of corrosion- and chemical-resistant polyester resins, polysulfone resins, polyetherimide resins, and polyarylate resins. 

Presentiy, multilayer capacitors and packaging make up more than half the electronic ceramics market. For multilayer capacitors, more than 20 biUion units are manufactured a year, outnumbering by far any other electronic ceramic component. Multilayer ceramics and hybrid packages consist of alternating layers of dielectric and metal electrodes, as shown in Figures 5 and 6, respectively. The driving force for these compact configurations is miniaturization. 

Equally important as tape casting in the fabrication of multilayer ceramics is thick film processing. Thick film technology is widely used in microelectronics for resistor networks, hybrid integrated circuitry, and discrete components, such as capacitors and inductors along with metallization of MLC capacitors and packages as mentioned above. 

Because of the high functional values that polyimides can provide, a small-scale custom synthesis by users or toU producers is often economically viable despite high cost, especially for aerospace and microelectronic appHcations. For the majority of iudustrial appHcations, the yellow color generally associated with polyimides is quite acceptable. However, transparency or low absorbance is an essential requirement iu some appHcations such as multilayer thermal iusulation blankets for satellites and protective coatings for solar cells and other space components (93). For iutedayer dielectric appHcations iu semiconductor devices, polyimides having low and controlled thermal expansion coefficients are required to match those of substrate materials such as metals, ceramics, and semiconductors usediu those devices (94). 

Silver Thick Films. About half of the silver consumed in the United States for its electrical properties is used by the electronics industry. Of this amount some 40% is used for the preparation of thick-film pastes in circuit paths and capacitors. These are silk-screened onto ceramic or plastic circuit boards for multilayer circuit sandwich components. 

Many grades of interlayer are produced to meet specific length, width, adhesion, stiffness, surface roughness, color (93,94), and other requirements of the laminator and end use. Sheet can be suppHed with vinyl alcohol content from 15 to about 23 wt %, depending on the suppHer and appHcation. A common interlayer thickness for automobile windshields is 0.76 mm, but interlayer used for architectural or aircraft glaring appHcations, for example, may be much thinner or thicker. There are also special grades to bond rear-view mirrors to windshields (95,96) and to adhere the components of solar cells (97,98). Multilayer coextmded sheet, each component of which provides a separate property not possible in monolithic sheet, can also be made (99—101). 

Optical Coatings. Thin surface coatings are appHed to optical components to improve performance. Wideband antireflection coatings for the visible and ir regions need materials with a refractive iadex of for the best efficieacy. Cerium fluoride, a stable material resistant to humidity damage, has a suitable iadex, 1.63 ia the visible, 1.59 ia the iafrared, and is transparent over the range 0.5 p.m to 5 p.m. It is one of the compounds used to build up the multilayers deposited on lenses, sensors, and the like. 

The reflectivity for this simple case can be extended readily to more complex situations where there are concentration gradients in single films or multilayers comprised of different components. Basically the reflectivity can be calculated from a simple recursion relationship that effectively reduces any gradients in composition to a histogram representing small changes in the concentration as a function of depth. Details on this can be found in the literature cited. ... 

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