Liquids, storage venting

If a ventilated flammable-liquid storage cabinet is used under a fume hood, it should not be vented into the fume hood above it. It should have a separate exhaust duct connected to the exhaust system. Fires occur most frequently in fume hoods. Fire from a fume hood may propagate into a flammable-liquid storage cabinet directly vented into the hood. 

A standard liquid storage and transfer system is composed of a double wall storage vessel with either metallic or synthetic flexible transport tubing, a pressure build-up coil, fill and vent valves and necessary pressure control elements. 

Liquid storage vessels must be well designed and properly insulated to maintain liquid temperature for a reasonable period of time without adverse pressure rise or venting. The inner vessel must be designed, fabri-... 

Fixed-roof atmospheric tanks require vents to prevent pressure changes which would othei wise result from temperature changes and withdrawal or addition of liquid. API Standard 2000, Venting Atmospheric and Low Pressure Storage Tanks, gives practical rules for vent design. The principles of this standard can be applied to fluids other than petroleum products. Excessive losses of volatile liquids, particularly those with flash points below 38°C (100°F), may result from the use of open vents on fixed-roof tanks. Sometimes vents are manifolded and led to a vent tank, or the vapor may be extracted by a recov-eiy system. 

Safety Considerations Design and location of storage tanks, vents, piping, and connections are specified by state fire marshals, underwriters codes, and local ordinances. In NFPA 30, Flammable and Combustible Liquids Code, 1993 (published by the National Fire Protection Association, Quincy, Mass.), liquid petroleum fuels are classified as follows for safety in handhng ... 

Liquified gases are sometimes stored in well-insulated spherical containers that are vented to the atmosphere. Examples in the industry are the storage of liquid oxygen and liquid ammonia in spheres. If the radii of the inner and outer walls are r, and r, and the temperatures at these sections are T, and T, an expression for the steady-state heat loss from the walls of the container may be obtained. A key assumption is that the thermal conductivity of the insulation varies linearly with the temperature according to the relation ... 

No particular industrial hazards are encountered in handling liquid alum. However, a face shield and gloves should be worn around leaking equipment. The eyes or skin should be flushed and washed upon contact with liquid alum. Liquid alum becomes very sick upon evaporation and therefore spillage should be avoided. Storage tanks may be open if indoors but must be closed and vented if outdoors. Outdoor tanks should also be heated, if necessary, to keep the temperature above 450F to prevent crystallization. Storage tanks should be constructed of type 316 stainless steel, FRP, steel lined with rubber, polyvinyl chloride, or lead. Liquid alum can be stored indefinitely without deterioration. 

Storage tanks for liquid caustic soda should be provided with an air vent for gravity flow. The storage capacity should be equal to 1.5 times the largest expected delivery, with an allowance for dilution water, if used, or two-weeks supply at the anticipated feed rate, whichever is greater. Tanks for storing 50 percent solution... 

The first vessel in the blowdown system is therefore an acid-hydrocarbon separator. This drum is provided with a pump to transfer disengaged acid to the spent acid tank. Disengaged liquid hydrocarbon is preferably pumped back to the process, or to slop storage or a regular non-condensible lowdown drum. The vented vapor stream from the acid-hydrocarbon separator is bubbled through a layer of caustic soda solution in a neutralizing drum and is then routed to the flare header. To avoid corrosion in the special acid blowdown system, no releases which may contain water or alkaline solutions are routed into it. 

OSHA 1910.106 (based on die 1969 edidon of NFPA 30) and NFPA 30 (2000) designate where conservation vents and flame arresters may be needed on storage tanks or process vessels containing flammable or combustible liquids at atmospheric pressure. Sections (b)(2)(iv)(f) and (g) of OSHA 1910.106 state as follows ... 

Fauske, H. K, et al, Emergency Relief Vent Sizing for Fire Emergencies Invoking Liquid-Filled Atmospheric Storage Vessels, Plant/Operations Progress, 5 (4), 205-208, October 1986. 

Epstein, M., Fauske, H. K. and Hauser, G. M., The Onset of Two-Phase Venting Via Entr ainment in Liquid-Filled Storage Vessels Exposed to Fire, Journal Loss Prevention Process Industries, 2 (1), 45-49, January 1989. 

In some cases the decision whether storage vessels will be equipped with a vapor recovery system has been determined by the United States Environmental Protection Agency (EPA). In 1973 it set the standards4,5 for all petroleum liquids that are stored in vessels of mcae than 65,000 gal (245 m3). It states that if the vapor pressure is greater than 11.1 psia (570 mm Hg) a vapor recovery system or its equivalent must be installed on any new tanks. If the vapor pressure is between 1.52 psia (78 mm Hg) and 11.1 psia (570 mm Hg), a floating head tank may be used or a vapor recovery system may be installed. Since the former is cheaper it will usually be selected. Below 1.52 psia (78 mm Hg) only a conservation vent or its equivalent is required. 

Large storage tanks need a breather vent (technically called a conservation vent) to allow air to move into and out of the tank as a result of temperature and pressure changes and a change in the tank liquid level. Unfortunately, these vents also allow volatile materials to escape, resulting in potential worker exposures. 

A storage tank is vented to the atmosphere. If a hole develops in the tank, the liquid level hL is given by the following differential equation ... 

At 77°F gasoline has a vapor pressure of 4.6 psia. Why can gasoline be stored in vented storage vessels without the presence of flammable vapors above the liquid in the vessel Comment on the EPA s effort to reduce gasoline volatility in order to reduce fugitive emissions. What will happen as the volatility is reduced ... 

The following liquids are stored in a storage vessel at 1 atm and 25°C. The vessels are vented with air. Determine whether the equilibrium vapor above the liquid will be flammable. The liquids are ... 

A liquid mixture containing 0.50 mole fraction benzene-toluene is contained in a storage vessel at 25°C and 1 atm. The vessel is vented to the atmosphere. 

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