Avoidance, of corrosion

Despite the high temperatures which are used in these reactions, our results show that zeolites are effective catalysts for promoting hydration of triple bond derivatives in respect of an easy handling and avoidance of corrosion. 

The corrosion engineer can play a major role in system design, material selection, process or environmental control, and remediation. The focus of these efforts should not necessarily be the complete elimination or avoidance of corrosion, but rather the selection of the most cost-effective means of corrosion control and abatement. 

Cumene is an important intermediate in the industrial production of phenol, acetone and a-methylstyrene. The large-scale production of cumene is based on the alkylation of benzene with propene over Friedel-Crafts [1] or phosphoric acid on silica catalysts [2]. Zeolites, namely ZSM-5 and ZSM-11, have also been shown to be potential catalysts for this process [3, 4]. However, the formation of cumene (isopropylbenzene. IPB) on this catalysts is accompanied by its isomerization to n-propylbenzene (NPB). The latter is considered as an undesired by-product with respect to further processing of cumene to phenol and acetone. Therefore, preventing the formation of NPB would enable the substitution of the current catalysts used in the industrial process by ZSM-5 or ZSM-11 type solid acids which have major advantages in terms of environmental protection, safety, and avoidance of corrosion. 

Change of different tubes and valves within the turbine hall Better material, reduction of iron entry into the reactor pressure vessel, avoidance of corrosion 1981, 1982... 

Strict control of purity relies on the avoidance of corrosion in the steam-distribution system and on chemical treatment of the feed water or steam condensate [15]. Treatment chemicals may include ... 

For jet fuels, the elimination of free water using filters and coalescers by purging during storage, and the limit of 5 ppm dissolved water are sufficient to avoid incidents potentially attributable to water contamination formation of micro-crystals of ice at low temperature, increased risk of corrosion, growth of micro-organisms. 

Gas leaving the converter is normally cooled to 180—250°C using boiler feedwater in an "economizer." This increases overall plant energy recovery and improves SO absorption by lowering the process gas temperature entering the absorption tower. The process gas is not cooled to a lower temperature to avoid the possibiUty of corrosion from condensing sulfuric acid originating from trace water in the gas stream. In some cases, a gas cooler is used instead of an economizer. 

Ferric sulfate (commercial product Fe2 (8O4 )3-H20) contains a minimum of 20 wt % iron(lll). It is available only as a soHd, which must be dissolved immediately before use. The solution must be kept concentrated to avoid premature hydrolysis and precipitation of Fe(OH)2. Such concentrated solutions have low pH values and, thus, prevent hydrolysis but are very corrosive. Containers must therefore be coated with or be constmcted of corrosion-proof materials. 

The hydrocarbon gas feedstock and Hquid sulfur are separately preheated in an externally fired tubular heater. When the gas reaches 480—650°C, it joins the vaporized sulfur. A special venturi nozzle can be used for mixing the two streams (81). The mixed stream flows through a radiantly-heated pipe cod, where some reaction takes place, before entering an adiabatic catalytic reactor. In the adiabatic reactor, the reaction goes to over 90% completion at a temperature of 580—635°C and a pressure of approximately 250—500 kPa (2.5—5.0 atm). Heater tubes are constmcted from high alloy stainless steel and reportedly must be replaced every 2—3 years (79,82—84). Furnaces are generally fired with natural gas or refinery gas, and heat transfer to the tube coil occurs primarily by radiation with no direct contact of the flames on the tubes. Design of the furnace is critical to achieve uniform heat around the tubes to avoid rapid corrosion at "hot spots."... 

Valve Trim Various alloys are available for valve parts such as seats, disks, and stems which must retain smooth finish For successful operation. The problem in seat materials is fivefold (1) resistance to corrosion by the fluid handled and to oxidation at high temperatures, (2) resistance to erosion by suspended solids in the fluid, (3) prevention of galling (seizure at point of contact) by differences in material or hardness or Both, (4) maintenance of high strength at high temperature, and (5) avoidance of distortion. 

Volume of Solution Volume of the test solution should be large enough to avoid any appreciable change in its corrosiveness through either exhaustion of corrosive constituents or accumulation of corrosion produces that might affect further corrosion. 

Turbine-Blade Cooling The turbine inlet temperatures of gas turbines have increased considerably over the past years and will continue to do so. This trend has been made possible by advancement in materials and technology, and the use of advanced turbine bladecooling techniques. The olade metal temperature must be kept below 1400° F (760° C) to avoid hot corrosion problems. To achieve this cooling air is bled from the compressor and is directed to the stator, the rotor, and other parts of the turbine rotor and casing to provide adequate cooling. The effect of the coolant on the aerodynamic, and thermodynamics depends on the type of cooling involved, the temperature of the coolant compared to the mainstream temperature, the location and direction of coolant injection, and the amount of coolant. 

All areas of the cooling water system where a specific form of damage is likely to be found are described. The corrosion or failure causes and mechanisms are also described. Especially important factors influencing the corrosion process are listed. Detailed descriptions of each failure mode are given, along with many common, and some not-so-common, case histories. Descriptions of closely related and similarly appearing damage mechanisms allow discrimination between failure modes and avoidance of common mistakes and misconceptions. 

Different microstructural regions in a material which has an almost uniform composition can also lead to the formation of corrosion cells (e.g., in the vicinity of welds). Basically, corrosion cells can be successfully overcome by cathodic protection. However, in practice, care has to be taken to avoid electrical shielding by large current-consuming cathode surfaces by keeping the area as small as possible. In general, with mixed installations of different metals, it must be remembered that the protection potentials and the protection range depend on the materials (Section 2.4). This can restrict the use of cathodic protection or make special potential control necessary. 

Ten percent of the anode mass is calculated for aluminum ships. The anode supports must also be of aluminum in order to allow them to be welded and to avoid bimetallic corrosion. 

Avoid, if possible, the use of corrosive or otherwise hazardous sampling media. 

The target composition of the undesirable species in each MSA is assigned by the designer based on the specific circumstances of the application. The nature of such circumstances may be physical (e.g., maximum solubility of the pollutant in the MSA), technical (e.g., to avoid excessive corrosion, viscosity or fouling), environmental (e.g., to comply with environmental regulations), safety (e.g., to stay away from flammability limits), or economic (e.g., to optimize the cost of subsequent regeneration of the MSA). 

Pipe, valve, and fittings tables must specify which size of each class of pipe is threaded, flanged, or socket welded. ANSI B31.3 provides no specific guidance except that it suggests that threads be avoided where corrosion, severe erosion, or cyclic loading is anticipated. 

On the basis of avoiding acid corrosion and obtaining required standby choose the number of boilers required and their relative sizes. Equally sized boilers should be used except where the provision of domestic hot water in summer requires one smaller boiler. Table 27.7 gives suggested relative sizes based on turndown to 30 per cent. 

Where the feed contains a large proportion of treated water, softening is a minimum requirement and the raw water quality dictates whether a more sophisticated form of external treatment would be preferable. If the water has a high alkalinity it calls for de-alkalization and base exchange. De-ionization is the ideal water treatment, but is usually avoided if possible because of its cost and use of corrosive chemicals. Membrane processes giving partial de-ionization are not normally installed at present, but are certain to become important in the future. 

Steel is the most common constructional material, and is used wherever corrosion rates are acceptable and product contamination by iron pick-up is not important. For processes at low or high pH, where iron pick-up must be avoided or where corrosive species such as dissolved gases are present, stainless steels are often employed. Stainless steels suffer various forms of corrosion, as described in Section 53.5.2. As the corrosivity of the environment increases, the more alloyed grades of stainless steel can be selected. At temperatures in excess of 60°C, in the presence of chloride ions, stress corrosion cracking presents the most serious threat to austenitic stainless steels. Duplex stainless steels, ferritic stainless steels and nickel alloys are very resistant to this form of attack. For more corrosive environments, titanium and ultimately nickel-molybdenum alloys are used. 

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