Headspace-solid-phase

Figure 11.14 Analysis of amphetamines by GC-NPD following HS-SPME exti action from human hair (a) Normal hair (b) normal hair after addition of amphetamine (1.5 ng) and methamphetamine (16.1 ng) (c) hair of an amphetamine abuser. Peak identification is as follows 1, a-phenethylamine (internal standard) 2, amphetamine 3, methamphetamine 4, N-propyl-/3-phenethyamine (internal standard). Reprinted from Journal of Chronatography, B 707,1. Koide et ai, Determination of amphetamine and methamphetamine in human hair by headspace solid-phase microextraction and gas cliromatography with niti ogen-phosphoms detection, pp. 99 -104, copyright 1998, with permission from Elsevier Science.

Z. Zhang and J. Pawlyszin, Headspace solid-phase microexti action , Anal. Chem. 65 1843-1852(1993). 

I. Koide, O. Noguclii, K. Okada, A. Yokoyama, H. Oda, S. Yamamoto and H. Kataoka, Detemination of amphetamine and methamphetamine in human hak by headspace solid-phase microexti action and gas cliromatogi aphy with niti ogen-phosphorus detection , J. Chromatogr. B707 99-104(1998). 

R. B. Gaines, E. B. Ledford-Jr and J. D. Stuait, Analysis of water samples for ti ace levels of oxygenated and aromatic compounds using headspace solid-phase microexti action and comprehensive two-dimensional gas clnomatography , ]. Microcolumn Sep. 10 597-604(1998). 

Lu, G. et al.. Quantitative determination of geosmin in red beets (Beta vulgaris L.) using headspace solid-phase microextraction, J. Agric. Food Chem., 51, 1021, 2003. 

Applications The potential of a variety of direct solid sampling methods for in-polymer additive analysis by GC has been reviewed and critically evaluated, in particular, static and dynamic headspace, solid-phase microextraction and thermal desorption [33]. It has been reported that many more products were identified after SPME-GC-MS than after DHS-GC-MS [35], Off-line use of an amino SPE cartridge for sample cleanup and enrichment, followed by TLC, has allowed detection of 11 synthetic colours in beverage products at sub-ppm level [36], SFE-TLC was also used for the analysis of a vitamin oil mixture [16]. 

HS-SPME Headspace solid-phase INAA Instrumental neutron activation... 

Classification of wines according to the grape variety succeeds better, in general, because there are many more typical bouquet components (several hundreds) than mineral and trace elements being typical for the origin of wine. The organic compounds can be analyzed easily and reliably by Headspace Solid-Phase Microextraction Capillary Gas Chromatography and afterwards used for classification (De la Calle et al. [1998]). An example... 

De la Calle D, Reichenbacher M, Danzer K, Hurlbeck C, Bartzsch C, Feller K-H (1998) Analysis of wine bouquet components using headspace solid-phase microextractioncapillary gas chromatography. J High Resol Chromatogr 21 373... 

S. Hamm, J. Bleton, A. Tchapla, Headspace solid phase microextraction for screening for the presence of resins in Egyptian archaeological samples, Journal of Separation Science, 27,235 243 (2004). 

A. Lattuati Derieux, S. Thao, J. Langlois, M. Regert, First results on headspace solid phase microextraction gas chromatography/mass spectrometry of volatile organic compounds emitted by wax objects in museums, Journal of Chromatography A, 1187, 239 249 (2008). 

Headspace solid phase microextraction (HS-SPME). With this extraction technique, it is possible to concentrate volatile compounds thus allowing their detection even at trace levels, as in the case of volatile and semi-volatile terpenes in archaeological findings [7,31]. Chapter 10 outlines how resinous materials are investigated using HS-SPME-GC/MS. 

M. Regert, V. Alexandre, N. Thomas, A. Lattuati Derieux, Molecular characterisation of birch bark tar by headspace solid phase microextraction gas chromatography mass spec trometry a new way for identifying archaeological glues, J. Chromatogr., A, 1101, 245 253 (2006). 

E. E. Stashenko, J. R. Martinez, Sampling volatile compounds from natural products with headspace/solid phase micro extraction, J. Biochem. Biophys. Methods, 70, 235 242 (2007). 

Y. F. Sha, S. Chen, G. L. Duan, Rapid determination of tramadol in human plasma by headspace solid phase microextraction and capillary gas chromatography mass spectrometry, J. Pharrn. Biomed. Anal., 37, 143 147 (2005). 

G. A. Mills, V. Walker, Headspace solid phase microextraction procedures for gas chromato graphic analysis of biological fluids and materials, J. Chromatogr. A, 902, 267 287 (2000). 

A. Lattuati Derieux, S. Bonnassies Termes, B. Lavedrine, Characterisation of compounds emitted during natural and artificial ageing of a hook. Use of headspace solid phase microex traction/gas chromatography/mass spectrometry, J. Cult. Her., 7, 123 133 (2006). 

S. Hamm, E. Lesellier, J. Bleton, A. Tchapla, Optimization of headspace solid phase micro extraction for gas chromatography/mass spectrometry analysis of widely different volatility and polarity terpenoids in olibanum, J. Chromatogr. A, 1018, 73 83 (2003). 

Z. Zhang, J. Pawliszyn, Analysis of organic compounds in environmental samples using headspace solid phase microextraction, J. High Resol. Chromatogr., 16, 689 692 (1993). 

D. Zabaras, S. G. Wyllie, Quantitative analysis of terpenoids in the gas phase using headspace solid phase microextraction (HS SPME), Flavour Fragr. J., 16, 411 416 (2001). 

J. Ai, Headspace solid phase microextraction. Dynamics and quantitative analysis before reaching a partition equilibrium, Anal. Chem., 69, 3260 (1997). 

Zhang, Z. and Pawliszyn, J. (1993) Headspace solid-phase microextraction. Anal.Chem. 65, 1843-1852. 

Bicchi, C., Cordero, C., Liberto, E., Rubiolo, P. and Sgorbini, B. (2004) Automated headspace solid-phase dynamic extraction to analyse the volatile fraction of food matrices. J. Chromatogr. A 1024, 217-226. 

Musshoff, F., Lachenmeier, D.W., Kroener, L. and Madea, B. (2002) Automated headspace solid-phase dynamic extraction for the determination of amphetamines and synthetic designer drugs in hair samples. J. Chromatogr. A 958, 231-238. 

Wei M-C, Jen J-F. Determination of chlorophenols in soil samples by microwave-assisted extraction coupled to headspace solid-phase microextraction and gas chromatography-electro-capture detection. J. Chromatogr. A 2003 1012 111-118. 

Eriksson M, Faldt J, Dalhammar G, Borg-Karlson A-K. Determination of hydrocarbons in old creosote contaminated soil using headspace solid phase microextraction and GC-MS. Chemosphere 2001 44 71641-71648. 

Koide I, Noguchi O, Okada K, Yokoyama A, Oda H, et al. 1998. Determination of amphetamine and methamphetamine in human hair by headspace solid-phase microextraction and gas chromatography with nitrogen—phosphorus detection. J Chromatogr B 707 99. 

Wilson JB (1970) Adjustment in the smoke pH of Winston cigarettes. Available from http // ltdlimages,library,ucsf,edu/imagesm/m/e/z/mez65d00/Smez65d00.pdf. Accessed 17 July 2007 Zhang Z, Pawliszyn J (1993) Headspace solid phase microextraction. Anal Chem 65 1843-1852... 

Source Identified among 139 volatile compounds identified in cantaloupe Cucumis melo wur. reticulates cv. Sol Real) using an automated rapid headspace solid phase microextraction method (Beaulieu and Grimm, 2001). 

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