Headspace-solid-phase volatiles

A. Lattuati Derieux, S. Thao, J. Langlois, M. Regert, First results on headspace solid phase microextraction gas chromatography/mass spectrometry of volatile organic compounds emitted by wax objects in museums, Journal of Chromatography A, 1187, 239 249 (2008). 

Headspace solid phase microextraction (HS-SPME). With this extraction technique, it is possible to concentrate volatile compounds thus allowing their detection even at trace levels, as in the case of volatile and semi-volatile terpenes in archaeological findings [7,31]. Chapter 10 outlines how resinous materials are investigated using HS-SPME-GC/MS. 

E. E. Stashenko, J. R. Martinez, Sampling volatile compounds from natural products with headspace/solid phase micro extraction, J. Biochem. Biophys. Methods, 70, 235 242 (2007). 

S. Hamm, E. Lesellier, J. Bleton, A. Tchapla, Optimization of headspace solid phase micro extraction for gas chromatography/mass spectrometry analysis of widely different volatility and polarity terpenoids in olibanum, J. Chromatogr. A, 1018, 73 83 (2003). 

Bicchi, C., Cordero, C., Liberto, E., Rubiolo, P. and Sgorbini, B. (2004) Automated headspace solid-phase dynamic extraction to analyse the volatile fraction of food matrices. J. Chromatogr. A 1024, 217-226. 

Source Identified among 139 volatile compounds identified in cantaloupe Cucumis melo wur. reticulates cv. Sol Real) using an automated rapid headspace solid phase microextraction method (Beaulieu and Grimm, 2001). 

Identified as one of 140 volatile constituents in used soybean oils collected from a processing plant that fried various beef, chicken, and veal products (Takeoka et al., 1996). Also identified among 139 volatile compounds identified in cantaloupe Cucumis melo vslV. reticulates cm. Sol Real) using an automated rapid headspace solid phase microextraction method (Beaulieu and Grimm, 2001). 

Jung, D.-M. and Ebeler, S.E. Headspace solid-phase microextraction method for the study of the volatility of selected flavor compounds, J. Agric. Food Chem., 51 (1) 200-205, 2003. 

Excerpt 4C is taken from an article in Analytical Chemistry. Headspace solid-phase microextraction (HSSPME) is coupled with GC to quantify polychlorinated biphenyls (RGBs) in milk. The RGBs are volatilized out of the liquid phase (milk) into the gas phase (headspace) and concentrated on an SPME fiber. The concentrated RGBs on the fiber are then injected into the GG. 

HSSPIVIE Headspace solid-phase microextraction a preconcentration technique that concentrates volatile analytes on a fiber than can be inserted directly into a GC... 

Williams, A., Ryan, D., Olarte Girasca, A., Marriot, P, Pang, E. (2005) Analysis of strawberry volatiles i ing comprehensive two-dimensional gas chromatography with headspace solid-phase microextraction. J. Chromatogr. B 817 97-107. 

F. Vilaplana, M. Martinez-Sanz, A. Ribes-Greus, and S. Karlsson, Emission pattern of semi-volatile organic compounds from recycled styrenic polymers using headspace solid-phase microextraction gas chromatography - mass spectrometry, J. Chromatogr. A, In Press, Accepted Manuscript -, 2010. 

Jelen, H.H., Obuchowska, M., Zawirska-Wojtasiak, R., and Wasowicz, E. 2000. Headspace solid-phase microextraction use for the characterization of volatile compounds in vegetable oils of different sensory quality. J. Agric. Food Chem. 48, 2360-2367. 

Tolgyessy, R and J. Hrivnak. 2006. Analysis of volatiles in water using headspace solid-phase microcolumn extraction. J. Chromatogr. A 1127 295-297. 

Lopez, R., Lapena, A.C., Cacho, J., and Ferreira, V. (2007). Quantitative determination of wine highly volatile sulfur compounds by using automated headspace solid-phase microextraction and gas chromatography-pulsed flame photometric detection - Critical study and optimization of a new procedure. J. Chromatogr. A., 1143, 8-15. 

Mejias, R.C., Matin, R.N., Moreno, M.V.G., Barroso, C.G. (2003). Optimisation of headspace solid-phase microextraction for the analysis of volatile phenols in wine. J. Chromatogr. A, 995, 11-20. 

Headspace solid-phase microextraction (HS-SPME) is a rapid and solvent-free modification of the SPME technique in which a fine fused silica fiber with a polymeric coating is inserted into a headspace gas to extract organic compounds and directly transfer them into the injector of a gas chromatograph for thermal desorption and analysis. In this technique, the quantity of compounds extracted onto the fiber depends on the polarity and thickness of the stationary phase as well as on extraction time and concentration of volatiles in the sample. 

Figure 5.12 Temperature effect in the HS-SPME adsorption of the wine CFSV on DVB/CAR/PDMS fiber. (Reprinted from Rapid Communications in Mass Spectrometry 21, Fedrizzi et al., Concurrent quantification of light and heavy sulphur volatiles in wine by headspace solid-phase microextraction coupled with gas chro-matography/mass spectrometry, p. 711, Copyright 2007, with permission from John Wiley Sons, Ltd)...

Mestres, M., Busto, O. and Gulasch, J. (2002) Application of headspace solid-phase microextraction to the determination of sulphur compounds with low volatility in wines,/. Chromatogr. A, 945(1-2), 211-219. 

D.J. Tranthim-Fryer, R.C. Hansson, K.W. Norman, Headspace/solid-phase microexlraction/gas chromatography-mass spectrometry a screening technique for the recovery and identification of volatile organic compounds (VOC s) in postmortem blood and viscera samples, J. Forensic Sci., 46, 934-946 (2001). 

J. Liu, H. Kenji, S. Kashimura, M. Kashiwagi, T. Hamanaka, A. Miyoshi, M. Kageura, Headspace solid-phase microextraction and gas chromatographic-mass spectrometric screening for volatile hydrocarbons in blood, J. Chromatogr. B, 748, 1-9 (1997). 

Abstract A presentation is given of headspace (HS) extraction and headspace solid-phase microextraction (HS-SPME) techniques and their combination with multiple headspace (MHS) extraction to enable quantitative determination of volatiles in solid polymer matrixes. As an example, the development of HS, HS-SPME, and MHS-SPME methods for... 

Abalos, M., Prieto, X., and Bayona, J. M., Determination of volatile alkyl sulfides in wastewater by headspace solid-phase microextraction followed by gas chromatography-mass spectrometry,... 

Abalos, M., Bayona, J. M., and Pawliszyn, J., Development of a headspace solid-phase microextraction procedure for the determination of free volatile fatty acids in waste waters, J. Chromatogr. A, 873, 107-115, 2000. 

Llompart, M., Li, K., and Fingas, M., Headspace solid phase microextraction (HSSPME) for the determination of volatile and semivolatile pollutants in soil, Talanta, 48, 451-459, 1999. 

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