Headspace solid phase microextraction-gas chromatography-mass spectrometry

A. Lattuati Derieux, S. Thao, J. Langlois, M. Regert, First results on headspace solid phase microextraction gas chromatography/mass spectrometry of volatile organic compounds emitted by wax objects in museums, Journal of Chromatography A, 1187, 239 249 (2008). 

M. Regert, V. Alexandre, N. Thomas, A. Lattuati Derieux, Molecular characterisation of birch bark tar by headspace solid phase microextraction gas chromatography mass spectrometry A new way for identifying archaeological glues, J. Chromatogr. A, 1101, 245 253 (2006). 

F. Vilaplana, M. Martinez-Sanz, A. Ribes-Greus, and S. Karlsson, Emission pattern of semi-volatile organic compounds from recycled styrenic polymers using headspace solid-phase microextraction gas chromatography - mass spectrometry, J. Chromatogr. A, In Press, Accepted Manuscript -, 2010. 

Camara, J. S., Alves, M. A., and Marques, J. C. (2006c). Development of headspace solid-phase microextraction-gas chromatography-mass spectrometry methodology for analysis of terpenoids in Madeira wines. Anal. Chim. Acta 555,191-200. 

Carrillo, J.D., Tena, M.T. (2007). Determination of ethylphenols in wine by in situ derivatisa-tion and headspace solid-phase microextraction-gas chromatography-mass spectrometry. Anal. Bioanal. Chem., Doi 10.1007/s00216-006-1086-x. 

Begala, M., Corda, L., Podda, G., Fedrigo, M.A., and Traldi, P. (2002). Headspace solid-phase microextraction gas chromatography/mass spectrometry in the analysis of the aroma constituents of Cannonau of Jerzu wine, Rapid Commun. Mass Spectrom., 16,1086-1091. 

Pellati, F., S. Benvenuti, F. Yoshizaki, D. BerteUl,andM. C. Rossi, 2005. Headspace solid-phase microextraction-gas chromatography mass spectrometry analysis of the volatile compounds of Evodia species fruits. J. Chromaloer. A. 1087 265-273. 

Analysis of Microbial Volatile Metabolites Responsible for Musty-Earthy Odors by Headspace Solid-Phase Microextraction Gas Chromatography/Mass Spectrometry... 

Investigation of volatile compounds in two raspberry cultivars by two headspace techniques solid-phase microextraction/gas chromatography-mass spectrometry (SPME/GC-MS) and proton-transfer reaction-mass spectrometry (PTR-MS). Journal of Agricultural and Food Chemistry, 57,4011-4018. 

Salado-Petinal, C., M. Garcia-Chao, M. Llompart, C. Garcia-Jares, and R. Cela. 2006. Headspace solid-phase microextraction gas chromatography tandem mass spectrometry for the determination of bromi-nated flame retardants in environmental solid samples. Anal. Bioanal. Chem. 385 637-644. 

Distillation. Essential Oils. Extraction Solvent Extraction Principles Solid-Phase Extraction Solid-Phase Microextraction. Gas Chromatography Detectors Mass Spectrometry Chiral Separations. Headspace Analysis Static Purge and Trap. Mass Spectrometry Principles Selected Ion Monitoring. Quality Assurance Quality Control. Sensors Overview. 

Y. F. Sha, S. Chen, G. L. Duan, Rapid determination of tramadol in human plasma by headspace solid phase microextraction and capillary gas chromatography mass spectrometry, J. Pharrn. Biomed. Anal., 37, 143 147 (2005). 

Moens, L., DeSmaele, T., Dams, R., VandenBroeck, R and Sandra, P. (1997) Sensitive, simultaneous determination of organomercury, -lead, and -tin compounds with headspace solid phase microextraction capillary gas chromatography combined with inductively coupled plasma mass spectrometry. Anal. Chem., 69, 1604—1611. 

G.L. Kimm, G.L. Hook and P.A. Smith, Application of headspace solid-phase microextraction and gas chromatography-mass spectrometry for detection of the chemical warfare agent bis(2-chloroethyl) sulfide in soil, J. Chromatogr. A, 971, 185-191 (2002). 

J. Vercauteren, A. De Meester, T. De Smaele, F. Vanhaecke, L. Moens., R. Dams, P. Sandra, Headspace solid-phase microextraction-capillary gas chromatography-ICP mass spectrometry for the determination of the organotin pesticide fentin in environmental samples, J. Anal. Atom. Spectrom., 15 (2000), 651D656. 

Fediizzi, B., Versini, G., Lavagnini, I., Nicolini, G., and Magno, F. (2007). Gas chromatography-mass spectrometry determination of 3-mercaptohexan-l-ol and 3-mercaptohexyl acetate in wine A comparison of headspace solid phase microextraction and solid phase extraction methods. Anal. Chim. Acta, 596, 291-297. 

Davarani, S.S.H., Masoomi, L., Banitaba, M.H., Zhad, H.R.L.Z., Sadeghi, O., Samiei, A. Determination of N-nitrosodiethanolamine in cosmetic products by headspace solid phase microextraction using a novel aluminum hydroxide grafted fused silica fiber followed by gas chromatography-mass spectrometry analysis. Talanta 105, 347-353 (2013)... 

Solid Phase MicroExtraction (SPME) is a solvent-free sample preparation method based on the adsorption of analytes directly from an aqueous sample onto a coated fused-silica fiber. Headspace SPME was used in combination with gas chromatography-mass spectrometry/ selective ion monitoring (GC/MS-SIM) to analyze for TCA in wine. 

Lizarraga, E., Irigoyen, A., Belsue, V. and Gonzalez-Penas, E. (2004) Determination of chloroanisole compounds in red wine by headspace solid-phase microextraction and gas chromatography-mass spectrometry,/. Chromatogr. A, 1052 (1-2), 145-149. 

Aprea, E., Biasioli, F., Carlin, S., Versini, G., Mark, T. and Gasperi, F. (2007) Rapid white truffle headspace analysis by proton transfer reaction-mass spectrometry and comparison with solid-phase microextraction coupled with gas chromatography/mass spectrometry, Rapid Commun. Mass Sp., 21(16), 2564-2572. 

Giordano, L., Calabrese, R., Davoli, E., and Rotilio, D. (2003). Quantitative analysis of 2-furfural and 5-methylfurfural in different Italian vinegars by headspace solid-phase microextraction coupled to gas chromatography-mass spectrometry using isotope dilution. J. Chromatogr. A 1017,141-149. 

Biological specimen extraction can be accomplished by liquid-liquid, solid-phase or solid-phase microextraction with subsequent detection of GHB or GBL by gas chromatography-mass spectrometry (GC-MS) using electron ionization (El), positive or negative chemical ionization (CI) or gas chromatography with flame ionization detection (GC-FID). LeBeau et al. (1999) describes a method that employs two ahquots of specimen. The first is converted to GBL with concentrated sulfuric acid while the second is extracted without conversion. A simple liquid-liquid methylene chloride extraction was utilized, and the ahquots were then screened by GC-FID without derivatization. Specimens that screened positive by this method were then re-aliquoted and subjected to the same extraction with the addition of the deuterated analog of GBL. The extract was then analyzed by headspace GC-MS in the full-scan mode. Quantitation was performed by comparison of the area of the... 

Prison, G.,Tedeschi, L, Maietti, S. and Ferrara, S.D. (1998). Determination of gamma-hydroxybutyric Acid (GHB) in plasma and urine by headspace solid-phase microextraction (SPME) and gas chromatography-positive ion chemical ionization-mass spectrometry. In Proceedings of the 1998 Joint Society of Forensic Toxicologists and the International Association of Forensic Toxicologists SOFT/TIAFT International Meeting, Spiehler, V. (Ed.), pp. 394 404. 

Francioli, S., Guerra, M., Lopez-Tamames, E., Guadayoi, J.M., and Caixach, J. (1999). Aroma of sparkling wines by headspace/solid phase microextraction and gas chromatography/mass spectrometry, Am../. Enol. Vitic, 50(4), 404-408. 

Abalos, M., Prieto, X., and Bayona, J. M., Determination of volatile alkyl sulfides in wastewater by headspace solid-phase microextraction followed by gas chromatography-mass spectrometry,... 

Present-day monodimensional (ID), open-tubular capillary column gas chromatography (GC) techniques can provide satisfactory analytical results for food samples of low complexity, but when challenged with moderate to highly complex matrices, these techniques often fail, as will be shown later in this chapter. As a typical example, the headspace solid-phase microextraction (HS-SPME) GC equipped with mass spectrometry (GC-MS) result for a sample of Arabica roasted coffee beans is shown in Figure 1 [1]. 

Monoterpene and sesquiterpene hydrocarbons of virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry. Journal of Chromatography A, Vol.1125, No.l, (August 2006), pp. 117-123, ISSN 0021-9673... 

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