Headspace solid phase microextraction-gas

A. Lattuati Derieux, S. Thao, J. Langlois, M. Regert, First results on headspace solid phase microextraction gas chromatography/mass spectrometry of volatile organic compounds emitted by wax objects in museums, Journal of Chromatography A, 1187, 239 249 (2008). 

M. Regert, V. Alexandre, N. Thomas, A. Lattuati Derieux, Molecular characterisation of birch bark tar by headspace solid phase microextraction gas chromatography mass spec trometry a new way for identifying archaeological glues, J. Chromatogr., A, 1101, 245 253 (2006). 

F. Vilaplana, M. Martinez-Sanz, A. Ribes-Greus, and S. Karlsson, Emission pattern of semi-volatile organic compounds from recycled styrenic polymers using headspace solid-phase microextraction gas chromatography - mass spectrometry, J. Chromatogr. A, In Press, Accepted Manuscript -, 2010. 

Salado-Petinal, C., M. Garcia-Chao, M. Llompart, C. Garcia-Jares, and R. Cela. 2006. Headspace solid-phase microextraction gas chromatography tandem mass spectrometry for the determination of bromi-nated flame retardants in environmental solid samples. Anal. Bioanal. Chem. 385 637-644. 

Camara, J. S., Alves, M. A., and Marques, J. C. (2006c). Development of headspace solid-phase microextraction-gas chromatography-mass spectrometry methodology for analysis of terpenoids in Madeira wines. Anal. Chim. Acta 555,191-200. 

Carrillo, J.D., Tena, M.T. (2007). Determination of ethylphenols in wine by in situ derivatisa-tion and headspace solid-phase microextraction-gas chromatography-mass spectrometry. Anal. Bioanal. Chem., Doi 10.1007/s00216-006-1086-x. 

Martorell, N., Marti, M.P., Mestres, M., Busto, O. and Guasch, J. (2002) Determination of 4-ethylguaiacol and 4-ethylphenol in red wines using headspace-solid-phase microextraction-gas chromatography,/. Chromatogr. A, 975, 349-354. 

Begala, M., Corda, L., Podda, G., Fedrigo, M.A., and Traldi, P. (2002). Headspace solid-phase microextraction gas chromatography/mass spectrometry in the analysis of the aroma constituents of Cannonau of Jerzu wine, Rapid Commun. Mass Spectrom., 16,1086-1091. 

Boutou, S. Chatonnet, P. (2007) Rapid headspace solid-phase microextraction/gas chromatographic/mass spectrometiic assay for the quantitative determination of some of the main odorants causing off-flavours in wine. Journal of Chromatography A Vol. 1141, pp. 1-9... 

Femandez-Alvarez, M. Llompart, M. Lamas, J.P. Lores, M. Garcia-Jares, C. Cela, R. Dagnac, T. Simultaneous determination of traces of pyrethroids, organochlorinated and other main plants protection agents in agricultural soils by headspace solid-phase microextraction-gas chromatography. J. Chromatogr. A, 2008,1188, 154—163. 

Bicchi, C., C. Cordero, and P. Rubiolo, 2000b. In uence of bre coating in headspace solid-phase microextraction-gas chromatographic analysis of aromatic and medicinal plants. 2 ... 

Pellati, F., S. Benvenuti, F. Yoshizaki, D. BerteUl,andM. C. Rossi, 2005. Headspace solid-phase microextraction-gas chromatography mass spectrometry analysis of the volatile compounds of Evodia species fruits. J. Chromaloer. A. 1087 265-273. 

I. Multivariate Anaiysis Using Dynamic Headspace Solid-Phase Microextraction Gas Chromatography Olfactometry... 

Figure 11.14 Analysis of amphetamines by GC-NPD following HS-SPME exti action from human hair (a) Normal hair (b) normal hair after addition of amphetamine (1.5 ng) and methamphetamine (16.1 ng) (c) hair of an amphetamine abuser. Peak identification is as follows 1, a-phenethylamine (internal standard) 2, amphetamine 3, methamphetamine 4, N-propyl-/3-phenethyamine (internal standard). Reprinted from Journal of Chronatography, B 707,1. Koide et ai, Determination of amphetamine and methamphetamine in human hair by headspace solid-phase microextraction and gas cliromatography with niti ogen-phosphoms detection, pp. 99 -104, copyright 1998, with permission from Elsevier Science.

Classification of wines according to the grape variety succeeds better, in general, because there are many more typical bouquet components (several hundreds) than mineral and trace elements being typical for the origin of wine. The organic compounds can be analyzed easily and reliably by Headspace Solid-Phase Microextraction Capillary Gas Chromatography and afterwards used for classification (De la Calle et al. [1998]). An example... 

Y. F. Sha, S. Chen, G. L. Duan, Rapid determination of tramadol in human plasma by headspace solid phase microextraction and capillary gas chromatography mass spectrometry, J. Pharrn. Biomed. Anal., 37, 143 147 (2005). 

G. A. Mills, V. Walker, Headspace solid phase microextraction procedures for gas chromato graphic analysis of biological fluids and materials, J. Chromatogr. A, 902, 267 287 (2000). 

D. Zabaras, S. G. Wyllie, Quantitative analysis of terpenoids in the gas phase using headspace solid phase microextraction (HS SPME), Flavour Fragr. J., 16, 411 416 (2001). 

Wei M-C, Jen J-F. Determination of chlorophenols in soil samples by microwave-assisted extraction coupled to headspace solid-phase microextraction and gas chromatography-electro-capture detection. J. Chromatogr. A 2003 1012 111-118. 

Koide I, Noguchi O, Okada K, Yokoyama A, Oda H, et al. 1998. Determination of amphetamine and methamphetamine in human hair by headspace solid-phase microextraction and gas chromatography with nitrogen—phosphorus detection. J Chromatogr B 707 99. 

Excerpt 4C is taken from an article in Analytical Chemistry. Headspace solid-phase microextraction (HSSPME) is coupled with GC to quantify polychlorinated biphenyls (RGBs) in milk. The RGBs are volatilized out of the liquid phase (milk) into the gas phase (headspace) and concentrated on an SPME fiber. The concentrated RGBs on the fiber are then injected into the GG. 

Ryan, D., Watkins, R, Smith,)., Allen, M., Marriott, P. (2005) Analysis of methoxypyrazines in wine using headspace solid phase microextraction with isotope dilution and comprehensive two-dimensional gas chromatography. J. Sep. Sci. 28 1075-1082. 

Williams, A., Ryan, D., Olarte Girasca, A., Marriot, P, Pang, E. (2005) Analysis of strawberry volatiles i ing comprehensive two-dimensional gas chromatography with headspace solid-phase microextraction. J. Chromatogr. B 817 97-107. 

A. M. Carro, I. Neira, R. Rodil and R. A. Lorenzo, Speciation of mercury compounds by gas chromatography with atomic emission detection. Simultaneous optimisation of a headspace solid-phase microextraction and derivatisation procedure by use of chemometric techniques, Chro-matographia, 56(11/12), 2002, 733-738. 

R. B. Gaines, E. B. Ledford-Jr and J. D. Stuart, Analysis of water samples for trace levels of oxygenated and aromatic compounds using headspace solid-phase microextraction and comprehensive two-dimensional gas chromatography , J. Microcolumn Sep. 10 597-604 (1998). 

Moens, L., DeSmaele, T., Dams, R., VandenBroeck, R and Sandra, P. (1997) Sensitive, simultaneous determination of organomercury, -lead, and -tin compounds with headspace solid phase microextraction capillary gas chromatography combined with inductively coupled plasma mass spectrometry. Anal. Chem., 69, 1604—1611. 

G.L. Kimm, G.L. Hook and P.A. Smith, Application of headspace solid-phase microextraction and gas chromatography-mass spectrometry for detection of the chemical warfare agent bis(2-chloroethyl) sulfide in soil, J. Chromatogr. A, 971, 185-191 (2002). 

K. Takekawa, M. Oya, A. Kido and O. Suzuki, Analysis of cyanide in blood by headspace solid-phase microextraction (SPME) and capillary gas chromatography, Chromatographia, 47, 209-214 (1998). 

J. Vercauteren, A. De Meester, T. De Smaele, F. Vanhaecke, L. Moens., R. Dams, P. Sandra, Headspace solid-phase microextraction-capillary gas chromatography-ICP mass spectrometry for the determination of the organotin pesticide fentin in environmental samples, J. Anal. Atom. Spectrom., 15 (2000), 651D656. 

Fan, W.L., and Qian, M.C. (2005). Headspace solid phase microextraction and gas chromatography-olfactometry dilution analysis of young and aged Chinese Yanghe Daqu liquors. J. Agric. Food Chem., 53, 7931-7938. 

Fediizzi, B., Versini, G., Lavagnini, I., Nicolini, G., and Magno, F. (2007). Gas chromatography-mass spectrometry determination of 3-mercaptohexan-l-ol and 3-mercaptohexyl acetate in wine A comparison of headspace solid phase microextraction and solid phase extraction methods. Anal. Chim. Acta, 596, 291-297. 

Lopez, R., Lapena, A.C., Cacho, J., and Ferreira, V. (2007). Quantitative determination of wine highly volatile sulfur compounds by using automated headspace solid-phase microextraction and gas chromatography-pulsed flame photometric detection - Critical study and optimization of a new procedure. J. Chromatogr. A., 1143, 8-15. 

Prouteau, C., Schneider, R., Lucchese, Y., Nepveu, F, Renard, R., and Vaca-Garda, C. (2004). Improving headspace-solid-phase microextraction of 3-isobutyl-2-methoxypyrazine by experimental design with regard to stable isotope dilution gas chromatography-mass spectrometric analysis of wine. Anal. Chim. Acta, 513, 223-227. 

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