Glycol methacrylate

TABLE 16.9 Producers (TosoHaas) Specification of Fractionation Ranges of Ethylene Glycol/Methacrylate Copolymer-Based TSK PW Gels... [Pg.491]

Glycol methacrylates (and retention times [RTs]) ethylene glycol dimethacrylate (RT = 13 min), diethyleneglycol dimethacrylate (RT = 18 min), triethylene glycol dimethacrylate (RT = 22 min), and tetraethylene glycol dimethacrylate... [Pg.62]

PHEGMA poly[hexa(ethylene glycol) methacrylate]... [Pg.16]

Trialkylsilyl-protected oligo(ethylene glycol)methacrylates, 2- 2- (tert-butyldimethylsilyl)oxy]ethoxy ethyl methacrylate (1), and 2- 2-[2-[(ferf-butyldimethylsilyl)oxy] ethoxy] ethoxy ethyl methacrylate (2) (Scheme 7) were used for the synthesis of amphiphilic block copolymers by anionic poly-... [Pg.24]

ABC, ACB, and BAC triblock terpolymers, where A is PMMA, B is PDMAEMA, and C is poly[hexa(ethylene glycol)methacrylate], PHEGMA, were synthesized via GTP and sequential monomer addition [89]. The polymerizations were conducted in THF using MTS and TBABB as the initiator... [Pg.51]

The triblock terpolymer polypropylene oxide)-h-poly[2-(dimethylami-no)ethyl methacrylate]-b-poly[oligo(ethylene glycol) methacrylate], PPO-fc-PDMAEMA-fc-POEGMA, was prepared using the PPO macroinitiator followed by the addition of CuCl, HMTETA, and DMAEMA for the polymerization of the second block and finally OEGMA for the synthesis of the final product (Scheme 54) [128]. [Pg.70]

Becer CR, Hahn S, Fijten MWM, Thijs HML, Hoogenboom R, Schubert US (2008) Libraries of methacrylic acid and oligo(ethylene glycol) methacrylate copolymers with LCST behavior. J Polym Sci Part A Polym Chem 46 7138-7147... [Pg.14]

Lutz JF, Hoth A (2006) Preparation of ideal PEG analogues with a tunable thermosensitivity by controlled radical copolymerization of 2-(2-methoxyethoxy)ethyl methacrylate and oligo(ethylene glycol) methacrylate. Macromolecules 39 893-896... [Pg.61]

Tissue Preparation for Electron Microscopy. Tissues were fixed in 2% paraformaldehyde, 2.5% glutaraldehyde in phosphate buffer (0.1 M, pH 7.4) and 0.02% picric acid. They were then dehydrated in glycol methacrylate monomer and embedded in glycol methacrylate (GMA) (24). [Pg.445]

We have recently evaluated the ATRP of a wide range of hydrophilic monomers such as 2-sulfatoethyl methacrylate (SEM), sodium 4-vinylbenzoate (NaVBA), sodium methacrylate (NaMAA), 2-(dimethylamino)ethyl methacrylate (DMA), 2-(iV-morpholino)ethyl methacrylate (MEMA), 2-(diethylamino)ethyl methacrylate (DEA), oligo(ethylene glycol) methacrylate (OEGMA), 2-hydroxyethyl methacrylate (HEMA), glycerol monomethacrylate (GMA), 2-methacryl-oyloxyethyl phosphorylcholine (MPC), and a carboxybetaine-based methacrylate [CBMA]. Their chemical structures and literature references (which contain appropriate experimental details) are summarised in Table 1. [Pg.23]

Lee and Matsuda modified a segmented polyurethane film with a dithio-carbamate moiety and then initiated the polymerization of (ethylene glycol) methacrylate and N,N-dimethylacrylamide [35]. The resulting films were hy-drophihc and were shown to inhibit adhesion of platelets. Such films could be useful as anti-coagulant substrates for devices implanted in vivo. [Pg.53]

Succinimide-group-earrying latex particles are another versatile reactive support (12). The fraction of active succinimide groups on the particle surface was measured to be about 1% of succinimide monomer charged for the heterogeneous copolymerization with diethylene glycol methacrylate. [Pg.650]

Several other thermally responsive systems can be cited, such as poly- or oligo(ethylene glycol) methacrylate (OEGMA) derivatives [33 13], We recently showed that copolymers of 2-(2-methoxyethoxy)ethyl methacrylate (MEO2MA) and OEGMA exhibited a LCST in water that can be adjusted to physiological... [Pg.3]

Uses Methyl alcohol is a clear, colorless liquid with a slight alcoholic odor. It is used in the synthesis of formaldehyde, methylamine, ethylene glycol, methacrylates, and as an industrial solvent for a number of products (e.g., inks, resins, adhesives, dyes for straw hats). Methyl alcohol is an important ingredient commonly used to prepare grease and dirt remover. It also is used in the manufacture of photographic films, plastics, celluloid, textile soaps, wood stains, coated fabrics, paper coatings, artificial leather, and other industrial products. [Pg.229]

FIG. 14 Platelet adhesion to the PU films grafted with methoxy polyethylene glycol) methacrylates at different concentrations of chain transfer agent (c-cysteine). Ethylene glycol units in monomers ( ) 4, (O) 9, and ( ) 23. (From Ref. 74.)... [Pg.350]

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