Efficient recovery systems

The compound of the distinct three oxo processes, all rhodium-based, enables a highly efficient recovery system to be achieved. Figure 5.17 describes the TPPTS manufacture and its use for the preparation of the rhodium catalyst, using either freshly introduced Rh acetate or recycled Rh 2-ethylhexanoate. The recycle technique of the RCH/RP process and its performance is depicted earlier. Spent Rh-TPPTS solutions are worked-up (see Figures 5.18 and 5.19), the resulting TPPTS returns to the RCH/RP process. The rhodium portion passes also a work-up stage and is reformulated as Rh 2-ethylhexanoate. This Rh salt may serve all various oxo processes of the oxo loop and will compensate for possible Rh losses as mentioned earlier. 

In the second type of application, the Tomlinson recovery boiler is replaced by a safer and thermally more efficient recovery system, in which the oil produced by thermal treatment is used as plant fuel. This type of process is, in many respects, similar to the Hydropyrolysis Recovery Process developed by the St. Regis Paper Company, USA ( ), the essential difference being the use of a reducing atmosphere in the YTT process. 

Crouzel et al. 1987). There is, however, a problem with if it is to be of high specific activity. Special precautions regarding gas composition, construction material, and chemicals are needed (cf. Crouzel et al. 1987 Suzuki et al. 2000). The most reliable production of demands a deuteron beam at the cyclotron. If it is not available, the (p,n) reaction on highly enriched is utilized. An efficient recovery system for the enriched target gas must then be incorporated in the target system. 

The compound of the three distinct 0x0 processes, all rhodium-based, enables a highly efficient recovery system to be achieved (Fig. 12.21). 

Asahi Chemical Industries (ACl, Japan) are now the leading producers of cuprammonium rayon. In 1990 they made 28,000 t/yr of filament and spunbond nonwoven from cotton ceUulose (65). Their continuing success with a process which has suffered intense competition from the cheaper viscose and synthetic fibers owes much to their developments of high speed spinning technology and of efficient copper recovery systems. Bemberg SpA in Italy, the only other producer of cuprammonium textile fibers, was making about 2000 t of filament yam in 1990. 

The water—carbon slurry formed in the quench vessel is separated from the gas stream and flows to the carbon recovery system needed for environmental reasons and for better thermal efficiency. The recovered carbon is recycled to the reactor dispersed in the feedstock. If the fresh feed does not have too high an ash content, 100% of the carbon formed can be recycled to extinction. 

Recovery and Purification. AH processes for the recovery and refining of maleic anhydride must deal with the efficient separation of maleic anhydride from the large amount of water produced in the reaction process. Recovery systems can be separated into two general categories aqueous- and nonaqueous-based absorption systems. Solvent-based systems have a higher recovery of maleic anhydride and are more energy efficient than water-based systems. 

Off-Gas Treatment. Before the advent of the shear, the gases released from the spent fuel were mixed with the entire dissolver off-gas flow. Newer shear designs contain the fission gases and provide the opportunity for more efficient treatment. The gaseous fission products krypton and xenon are chemically inert and are released into the off-gas system as soon as the fuel cladding is breached. Efficient recovery of these isotopes requires capture at the point of release, before dilution with large quantities of air. Two processes have been developed, a cryogenic distillation and a Freon absorption. 

Modem practice is to maintain the white water system as closed as possible, ie, as much water as is compatible with efficient machine operation is recycled. The loss of fibers and inert furnish components, particularly clay, has been gready reduced. Eiber losses, however, stiU occur into the white water, and greater economy of operation may be achieved if these fibers could be recovered. Thus, it is common to design a fiber-recovery system into the white water cycle. The three general types of save-all fiber recovery are based on filtration (qv), dotation (qv), and sedimentation (qv). If these are operated efficiendy, the net fiber loss can be less than 1%. 

Heterogeneous hydrogenation catalysts can be used in either a supported or an unsupported form. The most common supports are based on alurnina, carbon, and siUca. Supports are usually used with the more expensive metals and serve several purposes. Most importandy, they increase the efficiency of the catalyst based on the weight of metal used and they aid in the recovery of the catalyst, both of which help to keep costs low. When supported catalysts are employed, they can be used as a fixed bed or as a slurry (Uquid phase) or a fluidized bed (vapor phase). In a fixed-bed process, the amine or amine solution flows over the immobile catalyst. This eliminates the need for an elaborate catalyst recovery system and minimizes catalyst loss. When a slurry or fluidized bed is used, the catalyst must be separated from the amine by gravity (settling), filtration, or other means. 

BeryUium reacts with fused alkaU haUdes releasing the alkaU metal until an equUibrium is estabUshed. It does not react with fused haUdes of the alkaline-earth metals to release the alkaline-earth metal. Water-insoluble fluoroberyUates, however, are formed in a fused-salt system whenever barium or calcium fluoride is present. BeryUium reduces haUdes of aluminum and heavier elements. Alkaline-earth metals can be used effectively to reduce beryUium from its haUdes, but the use of alkaline-earths other than magnesium [7439-95-4] is economically unattractive because of the formation of water-insoluble fluoroberyUates. Formation of these fluorides precludes efficient recovery of the unreduced beryUium from the reaction products in subsequent processing operations. 

The steam balance in the plant shown in Figure 2 enables all pumps and blowers to be turbine-driven by high pressure steam from the boiler. The low pressure exhaust system is used in the reboiler of the recovery system and the condensate returns to the boiler. Although there is generally some excess power capacity in the high pressure steam for driving other equipment, eg, compressors in the carbon dioxide Hquefaction plant, all the steam produced by the boiler is condensed in the recovery system. This provides a weU-balanced plant ia which few external utiUties are required and combustion conditions can be controlled to maintain efficient operation. 

Considering the efficiency of slip recovery system as 95% and 300 operating days in a year, the power feedback to the main supply source through the slip recovery system in 20% of the time,... 

The pressure in the regenerator depends on several factors. As the actual inlet pressure is adjusted to 0.22-0.24 MPa, the expander matches the system, but power loss is considerable. The power consumption on the air blower may be reduced at the same time as the pressure in the regenerator is lowered. However, the overall efficiency of the power recovery system is not significantly affected. 

The equipment for the pollutant removal system includes all hoods, ducting, controls, fans, and disposal or recovery systems that might be necessary. The entire system should be engineered as a unit for maximum efficiency and economy. Many systems operate at less than maximum efficiency because a portion of the system was designed or adapted without consideration of the other portions (4). 

In recent years, the use of solvent-borne adhesives has been seriously restricted. Solvents are, in general, volatile, flammable and toxic. Further, solvent may react with other airborne contaminants contributing to smog formation and workplace exposure. These arguments have limited the use of solvent-bome adhesives by different national and European regulations. Although solvent recovery systems and afterburners can be effectively attached to ventilation equipment, many factories are switching to the use of water-borne rubber adhesives, hot melts or 100% solids reactive systems, often at the expense of product performance or labour efficiency. 

The advantages of thermal incineration are that it is simple in concept, has a wide application, and results in almost complete destruction of pollutants with no liquid or solid residue. Thermal incineration provides an opportunity for heat recovery and has low maintenance requirements and low capital cost. Thermal incineration units for small or moderate exhaust streams are generally compact and light. Such units can be installed on a roof when the plant area is limited. = The main disadvantage is the auxiliary fuel cost, which is partly offset with an efficient heat-recovery system. The formation of nitric oxides during the combustion processes must be reduced by control of excess air temperature, fuel supply, and combustion air distribution at the burner inlet, The formation of thermal NO increases dramatically above 980 Table 13.10)... 

LCC calculations frequently provide energy-efficient solutions. This gives reduced energy consumption and a reduction in environmental pollution. For example, the installation of a heat recovery system in a ventilation system may reduce the energy consumption and emissions by 50 to 80%. Figure 16.1 compares life cycle cost and life cycle assessment calculations. 

The major advantage of the use of two-phase catalysis is the easy separation of the catalyst and product phases. FFowever, the co-miscibility of the product and catalyst phases can be problematic. An example is given by the biphasic aqueous hydro-formylation of ethene to propanal. Firstly, the propanal formed contains water, which has to be removed by distillation. This is difficult, due to formation of azeotropic mixtures. Secondly, a significant proportion of the rhodium catalyst is extracted from the reactor with the products, which prevents its efficient recovery. Nevertheless, the reaction of ethene itself in the water-based Rh-TPPTS system is fast. It is the high solubility of water in the propanal that prevents the application of the aqueous biphasic process [5]. 

Flash steam and heat recovery systems perform more efficiently if a continuous source of blowdown is provided. Depending on boiler pressure, the potential BW blowdown recovery is up to 25% of the blowdown volume recovered as flash steam and up to 75% of the heat content recovered. The flash steam can be passed to a LP steam line or sent back to a deaerator or feed tank, where it provides both FW heating and a replacement for MU water. 

Electrolytic recovery systems work best on concentrated solutions. For optimal plating efficiency, recovery tanks should be agitated ensuring that good mass transfer occurs at the electrodes. Another important factor to consider is the anode/cathode ratio. The cathode area (plating surface area) and mass transfer rate to the cathode greatly influence the efficiency of metal deposition. 

Sodium hydrosulfite is produced through the Formate process where sodium formate solution, sodium hydroxide, and liquid sulfur dioxide reacted in the presence of a recycled stream of methanol solvent. Other products are sodium sulfite, sodium bicarbonate, and carbon monoxide. In the reactor, sodium hydrosulfite is precipitated to form a slurry of sodium hydrosulfite in the solution of methanol, methyl formate, and other coproducts. The mixture is sent to a pressurized filter system to recover sodium hydrosulfite crystals that are dried in a steam-heated rotary drier before being packaged. Heat supply in this process is highly monitored in order not to decompose sodium hydrosulfite to sulfite. Purging is periodically carried out on the recycle stream, particularly those involving methanol, to avoid excessive buildup of impurities. Also, vaporized methanol from the drying process and liquors from the filtration process are recycled to the solvent recovery system to improve the efficiency of the plant. 

Packaging waste is normally recovered from one of two sources. The first is the waste which is not used by the converter (i.e. the maker of the package) and the second is from the packages which are discarded at the point of sale. The former is relatively free of contaminates whereas the latter may contain adhesives, plastics, staples and other contraries . Many countries, including the UK, have developed very efficient collection and recovery systems for packaging material from wholesale and retail outlets. For example in 1991, the Japanese were recovering almost 70% of corrugated containers from this source. 

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