Displays hquid crystal

Naphthalenediol. This diol is prepared by the alkah fusion of 2-hydroxynaphthalene-6-sulfonic acid (Schaffer acid) at 290—295°C. Schaffer acid is usually produced by sulfonation of 2-naphthol with the addition of sodium sulfate at 85—105°C. This acid is also used as a coupling component in the production of a2o dyes such as Acid Black 26. 2,6-Naphthalenediol is used as a component in the manufacture of aromatic polyesters which, as is also tme of the corresponding amides, display Hquid crystal characteristics (52). 

Other glass-ceramics may find potential use in Hquid crystal and electroluminescent displays. 

Liquid crystal polymers are also used in electrooptic displays. Side-chain polymers are quite suitable for this purpose, but usually involve much larger elastic and viscous constants, which slow the response of the device (33). The chiral smectic C phase is perhaps best suited for a polymer field effect device. The abiHty to attach dichroic or fluorescent dyes as a proportion of the side groups opens the door to appHcations not easily achieved with low molecular weight Hquid crystals. Polymers with smectic phases have also been used to create laser writable devices (30). The laser can address areas a few micrometers wide, changing a clear state to a strong scattering state or vice versa. Future uses of Hquid crystal polymers may include data storage devices. Polymers with nonlinear optical properties may also become important for device appHcations. 

This supertwisted nematic display utilizes a twist of the Hquid crystal director of 270° within the ceU rather than 90° (45). The basic operation of the ceU is unchanged ia that the effect of the analyzer on light which has been rotated by 270° is the same as for 90° rotation. 

Fig. 17. Polymer dispersed Hquid crystal display (PDLC). (a) U < clear state, where U) is the threshold voltage of the ceU. and rij represent the indexes of refraction for light polarized parallel and perpendicular to the director of the Hquid crystal represents the index of refraction of the isotropic...

The amount of Hquid crystals produced each year for appHcations is several tens of tons, with the vast majority designed specifically for display appHcations. Several of the largest producers of commercial Hquid crystals are E. Merck, Hoffmann-LaRoche Inc., and Chisso. E. M. Chemicals (Hawthorne, New York) is the distributor for E. Merck in the United States and Chisso America Inc. has an office in New York. Hoffmann-LaRoche and Di Nippon Inc. have joined forces to form a new company, Rodic. 

Microcapsules are used in several film coatings other than carbonless paper. Encapsulated Hquid crystal formulations coated on polyester film are used to produce a variety of display products including thermometers. Polyester film coated with capsules loaded with leuco dyes analogous to those used in carbonless copy paper is used as a means of measuring line and force pressures (79). Encapsulated deodorants that release their core contents as a function of moisture developed because of sweating represent another commercial appHcation. Microcapsules are incorporated in several cosmetic creams, powders, and cleansing products (80). 

Licjuid Crystals. Ferroelectric Hquid crystals have been appHed to LCD (Uquid crystal display) because of their quick response (239). Ferroelectric Hquid crystals have chiral components in their molecules, some of which are derived from amino acids (240). Concentrated solutions (10—30%) of a-helix poly(amino acid)s show a lyotropic cholesteric Hquid crystalline phase, and poly(glutamic acid ester) films display a thermotropic phase (241). Their practical appHcations have not been deterrnined. 

Since 1970 the subject of amoiphous semiconductors, in particular silicon, has progressed from obscurity to product commercialisation such as flat-panel hquid crystal displays, linear sensor arrays for facsimile machines, inexpensive solar panels, electrophotography, etc. Many other appHcations are at the developmental stage such as nuclear particle detectors, medical imaging, spatial light modulators for optical computing, and switches in neural networks (1,2). 

In order to develop the dyes for these fields, characteristics of known dyes have been re-examined, and some anthraquinone dyes have been found usable. One example of use is in thermal-transfer recording where the sublimation properties of disperse dyes are appHed. Anthraquinone compounds have also been found to be usehil dichroic dyes for guest-host Hquid crystal displays when the substituents are properly selected to have high order parameters. These dichroic dyes can be used for polarizer films of LCD systems as well. Anthraquinone derivatives that absorb in the near-infrared region have also been discovered, which may be appHcable in semiconductor laser recording. 

Liquid crystal display systems have been increasingly used in electro-optical devices such as digital watches, calculators, televisions, instmment panels, and displays of various kinds of electronic equipment, ie, lap-top computers and word processors. The dominant reason for thek success is thek extremely low power consumption. Furthermore, the Hquid crystal display systems have been remarkably improved in recent years, and today they have high resolution (more than 300,000 pixels) and full color capabiUty almost equivalent to those of a cathode ray tube. 

Guest-Host Mode LCD Systems. Guest-host hquid crystal display systems consisting of dichioic dyes (guest) and hquid crystal media... 

Several basic chromophore stmctures have been proposed for this purpose. Anthraquinone dyes appear to be predominant since they have a wider color range, excellent photostabiHty, good solubiHty in Hquid crystal media, and very high order parameters. Typical basic stmctures of the three primary colors are illustrated in Figure 11. Some examples are given in Table 10. The appropriate combination of three primary colors gives a black display. 

Dyes for Color Filters. Colorhquid crystal display systems consist of LSI drivers, glass plates, polarizers, electrodes (indium—tin oxide), and microcolor filters. The iadependent microcolor filter containing dyes is placed on each Hquid crystal pixel addressed electrically and acts as an iadividual light switch. All colors can be expressed by the light transmitted through each filter layer of the three primary colors, ie, red, green, and blue (Fig. 12). 

However, conductive elastomers have only ca <10 of the conductivity of soHd metals. Also, the contact resistance of elastomers changes with time when they are compressed. Therefore, elastomers are not used where significant currents must be carried or when low or stable resistance is required. Typical apphcations, which require a high density of contacts and easy disassembly for servicing, include connection between Hquid crystal display panels (see Liquid crystals) and between printed circuit boards in watches. Another type of elastomeric contact has a nonconducting silicone mbber core around which is wrapped metalized contacts that are separated from each other by insulating areas (25). A newer material has closely spaced strings of small spherical metal particles in contact, or fine soHd wires, which are oriented in the elastomer so that electrical conduction occurs only in the Z direction (26). 

Another major technology area that can utflize conductive IJ ink is the display market. Inkjet can be applied for both flexible and rigid displays such as electroluminescent and electrophoretic displays (including e-paper), hquid crystal displays (LCD), plasma display panels (PDP) and touch screens some functionalities have already been printed by IJ technology in certain display apphcations, for example RGB color filters. Conductive IJ is also appropriate for use in thin film transistors (TFT), disposable batteries, radio-frequency identification (RFID) tags, and a range of chemical and electronic sensors. 

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