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Contacting surfaces metal contacts

Jote the greater complexity of defining adsorption here in studies of electric double layers than, e.g., for metal-gas systems. With electric double layers, one is concerned with the whole interphasial region. The total adsorption is the sum of the increases of concentration over a distance, which in dilute solutions may extend for tens of nanometers. Within this total adsorption, there are, as will be seen, various types of adsorptive situations, including one, contact adsorption, which counts only Arose ions in contact with the electronically conducting phase (and is Aren, like the adsorption referred to in metal-gas systems, the particles on Are surface). Metal-gas systems deal with interfaces, one might say, whereas metal-electrolyte systems deal primarily with interphases and only secondarily with interfaces. [Pg.128]

The shorter-term exposure experiments show that some portion of the organically-bound chlorine, such as trichlorethane or its decomposition products, remains absorbed on a 304 stainless steel surface, even after heating at 35-40°C in a high vacuum. Conversion to an ionic species begins after a short contact period and can be detected using XPS. Formation of the ionic chloride is likely the result of hydrolysis by water also absorbed on the surface, and is perhaps catalyzed by the surface metal oxides. Further atmospheric exposure up to a few months increases the relative amount of the ionic form of chlorine. The composition of the surface oxide layer was altered, with chromium oxide replacing iron oxide as the major species. There was further evidence that chlorine was present as iron chloride, perhaps up to 5% of the surface film. The conditions under which oxidation of such surfaces occurred are quite comparable to those which could occur on steel surfaces in industrial usage. [Pg.359]

Marketed as an aqueous solution in concentrations of 3-90% by weight. Solutions of hydrogen peroxide gradually deteriorate and are usually stabilized by organic material. Agitation, contact with rough surfaces, metals, alkalies, and many other substances accelerate decomposition.1... [Pg.297]

Photoanode Contact metal ohmic contact -Si p-Si surface metal solution Photocathode Contact metal ohmic contact p-Si n-Si surface metal solution... [Pg.622]

Marketed as a soln in water in concns of 3-90% by wt. Solns of hydrogen paroxide gradually deteriorate and are usually stabilized by the addition of acetanilide or similar organic materials. Agitation Or contact with rough surfaces, metals or many other substances accelerates decomposition. Rapidly dec by alkalies, finely divided metals the presence of mineral add renders it more stable. [Pg.760]

An important consideration in constructing certain types of geochemical models, especially those applied to environmental problems, is to account for the sorption of ions from solution onto mineral surfaces. Metal oxides and aluminosilicate minerals, as well as other phases, can sorb electrolytes strongly because of their high reactivities and large surface areas (e.g., Davis and Kent, 1990). When a fluid comes in contact with minerals such as iron or aluminum oxides and zeolites, sorption may significantly diminish the mobility of dissolved components in solution, especially those present in minor amounts. [Pg.129]

Biofilms can form on just about any imaginable surface metals, plastics, natural materials (such as rocks), medical implants, kitchen coimters, contact lenses, the walls of a hot tub or swimming pool, hmnan and animal tissue, etc. Indeed, wherever the combination of moisture, nutrients, and a surface exists, biofilms will likely be foimd as well. Biofilms are characterized by structural heterogeneity, genetic diversity, complex community interactions, and an extracellular matrix of pol)uneric substances. Biofilms are an important link in the energy budget of many natural commimities. Both types of cells produce a pol)uneric extracellular slime layer which encloses the cells. This complex aggregate of cells and polysaccharide is the biofilm community. [Pg.405]

Tires syn. tyres are the outer circumference of a wheel which makes contact with a surface. Metal tires are used on rail and other vehicles. Solid rubber tires are used in factories where they carry high loads to resist abrasion and puncture. Where the greatest need for protection from shock is required (e.g., in automobiles, aircraft, and other vehicles) pneumatic (compressed air-filled) tires are used. Tire assemblies consist of the tire and the wheel to which they are attached. Assemblies may also include rubber inner tubes which hold the air. On inflation, the edge of the tire is pressed against the rim of the wheel and forms an airtight seam or an inner tube is filled. Tires are manufactured to rated inflation pressures appropriate to the weight of the vehicle and driving conditions. [Pg.254]

Figure fSO. Three-dimensional distributions of oxygen and hydrogen sites of ambient water in contact with the (100) FCC metal slab. Section by the plane passing through the on-top and hollow site adsorption positions of the (100) surface. Metal ionic cores of the slab are located as in Figure 4.27a, and are schematically shown with humps in the void g i r) = 0. [Pg.250]

Figure 10.10 PDOS of surface atom in contact with atop and threefold adsorbed CO on the Ru(OOOl) surface. Similar VASP-DFT calculations as in Figures 10.3 and 10.5 (a) PDOS of CO adsorbed atop and of metal valence d-atomic orbitals (a2 is partial blow up of al) (b) LDOS difference of the valence electron density localized on the surface metal atom with and... Figure 10.10 PDOS of surface atom in contact with atop and threefold adsorbed CO on the Ru(OOOl) surface. Similar VASP-DFT calculations as in Figures 10.3 and 10.5 (a) PDOS of CO adsorbed atop and of metal valence d-atomic orbitals (a2 is partial blow up of al) (b) LDOS difference of the valence electron density localized on the surface metal atom with and...
Contact metal Ohmic contact w-Si p-Si I Surface metal Solution... [Pg.334]

Sodium tallowate Stannous stearate Stearamide Stearyl citrate Stearyl stearate Tall oil acid Tallow acid Triethanolamine Triethylene glycol Trilinoleic acid Trisodium EDTA Tristearyl citrate Zinc laurate lubricant, surface food-contact polyolefin film Polymethylsilsesquioxane lubricant, surface metallic articles Dioctyl sebacate lubricant, surgical Oxidized cellulose lubricant, surgical equip. [Pg.5451]

When imaging, with the tip held in direct contact with the surface, metal-coated tips are prone to wear over a prolonged period of time. This process that can affect the validity of the electrical measurement. In order to minimize this potential problem, some workers have advocated the use of tapping mode imaging for identifying topographical features of interest [74]. However, this makes simultaneous collection of topography and conductance data (where ideally the tip should remain in contact with the surface) virtually impossible. [Pg.437]

This relation holds for a saturated solution of Fe(OH)2 in water, the natural pH of which is 9.5. This pH is observed at an iron surface between an external pH of 4-10, as diseussed in Section 12.3. Values of surface pH for other corroding metals are specitic to the metal but the relation (2M ) = (OH ) also appUes, provided that the external solution in contact does not alter the natural pH of the surface metal hydroxide. [Pg.261]

According to Dowson (1995), if the mean contact stresses are not too high the wear of polymer against a hard surface (metal or ceramic) is obtained with fair accuracy with the relationship V = kFL. [Pg.368]

The most common cause of contact angle hysteresis arises from heterogeneous contamination of the sofid with islands of adsorbed or smeared low-energy impurities. High-energy surfaces attract such contamination more readily than low and often exhibit the surface of low-energy surfaces. Metals also may possess islands of oxidation that induce hysteresis. Low-energy surfaces, on the other hand, can also acquire contamination, more often with surface-active material that is amphipathic in nature. [Pg.83]

Changes in the surface properties of cationic complexes, in which the surface metal cations of natural clays have been exchanged with an ammonium cationic surfactant, could be simply confirmed by mixing them with polar solvents and observing their dispersibility. It should be noted that quantitative measurements of surface properties may be obtained by contact-angle measurements [4, 10]. This method allowed measuring the change of surface polarity of Cloisite 30B (a dimethylbenzyl tallow ammonium chloride-modified montmorillonite) subjected to elevated temperatures for the duration of typical... [Pg.29]


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See also in sourсe #XX -- [ Pg.217 , Pg.218 ]




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