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Caldum carbonate solubility

High-performance liquid chromatography is performed using a Hewlett-Packard 1090 chromatograph equipped with a ternary-solvent delivery system, an autoinjector with a 0 -20- u.L injection loop, an oven compartment, and a diode-array UV detector. An ELS detector (Alltech Associates, Deerfield, IL) is connected in series to the UV detector. Hexane, 2-propanol, and water were used for the analysis of nonionic surfactants. Water and tetrahydrofuran (THF) are used for the analysis of anionic surfactants. No preliminary sample preparation is used other than dilution. The nonionic surfactants are diluted 1 40 (v/v) with hexane. The anionic surfactants (alkyl ether sulfates and synthetic and petroleum sulfonates) are diluted 1 20 (v/v) with water-THF (50 50). The calcium sulfonate surfactants were diluted 1 20 (v/v) with a THF-38% hydrochloric acid solution of pH 1. Hydrochloric add is required to prevent salt precipitation by converting any excess water-insoluble caldum carbonate into water-soluble calcium chloride. All diluted samples are... [Pg.1559]

Alternatively, antisealants can be used to control caldum carbonate scale at LSI values as high as 2.0-2.5, depending on the specific antisealants. Calcium also forms scales with fluoride, sulfate, and phosphate. The LSI will not help predict these scales analysis of water quality, using the ion product and solubility constants, is required to determine the potential for scaling with caldum fluoride or calcium phosphate. Antisealants currently available can address calcium fluoride and caldum sulfate scale they do not address calcium phosphate scale (although newer antisealants will be available in the near future to address this scale). [Pg.135]

Caldum hydrogen carbonate is the most common cause of hard water. It forms when rain falls on rocks of limestone and chalk. Limestone and chalk are mostly caldum carbonate, which is not soluble in water. However, rain is not pure water. As it falls through the air, it dissolves carbon dioxide, forming a weak addic solution. This solution then attacks the caldum carbonate, forming calcium hydrogen carbonate which is soluble. The reaction is ... [Pg.108]

One harmful effect of acid rain is the deterioration of structures and statues made of marble or limestone, both of which are essentially calcium carbonate. The reaction of calcium carbonate with sulfuric acid yields carbon dioxide, water, and calcium sulfate. Because calcium sulfate is marginally soluble in water, part of the object is washed away by the rain. Write a balanced chemical equation for the reaction of sulfuric add with caldum carbonate. [Pg.896]

In many of its chemical properties, radium is like the elements magnesium, caldum, strontium and barium, and it is placed in group 2, as is consistent with its 6s26pcls2 electron configuraUon. Its sulfate (Ksp — 4.2 a 10-1 ) is even more insoluble in water than barium sulfate, with which it is conveniently coprecipitated, Like barium and other alkaline earth metals, it forms a soluble chloride (X p = 0,4) and bromide, which can also be obtained as dihydrates, Radium also resembles the other group 2 elements in forming an insoluble carbonate and a very slightly soluble lodate (Xsp = 8.8 x 1(T10). [Pg.1417]

Concerning the purification of the add-esters, it may be mentioned, that the crude reaction-product is shaken with a sodium carbonate solution until the ester no longer shows an acid reaction. The alcohol may be removed from esters difficultly soluble in water by repeatedly washing with water in case an ester is moderately soluble In water, as ethyl acetate, it is better to use a solution of caldum chloride... [Pg.139]

According to the temperature at which the sulphonation takes place, more of one than of the other acid is formed at lower temperatures an excess of the a-add is obtained, at higher an excess of the /3-add. If the mixture is heated to too0, a mixture of 4 parts of the a-acid and 1 part of the /3-add is formed, while at 170° a mixture of the 3 parts of the /3-add and 1 part of the a-add is obtained. In order to separate the sulphonic adds from the excess of sulphuric acid, advantage is taken of the fact that sulphonic adds differ from sulphuric add in that they form soluble salts of caldum, barium, and lead, as mentioned under benzenesulphonic acid. For the separation of the sulphonic acid from sulphuric add, the caldum salt is prepared by neutralising the acid mixture with chalk or lime, since it is cheaper than lead carbonate or barium carbonate. This method is followed technically on the large. scale as well as in laboratory preparations. Since the caldum salts of the two isomeric sulphonic adds possess a very different solubility in water,—at io° 1 part of the a-salt dissolves in 16.5 parts of water, and 1 part of the /3-salt dissolves in 76 parts of water,—the /3-salt, which is more difficultly soluble, and consequently crystallises out first, can be separated by fractional crystallisation from the a-salt which remains in solution. For the conversion into naphthol the caldum salt cannot be used directly it must first be changed into the sodium salt by treatment with sodium carbonate ... [Pg.263]

It disappears again because it reacts with more carbon dioxide to form caldum hydrogen carbonate, which is soluble ... [Pg.183]

Contrarily to fatty add salts (i.e., sodium laurate soap), the long-chain iV -acyl amino adds have excellent water solubility (due to the presence of additional CO-NH linkages), quick biodegradability and good lime resistance (i.e., caldum ion tolerance) [11]. The surfactant properties of pure sodium salts of iV -acyl amino acids (anionic surfactants) with different alkyl chains (saturated and unsaturated with 10-18 carbon atoms) and amino acid residues have been described and compared with those of sodium lauryl sulfate (SLS) and sodium laurate [11-14]. The authors showed that the critical micelle concentration (CMQ of the amino acid-based surfactants was lower than that of the SLS but higher than that of sodium laurate. The surface activity increased and the CMC decreased by raising the alkyl chain... [Pg.194]


See other pages where Caldum carbonate solubility is mentioned: [Pg.144]    [Pg.144]    [Pg.724]    [Pg.142]    [Pg.131]    [Pg.142]    [Pg.255]    [Pg.142]    [Pg.252]    [Pg.995]    [Pg.372]    [Pg.223]    [Pg.223]    [Pg.241]   
See also in sourсe #XX -- [ Pg.639 ]




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