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Amperometric Techniques

The use of semiconducKrr structures, such as field-effect transistors (ISFET), means that the results of electrochemical techniques can be exploited, and the problem of the strong impedances exhibited by potentiometric transducers can be solved. The pH and the concentration of ions or even gaseous compounds can be detomined by measurement of the drain current in the presence of a reference electrode. Here, the biological system is immobilized on an Si02 oxide layer, which forms the sensitive component of the transistor. [Pg.12]


The continuous methods combine sample collection and the measurement technique in one automated process. The measurement methods used for continuous analyzers include conductometric, colorimetric, coulometric, and amperometric techniques for the determination of SO2 collected in a liquid medium (7). Other continuous methods utilize physicochemical techniques for detection of SO2 in a gas stream. These include flame photometric detection (described earlier) and fluorescence spectroscopy (8). Instruments based on all of these principles are available which meet standard performance specifications. [Pg.201]

Discussion. Iodine (or tri-iodide ion Ij" = I2 +1-) is readily generated with 100 per cent efficiency by the oxidation of iodide ion at a platinum anode, and can be used for the coulometric titration of antimony (III). The optimum pH is between 7.5 and 8.5, and a complexing agent (e.g. tartrate ion) must be present to prevent hydrolysis and precipitation of the antimony. In solutions more alkaline than pH of about 8.5, disproportionation of iodine to iodide and iodate(I) (hypoiodite) occurs. The reversible character of the iodine-iodide complex renders equivalence point detection easy by both potentiometric and amperometric techniques for macro titrations, the usual visual detection of the end point with starch is possible. [Pg.541]

An amperometric technique relies on the current passing through a polarizable electrode. The magnitude of the current is in direct proportion to the concentration of the electroanalyte, with the most common amperometric techniques being polarography and voltammetry. The apparatus needed for amperometric measurement tends to be more expensive than those used for potentiometric measurements alone. It should also be noted that amperometric measurements can be overly sensitive to impurities such as gaseous oxygen dissolved in the solution, and to capacitance effects at the electrode. Nevertheless, amperometry is a much more versatile tool than potentiometry. [Pg.3]

It is used in IC systems when the amperometric process confers selectivity to the determination of the analytes. The operative modes employed in the amperometric techniques for detection in flow systems include those at (1) constant potential, where the current is measured in continuous mode, (2) at pulsed potential with sampling of the current at dehned periods of time (pulsed amperometry, PAD), or (3) at pulsed potential with integration of the current at defined periods of time (integrated pulsed amperometry, IPAD). Amperometric techniques are successfully employed for the determination of carbohydrates, catecholamines, phenols, cyanide, iodide, amines, etc., even if, for optimal detection, it is often required to change the mobile-phase conditions. This is the case of the detection of biogenic amines separated by cation-exchange in acidic eluent and detected by IPAD at the Au electrode after the post-column addition of a pH modiher (NaOH) [262]. [Pg.409]

In this section the use of amperometric techniques for the in-situ study of catalysts using solid state electrochemical cells is discussed. This requires that the potential of the cell is disturbed from its equilibrium value and a current passed. However, there is evidence that for a number of solid electrolyte cell systems the change in electrode potential results in a change in the electrode-catalyst work function.5 This effect is known as the non-faradaic electrochemical modification of catalytic activity (NEMCA). In a similar way it appears that the electrode potential can be used as a monitor of the catalyst work function. Much of the work on the closed-circuit behaviour of solid electrolyte electrochemical cells has been concerned with modifying the behaviour of the catalyst (reference 5 is an excellent review of this area). However, it is not the intention of this review to cover catalyst modification, rather the intention is to address information derived from closed-circuit work relevant to an unmodified catalyst surface. [Pg.29]

Amperometric techniques can also be useful in gaining information on the state of a catalyst. These techniques tend to be more complex than potentiometric methods and are as a result less developed. In particular, early work with the technique of cyclic voltammetry has produced some promising results. [Pg.33]

Analytical separation of several organics from water by PVC polymer is feasible. A solvent extraction model describes the separation dynamics and pH dependence. Selectivity via pH control of the extraction step and preconcentration of analyte can be accomplished. These results suggest that other polymer solvent extraction schemes can be developed by using this approach. The flow-through amperometric technique provides a well-suited detector component for the technique. [Pg.352]

Electrochemical (amperometric) techniques provide the possibility for in situ, continuous and automated measurements of ozone in the liquid. The membrane electrode usually consists of a gold cathode, a silver anode, an electrolyte (e. g. AgBr, K2S04 or KBr) and a teflon membrane. Several companies offer such electrodes in different configurations. The application range and accuracy differs depending on the kind of electrode. [Pg.71]

For amperometric techniques at a fixed potential (e.g., liquid chromatography detectors), the classical charging current is zero since dE/dt = 0. There is still a background current, however, due to surface redox processes or slow... [Pg.296]

It is seen that the amperometric technique is more used for heavy-metal determination in comparison to potentiometric techniques. The research published during the last 5 years concerning heavy-metal determination has shown the applications especially for water samples (Table 14.1). [Pg.306]

Amperometry is the most widely reported EC detection mode for CE microchips, which primarily relies on oxidation or reduction of elect-rochemically active species by applying a constant potential to a working electrode. The current is then monitored as a function of time. Since it is based on the redox reaction that occurs at the electrode surface, electrodes can be miniaturised without loss in sensitivity. The relevance of this simple technique is reported in several reviews [48,74], In this section, a general overview of the combination of this detection technique to CE microchips together with special sections for different amperometric techniques and electrode materials and types are considered. [Pg.837]

Potentiometric. Not all analytes can be readily assayed via a redox enzyme and in these instances the assay schemes suggest parameters other than electron transfer which may be probed. Indeed, even where a redox enzyme is available for the analyte in question, it is not always desirable to deploy an amperometric technique. [Pg.12]

Specially engineered thin hlms can be very effective as molecular interfaces for many substrates, but the requirements will depend on the measurement techniques employed. A very useful one is the amperometric technique. In this case, the detection method is based on the measurement of faradaic currents produced by the... [Pg.434]

Voltammetric and amperometric techniques are among the most sensitive and widely applicable of ail electroanalytical methods. [Pg.101]

Fig. 12.4 HT-29 colon cancer cells response to BA, AN-7, and AN-9. Amperometiic response curves for monitoring of alkaline phosphatase activity using the electrochemical array chip. The HT-29 colon cancer cells were exposed to the differentiation agents Butyric acid (2.5 mM), AN-7 and AN-9 (50 pM). The HT-29 cells with the substrate PAPP were placed into the 100 nL volume electrochemical chambers on the chip. Current was measured using the amperometric technique at 220 mV... Fig. 12.4 HT-29 colon cancer cells response to BA, AN-7, and AN-9. Amperometiic response curves for monitoring of alkaline phosphatase activity using the electrochemical array chip. The HT-29 colon cancer cells were exposed to the differentiation agents Butyric acid (2.5 mM), AN-7 and AN-9 (50 pM). The HT-29 cells with the substrate PAPP were placed into the 100 nL volume electrochemical chambers on the chip. Current was measured using the amperometric technique at 220 mV...
Detection limits as low as 10 nrnol/1 and a linear measuring range of 3-6 concentration decades are the main advantages of amperometric techniques. [Pg.24]

Measurement of NTE activity has classically been done by colorimetric determination of phenol released by hydrolysis of the substrate, phenyl valerate [89,90]. The absorbance maximum of the red phenol chromophore overlaps substantially with that of whole blood homogenates and dilution of the blood to remove the interfering absorbance decreases NTE activity below the detection limit of the colorimetric assay [88], Thus, the colorimetric assay cannot be used to assay NTE in whole blood. The problems inherent in a colorimetric NTE assay can be eliminated by using an amperometric technique to detect phenol. [Pg.289]

To create a fast and simple method for monitoring of human exposure to neuropathic OPs, a principal new approach to NTE activity analysis has been developed in joint study of the Institite of Physiologically Active Compounds Russian Acad. Sci. and Chemical Department of Moscow State University [88,91,92], Recently, a new biosensor for NTE assay was introduced using a tyrosinase carbon-paste electrode to detect phenol produced by the hydrolysis of phenyl valerate. In this type biosensor phenol is quantified by measuring electroreduction of the generated o-quinone on a graphite electrode (Fig. 6) [88,91 ]. The tyrosinase carbon-paste electrode improved the sensitivity of the NTE assay 10-fold compared to the colorimetric method or an earlier amperometric technique based on oxygen detection [92]. Moreover, the new electrode operates in a... [Pg.289]

The main sources of water contaminants are industries, pesticides, private sources at home, and public and private sewage disposal. There are many inorganic and organic compounds that are soluble in water, so it is very important to improve the sampling process — and the separation technique — to obtain reliable analytical information. The methods used for water analysis are based in many cases on spectrometric techniques. An increase in the use of potentiometric and amperometric techniques has been reported in the last few years. [Pg.30]

The precision of the method is a measure of its sensitivity. The most sensitive methods result in high precision. This property is very important for the quality and reliability of the analytical information. The high sensitivity property represents the main requirement for an analytical method to be used in trace analysis. For example, if a sample contains an ion at 10 8 mol/1 concentration level, and it is therefore necessary to select between the electrometric methods of analysis, an amperometric technique is applied for its determination. The potentiometric methods cannot be applied in this case since their limit of detection is not less than 10 6 mol/1. [Pg.75]

Amperometric techniques are very useful for detecting analytes that have been separated by chromatographic means but have no chromophores or other easy means of detection. Adsorptive stripping voltammetry (ASV) can be used for the direct sensitive analysis of metals in many types of sample matrix. For example, ASV has been used to determine cadmium, lead and zinc in urine, copper and bismuth in human hair tin in fruit juice, zinc and copper in fish and lead in gunshot residue. Stripping analysis can also be used for other applications such as determining flavanols in wine °, inorganic compounds such as cyanide and pharmaceuticals. ... [Pg.159]

As the name implies, amperometric techniques involve the measurement of current. The term polarography derives from the fact that the electrode at which the reaction of interest occurs is in a polarized... [Pg.422]

The ODR method relies on amperometric or polarographic techniques to measure the oxygen concentration of the soil pores. The amperometric techniques imply the measurement of current. The polarographic techniques imply that the electrode at which reduction of reactants occurs is in a polarized condition. Under polarized conditions, the concentration of reactants at the electrode surface is low, whereas the concentration of products is high. Under these conditions, the amount of current that the electrode will pass is directly proportional to the flux of reactant to the electrode surface. These principles are used in the ODR method. [Pg.195]

Changes in capadtances of the CyD monolayers on gold surfaces in the presence of selected analytes may be used as a signal transdudion mode alternative to the more commonly used voltammetric and amperometric techniques and impedance analysis for monitoring host-guest interadions in monolayers. [Pg.311]


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