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Alkylating compounds

Synthesis This route has been carried out successfully (Rec. Trav. Chem., 1958, 77, 854). Note that no AICI3 is needed for Friedel-Crafts alkylation with easily formed t-alkyl compounds. [Pg.128]

Data for alkyl-benzenes are collected in table 9.1, and for substituted-alkyl compounds in table 9.2. [Pg.163]

Products are contaminated with more highly alkylated compounds, but less so than without the active metal. The phosphide can be generated from a Grignard or organolithium reagent. [Pg.379]

RTIX2 derivatives are covalent compounds, generally soluble in organic solvents. The aryl and vinyl derivatives are more stable than the corresponding alkyl compounds. This type of compound has been postulated to be an intermediate in many organic synthetic reactions involving thaUium(III) species. [Pg.470]

Metals and metalloids that form alkyl compounds, eg, methylmercury and methylarsenic acid, tributjltin, deserve special concern because these compounds are volatile and accumulate in cells they are poisonous to the central nervous system of higher organisms. Because methylmercury or other metal alkyls may be produced at a rate faster than it is degraded by other organisms, it may accumulate in higher organisms such as fish. Hg species are also reduced to elementary Hg which is soluble in water but lost by volatilization to the atmosphere (40). [Pg.217]

Ketones can be reduced by the Wolff-Kishner method to the corresponding alkyl compounds, or by sodium in ethanol to the corresponding alcohols. An alkali-catalyzed deacylation of 3-acetyl-6-methoxypyridazine 1-oxide occurs quantitatively on treatment with dilute sodium hydroxide. [Pg.32]

In the diaziridinimine field there is no sharp contrast between stable t-alkyl and unstable primary alkyl compounds. Both types are known as stable compounds (80H(14)1677). [Pg.219]

Such A-alkyl compounds are not known to be of any current application although fibres from a partially A-alkylated derivative of nylon 610 have been described. [Pg.505]

Manganese cyclopentadienyl tricarbonyl (as Mn) Marble/calcium carbonate Mercury (alkyl compounds) (as Hg)... [Pg.379]

Atid aie pioduced by passing carbon dioxide into tlie ether bolution of the magnesium alkyl compound. [Pg.308]

Monomeric alkyl compounds of the form MR3 have also been obtained for Sc and Y, where the alkyl groups are of the types Me3SiOH2 and Me300H2 which are bulky and contain no )3 hydrogen atoms (p. 926). [Pg.953]

Although compound 38 liberates the calculated amount of iodine, the completely alkylated compound 34 only gives traces of iodine. The... [Pg.116]

Alkyl-rest, n. alkyl residue, alkyl group, -sulfo-aSore, /. alkyl sulfonic acid, -verbindung, /. alkyl compound. [Pg.19]

Alkyl compounds can be synthesized by substitution, oxidative addition and insertion reactions... [Pg.219]

Water, which can be taken to a minimum by the use of molecular sieves, can produce a lactamide either through direct reaction with the aziridinone intermediate, or upon hydrolysis of oxazolidinone self-condensation products, previously obtained also in the presence of a strong non-nucleophilic base (H ) (ref. 17). The recently reported 0-self-alkylation compound H bears the (S,S)-configurations at the unreacted C-Br and newly formed C-0 bonds. The presence of bromine was expedient for the x-ray assessment of configuration at the two chiral centers of 11 which forms in high diastereoisomeric excess (ref. 5). [Pg.166]

Sulfinic acids can be prepared by reduction of sulfonyl chlorides. Though mostly done on aromatic sulfonyl chlorides, the reaction has also been applied to alkyl compounds. Besides zinc, sodium sulfite, hydrazine, sodium sulfide, and other reducing agents have been used. For reduction of sulfonyl chlorides to thiols, see 19-57. [Pg.577]

Various N-nitroso-AT-alkyl compounds undergo elimination to give diazoalkanes. One of the most convenient methods for the preparation of diazomethane involves base treatment of V-nitroso-V-methyl-p-toluenesulfonamide (illustrated above, with... [Pg.1352]

This is intimately related to the nature of the solvent. If the solvent is nonpolar and lacks coordinating ability, then generally [known exceptions are the Pt(II) and Ir(III) complexes mentioned in Section B] the insertion will proceed via attack of L upon the alkyl compound ( 2 path), e.g.. Table I, reaction 6. [Pg.99]

D. G. H. Ballard Polymerisation by homogeneous transition metal alkyl compounds, pp. 213-264 (25). [Pg.452]


See other pages where Alkylating compounds is mentioned: [Pg.186]    [Pg.339]    [Pg.116]    [Pg.288]    [Pg.210]    [Pg.14]    [Pg.15]    [Pg.71]    [Pg.163]    [Pg.7]    [Pg.104]    [Pg.350]    [Pg.126]    [Pg.135]    [Pg.12]    [Pg.298]    [Pg.387]    [Pg.322]    [Pg.85]    [Pg.13]    [Pg.180]    [Pg.315]    [Pg.1664]    [Pg.109]    [Pg.150]    [Pg.155]    [Pg.136]    [Pg.160]    [Pg.87]    [Pg.253]   
See also in sourсe #XX -- [ Pg.93 ]




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1.2- Dicarbonyl compounds from alkyl halides

1.3- Dicarbonyl compounds y-alkylation

1.3- Dicarbonyl compounds, alkylation

4-Alkyl-4 -cyanobiphenyl compounds

A -Alkyl compounds

Acidic zeolite aromatic compounds alkylation

Actinide alkyl compounds

Active hydrogen compounds alkylation

Active methylene compounds with alkyl halides

Aliphatic compounds alkylation

Alkyl Azo Compounds

Alkyl aluminium compounds

Alkyl aluminium compounds determination

Alkyl aluminum compounds

Alkyl ammonium compounds

Alkyl and Aryl Compounds

Alkyl and Metal Halide Compounds

Alkyl and aryl metal compound

Alkyl carbamate compounds

Alkyl compounds

Alkyl compounds diffraction studies

Alkyl compounds manganese group

Alkyl compounds reactions

Alkyl compounds rhenium based

Alkyl compounds spectroscopy

Alkyl compounds structure

Alkyl compounds synthesis

Alkyl compounds, conjugate

Alkyl compounds, conjugate synthesis

Alkyl compounds, general

Alkyl copper compounds

Alkyl derivatives boron compounds

Alkyl derivatives compounds

Alkyl derivatives enolate compounds

Alkyl derivatives lead compounds

Alkyl halides Compounds with halogen

Alkyl halides Compounds with halogen Table

Alkyl halides Compounds with halogen ammonia

Alkyl halides Compounds with halogen elimination reaction

Alkyl halides Compounds with halogen from alcohols

Alkyl halides Compounds with halogen nucleophilic

Alkyl halides and related compounds

Alkyl halides and related compounds azoles without a free NH group

Alkyl halides carbonyl compound

Alkyl halides compounds

Alkyl halides organomercury compounds

Alkyl halides, oxonium salts and related compounds

Alkyl in compounds

Alkyl lead compounds

Alkyl lead compounds in air

Alkyl lithium compounds

Alkyl lithium compounds anionic polymerization

Alkyl lithium compounds initiators

Alkyl mercuric compounds

Alkyl metals, 1-silyl-1-selenoreactions with carbonyl compounds

Alkyl metals, a-selenocarbonyl compound homologation

Alkyl metals, a-selenocarbonyl compound homologation functionalized

Alkyl metals, a-selenocarbonyl compound homologation reactions

Alkyl metals, a-selenocarbonyl compound homologation reactions with carbonyl compounds

Alkyl metals, a-selenocarbonyl compound homologation reactions with enals

Alkyl metals, a-selenocarbonyl compound homologation reactions with enones

Alkyl metals, a-selenocarbonyl compound homologation regiochemistry

Alkyl metals, a-selenocarbonyl compound homologation synthesis

Alkyl metals, a-selenocarbonyl compound homologation via metallation of selenides

Alkyl metals, a-selenoxyreactions with carbonyl compounds

Alkyl naphthalene compounds

Alkyl nitrites compounds

Alkyl nitrites, -nitroso compounds

Alkyl nitrogen compounds

Alkyl organophosphorus compounds

Alkyl peroxy radical reactivity compounds

Alkyl phenol-formaldehyde compounds

Alkyl phosphates, reaction with compounds

Alkyl sulfates compounds

Alkyl sulfonates compounds

Alkyl titanium compound

Alkyl-azonium and -pyrylium compounds

Alkyl-metal compounds

Alkylating the a-Carbon of Carbonyl Compounds

Alkylation by Unsaturated Compounds

Alkylation carbonyl compound nitrogen derivatives

Alkylation compounds

Alkylation compounds

Alkylation of 3-dicarbonyl compounds

Alkylation of Active Methylene Compounds with Alcohols

Alkylation of Cyclic Ketones and Related Compounds

Alkylation of Nitro Compounds Using Transition Metal Catalysis

Alkylation of Nitro Compounds via Alkyl Radicals

Alkylation of Reissert compounds

Alkylation of Reisserts Compound

Alkylation of active methylene compounds

Alkylation of alcohols and related compounds

Alkylation of amides and related compounds

Alkylation of aromatic compounds

Alkylation of aromatic nitro compound

Alkylation of carbonyl compounds

Alkylation of nitro compounds

Alkylation of nitrogen compounds

Alkylation of nitrogen compounds by sulfuric esters

Alkylation of p-dicarbonyl compounds

Alkylation or arylation of heterosubstituted tricoordinated phosphorus compounds

Alkylation organomercury compounds

Alkylation propargylic compounds

Alkylation reactions aromatic compounds

Alkylation reactions compounds

Alkylation with Carbonyl Compounds The Prins Reaction

Alkylation with Carbonyl Compounds and Derivatives

Alkylation, Acylation, and Halogenation of Nitro Compounds

Alkylation, heteropoly compounds

Alkylation, photochemical compounds

Alkylations by Unsaturated Compounds

Alkylations of aromatic compounds

Alkyls => sulfur compounds

Alkyls and Related Compounds

Alkyls neopentyl compounds

Alkyls trimethylsilyl)methyl compounds

Alkylzinc compounds alkylation

Aluminum compounds alkylation

Aluminum compounds alkylation reactions

Aluminum compounds systems, alkylation

Amides alkylation with diazo compounds

Amino compounds alkylation/arylation

Aromatic compound alkylated

Aromatic compounds Friedel-Crafts alkylation

Aromatic compounds alkyl

Aromatic compounds alkyl, oxidation

Aromatic compounds alkyl-substituted

Aromatic compounds, addition alkyl substituents

Aromatic compounds, alkylation

Aromatic compounds, fused alkyl

Aromatic compounds, fused radical alkylation

Azinium compounds, N-alkyl-, substituent displacement

Azinium compounds, N-alkyl-, substituent displacement formation

Azinium compounds, N-alkyl-, substituent displacement kinetics of substitution

Azinium compounds, N-alkyl-, substituent displacement reaction with nucleophiles

B-Alkyl-9-BBN compounds

Basic zeolites aromatic compounds alkylation

Boron compounds alkylation

Boron compounds alkylation reactions

By the activation of alkyl nitro compounds

C-Alkylation compounds

Carbene complexes, alkyl pentacarbonylalkylation reaction with carbonyl compounds

Carbon compounds alkyl halides

Carbonyl compound, acidity alkylation

Carbonyl compounds 3-alkylation

Carbonyl compounds alkylation, regiochemistry

Carbonyl compounds alkylation, stereochemistry

Carbonyl compounds enolate alkylation

Carbonyl compounds reductive alkylation

Carbonyl compounds, asymmetric alkylation

Chromium alkyl compounds

Cluster compounds lithium alkyls

Cobalt compounds alkyl derivatives

Compounds alkylation with alcohol

Compounds as Alkylating Agents

Compounds of Alkyl and Aryl Alanes

Compounds of silicon with hydrogen and alkyl groups

Condensation reactions, carbonyl compounds alkylation, enolate ions

Copper compounds palladium-catalyzed alkylation

Coupling of Alkyl Iodides with a,-Unsaturated Compounds

Coupling of alkyl halides with organometallic compounds

Di O-Alkyl Derivatives of 1,2-Dihydroxy Compounds

Diazo compounds, alkylation

Diazo compounds, alkylation acids

Diazo compounds, alkylation amines

Diazo compounds, alkylation protonation

Diazo compounds, alkylation reaction

Diazo compounds, alkylation with boranes

Diazo compounds, alkylation with sulfur

Diazo compounds, alkylation with thioketones

Enolate compounds alkylation-annulation

Exchange Reactions of Group III Alkyl Addition Compounds

Formaldehyde compounds, alkylated

Friedel-Crafts Alkylation Reaction with Organosilicon Compounds

Friedel-Crafts alkylation carbonyl compounds

Friedel-Crafts alkylation compounds

Friedel-Crafts alkylation deactivated compounds

Friedel-Crafts alkylation reactions carbonyl compounds

From 2-R-Phenyl Alkyl Tellurium Compounds

From Alkyl Aryl Tellurium Compounds

Gasoline alkyl lead antiknock compounds

GeR4 Compounds with R Substituted Alkyl

Grignard reaction: alkylation with carbonyl compounds

Group 13 elements alkyl halide compounds

Halides, alkyl from aromatic compounds

Halides, alkyl from organometallic compounds

Halides, alkyl reaction with aromatic compounds

Halides, alkyl, reaction with nitro compounds

Halo-l-alkyl Organo Tellurium Compounds

Heteroaromatic compounds, alkylation

Heterocyclic compounds, alkylation

Heterogeneous Polymerization Catalysts Derived from Transition Metal Alkyl Compounds

Hydroxy Alkylation with Carbonyl Compounds

Imidazoles, l-benzyl-2-alkyl-4,5-dihydromethiodide salt reactions with organometallic compounds

Indole compounds alkyl halide reactions

Infrared spectroscopy alkylated compounds

Lead compounds tetra-alkyls

Lithium compounds alkyl or aryl

Lithium, organo- compounds alkylation

Long-chain alkyl-substituted heterocyclic compounds

Magnesium alkyl compounds

Magnesium compounds alkylation

Magnesium, organo- compounds alkylation

Mercury alkyl compounds

Mercury, organo-, compounds alkyl

Metallic alkyl compounds

Mono-alkyl compound

Niobium complexes, hexahalogeno salts and compounds with alkyl

Nitro compounds alkylation

Nitro compounds from alkyl halides

Nitro compounds reductive alkylation

Nitro compounds, aliphatic alkylation

Nitro compounds, alkylation preparation

Nitroso compounds reductive alkylation

Nomenclature alkyl compounds

Organochromium alkyl compounds

Organocopper compounds alkylation

Organocopper compounds alkylations

Organocopper compounds stereoselective alkylation

Organocopper compounds, reactions with alkyl halides

Organolithium compounds from alkyl halide reduction

Organometallic compound, coupling with alkyl halide

Organometallic compounds alkyl

Organometallic compounds alkyl group exchange

Organometallic compounds alkyl halides

Organometallic compounds coupling with alkyl

Organometallic compounds metal alkyls

Organometallic compounds reaction with alkyl halides

Organometallic compounds with alkyl halides

Organometallic compounds, 1,4-addition with alkyl-metal bonds

Organometallic compounds, also from alkyl halides

Organonickel compounds carbanion alkylations

Organotin compounds primary alkyl

Organozinc compounds alkylation

Organozinc compounds conjugate addition-alkylation

Organozinc compounds from alkyl halides

Organozinc compounds primary alkyl

Organozinc compounds secondary alkyl

Other Metal Compounds with Bridging Alkyl Groups

Pd-Catalyzed Allylic C-Alkylation of Nitro Compounds

Phosphorus, alkylation cyclic compounds

Platinum alkyl compounds

Polynuclear aromatic compounds, alkylation

Potassium alkoxides alkyl compounds

Potassium compounds alkyl halides

Potassium compounds alkylation

Prochiral compounds alkylations

Quaternary carbon compounds allylic alkylation

Reactions of Transition Metal Compounds with Alkylating or Arylating Reagents

Reactivity, alkyl halides with aromatic compounds

Reductive Alkylation of Ammonia with Carbonyl Compounds

Reductive Alkylation of Primary Amines with Carbonyl Compounds

Reductive N-Alkylation of Primary Amides with Carbonyl Compounds

Reissert compounds alkylation

Replacement in Transition Metal Alkyl Compounds and Polymerization Activity

Samarium complexes alkyl compounds

Scandium complexes alkyl compounds

Selenides, alkyl vinyl carbonyl compounds from

Silicon compounds alkylation

Silicon compounds. Friedal-Crafts alkylations

Sodium alkyl sulphates compounds)

Straight chain alkylated aromatic compounds

Substituted Alkyl Compounds

Substitutive Alkylation of a-Halocarbonyl Compounds

Sulfides, alkyl vinyl carbonyl compounds from

Sulfones, alkylation compounds

Sulfoxides, alkyl aryl reactions with carbonyl compounds

Tantalum complexes, hexahalogeno salts and compounds with alkyl

Thallium organic compounds alkyl derivatives

Transition alkyl compounds

Transition metal alkyl compounds

Transition metal alkyl compounds activity

Transition metal alkyl compounds heterogeneous polymerization catalysts

Transition metal alkyl compounds stereoregular polymerizations with

Transition metal alkyl compounds synthesis

Transition-metal organic compounds, alkyl

Transition-metal organic compounds, alkyl groups

Unsaturated compounds, alkylation

Unsaturated compounds, alkylation phosphorus

Uranium complexes, hexahalogeno salts and compounds with alkyl

Vinyl compounds alkyl substituted

Yttrium complexes alkyl compounds

Zinc compounds alkylation

Zinc compounds alkylation reactions

Zirconium complexes, hexahalogeno salts and compounds with alkyl nitriles

Zirconium compounds alkyl derivations

Zirconium compounds alkyl derivatives

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