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Reactivity, alkyl halides with aromatic compounds

Ferrocene behaves in many respects like an aromatic electron-rich organic compound which is activated toward electrophilic reactions.In Friedel-Crafts type acylation of aromatic compounds with acyl halides, ferrocene is lO times more reactive than benzene and gives yields over 80%. However, ferrocene is different from benzene in respect to reactivity and yields in the Friedel-Crafts alkylation with alkyl halides or olefins. The yields of ferrocene alkylation are often very low. and the separations of the polysubstituted byproducts are tedious. [Pg.155]

By this strategy, reactive carbon electrophiles can be generated for successful reaction with a variety of weak carbon nucleophiles. More important examples include the Friedel-Crafts reaction in which aromatic compounds (nucleophiles) react with alkyl and acyl halides (electrophiles in the presence of Lewis acids). [Pg.240]

The conventional resinsulfonic acids such as sulfonated polystyrenes (Dowex-50, Amberlite IR-112, and Permutit Q) are of moderate acidity with limited thermal stability. Therefore, they can be used only to catalyze alkylation of relatively reactive aromatic compounds (like phenol) with alkenes, alcohols, and alkyl halides. Nafion-H, however, has been found to be a suitable superacid catalyst in the 110-190°C temperature range to alkylate benzene with ethylene (vide infra) 16 Furthermore, various solid acid catalysts (ZSM-5, zeolite /3, MCM-22) are applied in industrial ethylbenzene technologies in the vapor phase.177... [Pg.554]

Alkyl chlorides and bromides, aromatic compounds containing halogen in the side chain, or nuclear-halogenated aromatic compounds with nitro groups in the ortho and/or para position, do not usually react readily at room temperature but react fairly rapidly on heating. The order of reactivity of alkyl halides is tertiary > secondary > primary, and indeed some tertiary halides may react in the cold. [Pg.1233]

Electrochemical studies are usually performed with compounds which are reactive at potentials within the potential window of the chosen medium i.e. a system is selected so that the compound can be reduced at potentials where the electrolyte, solvent and electrode are inert. The reactions described here are distinctive in that they occur at very negative potentials at the limit of the cathodic potential window . We have focused here on preparative reductions at mercury cathodes in media containing tetraalkylammonium (TAA+) electrolytes. Using these conditions the cathodic reduction of functional groups which are electroinactive within the accessible potential window has been achieved and several simple, but selective organic syntheses were performed. Quite a number of functional groups are reduced at this limit of the cathodic potential window . They include a variety of benzenoid aromatic compounds, heteroaromatics, alkynes, 1,3-dienes, certain alkyl halides, and aliphatic ketones. It seems likely that the list will be increased to include examples of other aliphatic functional groups. [Pg.98]


See other pages where Reactivity, alkyl halides with aromatic compounds is mentioned: [Pg.178]    [Pg.498]    [Pg.49]    [Pg.887]    [Pg.345]    [Pg.708]    [Pg.708]    [Pg.807]    [Pg.95]    [Pg.660]    [Pg.296]    [Pg.823]    [Pg.653]    [Pg.535]    [Pg.535]    [Pg.625]    [Pg.107]    [Pg.241]    [Pg.887]    [Pg.225]    [Pg.150]    [Pg.862]    [Pg.190]    [Pg.345]    [Pg.168]    [Pg.97]    [Pg.249]    [Pg.706]    [Pg.833]    [Pg.83]    [Pg.887]    [Pg.226]    [Pg.345]    [Pg.176]    [Pg.250]    [Pg.258]    [Pg.290]    [Pg.466]    [Pg.484]    [Pg.315]    [Pg.323]    [Pg.200]    [Pg.887]   
See also in sourсe #XX -- [ Pg.665 , Pg.679 ]




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Alkyl aromatics

Alkyl halides compounds

Alkyl halides reactivity

Alkylated aromatics

Alkylating compounds

Alkylation aromatic

Alkylation compounds

Alkylation with alkyl halides

Aromatic alkylations

Aromatic compound alkylated

Aromatic compounds alkyl

Aromatic compounds, alkylation

Aromatic halides

Aromaticity reactivity

Aromatics alkylation

Aromatics reactivity

Halides compounds

Reactive compounds

Reactivity compounds

Reactivity with

Reactivity, alkyl halides with

With alkyl halides

With aromatic compounds

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