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Aluminum compounds alkylation reactions

Organochromium Catalysts. Several commercially important catalysts utilize organ ochromium compounds. Some of them are prepared by supporting bis(triphenylsilyl)chromate on siUca or siUca-alumina in a hydrocarbon slurry followed by a treatment with alkyl aluminum compounds (41). Other catalysts are based on bis(cyclopentadienyl)chromium deposited on siUca (42). The reactions between the hydroxyl groups in siUca and the chromium compounds leave various chromium species chemically linked to the siUca surface. The productivity of supported organochromium catalysts is also high, around 8—10 kg PE/g catalyst (800—1000 kg PE/g Cr). [Pg.383]

Dicyclopentadiene is also polymerized with tungsten-based catalysts. Because the polymerization reaction produces heavily cross-Unked resins, the polymers are manufactured in a reaction injection mol ding (RIM) process, in which all catalyst components and resin modifiers are slurried in two batches of the monomer. The first batch contains the catalyst (a mixture of WCl and WOCl, nonylphenol, acetylacetone, additives, and fillers the second batch contains the co-catalyst (a combination of an alkyl aluminum compound and a Lewis base such as ether), antioxidants, and elastomeric fillers (qv) for better moldabihty (50). Mixing two Uquids in a mold results in a rapid polymerization reaction. Its rate is controlled by the ratio between the co-catalyst and the Lewis base. Depending on the catalyst composition, solidification time of the reaction mixture can vary from two seconds to an hour. Similar catalyst systems are used for polymerization of norbomene and for norbomene copolymerization with ethyhdenenorbomene. [Pg.431]

Organoaluminum Compounds. Apphcation of aluminum compounds in organic chemistry came of age in the 1950s when the direct synthesis of trialkylalurninum compounds, particularly triethylalurninum and triisobutylalurninum from metallic aluminum, hydrogen, and the olefins ethylene and isobutylene, made available economic organoalurninum raw materials for a wide variety of chemical reactions (see a-BONDED alkyls and aryls). [Pg.137]

Aluminum alkyls react by the Ziegler reaction with the least substituted double bond to give the tricitroneUyl aluminum compound. Oxidation of the iatermediate compound then produces the tricitroneUyl aluminate, which is easily hydroly2ed with water to give citroneUol (112,113). If the citroneUene is opticaUy active, opticaUy active citroneUol can be obtained (114). The (—)-citroneUol is a more valuable fragrance compound than the ( )-citroneUol. [Pg.419]

An important use of the Friedel-Crafts alkylation reaction is to effect ring closure. The most common method is to heat with aluminum chloride an aromatic compound having a halogen, hydroxy, or alkene group in the proper position, as, for example, in the preparation of tetralin ... [Pg.710]

In this section, the reactivities of organosilicon compounds for the Friedel-Crafts alkylation of aromatic compounds in the presence of aluminum chloride catalyst and the mechanism of the alkylation reactions will be discus.sed, along with the orientation and isomer distribution in the products and associated problems such as the decomposition of chloroalkylsilanes to chlorosilanes.. Side reactions such as transalkylation and reorientation of alkylated products will also be mentioned, and the insertion reaction of allylsilylation and other related reactions will be explained. [Pg.146]

In the case of alkylation using allylsilancs in the presence of aluminum chloride as a catalyst, allylsilanes containing one or more chlorine substituents on the silicon react with aromatic compounds at room temperature or below 0 C to give alkylated products. 2-aryl-1 -silylpropanes.- while allyltrimethylsilane did not give the alkylated product but instead dimerized to give the allylsilylation product.. S-itrimethylsilyli-d-itrimethylsilylrnethyl)- 1-pentene (Eq. (1 )). In the alkylation reaction, the reactivity of allylsilanes increased as the number of chlorine... [Pg.146]

Nickel(O) reacts with the olefin to form a nickel(0)-olefin complex, which can also coordinate the alkyl aluminum compound via a multicenter bond between the nickel, the aluminum and the a carbon atom of the trialkylaluminum. In a concerted reaction the aluminum and the hydride are transferred to the olefin. In this mechanistic hypothesis the nickel thus mostly serves as a template to bring the olefin and the aluminum compound into close proximity. No free Al-H or Ni-H species is ever formed in the course of the reaction. The adduct of an amine-stabihzed dimethylaluminum hydride and (cyclododecatriene)nickel, whose structure was determined by X-ray crystallography, was considered to serve as a model for this type of mechanism since it shows the hydride bridging the aluminum and alkene-coordinated nickel center [31]. [Pg.52]

The patent literature contains several references to the use of sulfoxide complexes, usually generated in situ, as catalyst precursors in oligomerization and polymerization reactions. Thus, a system based upon bis(acrylonitrile)nickel(0> with added Me2SO or EtgSO is an effective cyclotrimerization catalyst for the conversion of butadiene to cyclo-1,5,-9-dodecatriene (44). A similar system based on titanium has also been reported (407). Nickel(II) sulfoxide complexes, again generated in situ, have been patented as catalyst precursors for the dimerization of pro-pene (151) and the higher olefins (152) in the presence of added alkyl aluminum compounds. [Pg.160]

A reaction in which an electrophile participates in het-erolytic substitution of another molecular entity that supplies both of the bonding electrons. In the case of aromatic electrophilic substitution (AES), one electrophile (typically a proton) is substituted by another electron-deficient species. AES reactions include halogenation (which is often catalyzed by the presence of a Lewis acid salt such as ferric chloride or aluminum chloride), nitration, and so-called Friedel-Crafts acylation and alkylation reactions. On the basis of the extensive literature on AES reactions, one can readily rationalize how this process leads to the synthesis of many substituted aromatic compounds. This is accomplished by considering how the transition states structurally resemble the carbonium ion intermediates in an AES reaction. [Pg.225]

Several authors have studied the reaction products in the Lewis acid catalyzed decomposition of phenyl and alkyl azides.179-185 Hoegerlee and Butler have found that phenyl azide forms a hydrocarbon-soluble complex at —70° with triethylaluminum, diethylchloroaluminum, and ethyldichloro-aluminum. 1 Upon warming to room temperature, this complex slowly decomposes into an intermediate phenylimine-aluminum compound (25) which then rearranges into a variety of amidoalkylaluminum reaction products (RP) (eq 4). [Pg.7]

Telraorganotins, RaSn, prepared either by alkylation of tin halides with Grignard Reagents or alkyl lithium by reaction of an organic halide with a tin-sodium alloy by direct reaction of tin with an organic halide or by reaction of stannic chloride with alkyl aluminum compounds. [Pg.1618]

Alumina, in alkynol hydration-dehydration reactions, 6, 841 Aluminate organic liquids, characteristics, 1, 852 Alumination, direct, aromatic rings, 9, 267 Aluminum(III) alkyl compounds... [Pg.52]

Concomitant with continued olefin insertion into the metal-carbon bond of the titanium-aluminum complex, alkyl exchange and hydrogen-transfer reactions are observed. Whereas the normal reduction mechanism for transition-metal-organic complexes is initiated by release of olefins with formation of hydride followed by hydride transfer (184, 185) to an alkyl group, in the case of some titanium and zirconium compounds a reverse reaction takes place. By the release of ethane, a dimetalloalkane is formed. In a second step, ethylene from the dimetalloalkane is evolved, and two reduced metal atoms remain (119). [Pg.131]

With increasing temperature the As-B adducts convert to the N-B adduct, except for the i-Pr compound, which is stable at room temperature, and decomposition leads to the formation 0fMe2AsAsMc2, Mc2AsH, [R2NBH2]2, andR2NH-BH3. The results from the aluminum alkyl reactions have been used to develop new syntheses to tertiary arsines (see Section 2). [Pg.261]


See other pages where Aluminum compounds alkylation reactions is mentioned: [Pg.212]    [Pg.515]    [Pg.551]    [Pg.367]    [Pg.339]    [Pg.840]    [Pg.87]    [Pg.708]    [Pg.146]    [Pg.167]    [Pg.232]    [Pg.282]    [Pg.274]    [Pg.345]    [Pg.98]    [Pg.50]    [Pg.644]    [Pg.182]    [Pg.113]    [Pg.454]    [Pg.371]    [Pg.287]    [Pg.237]    [Pg.118]    [Pg.40]    [Pg.100]    [Pg.116]    [Pg.50]    [Pg.24]    [Pg.282]    [Pg.2957]    [Pg.47]   
See also in sourсe #XX -- [ Pg.599 , Pg.600 , Pg.601 , Pg.602 ]




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Aluminum compounds alkylation

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