Additives biocides

Other additives Biocides Prevent growth of microorganisms... 

Use Disinfectant, cleanser and sterilizer, cosmetics (deodorants, dandruff removers, emulsion stabilizers), fungicides, mildew control, to increase affinity of dyes for film in photography, coating of pigment particles to improve dispersibility, to increase adhesion of road dressings and paints, antistatic additive, biocide. 

This article looks at the challenges involved in the development of anti-fouling paint for marine appUcations, and also on the use of additional biocides in the pairrts. It describes experimentation carried out on nine biocides on the market today, and discusses the results. 15 refs. EUROPEAN COMMUNITY EUROPEAN UNION ITALY WESTERN EUROPE... 

A biocidal gel composition for treating water containing systems comprises polyethylene glycols andbisftrichloro methyl) sulphone in combination with additional biocidal components. 

A suitable latex stabilizer is essential in view of the high filler content. The cellulose thickener aids spreading by retarding loss of water into concrete or other porous substrates. Zinc diethyldithiocaibamate serves the dual function of antioxidant and fiingicide/bactericide, but additional biocide is advisable for use under adverse conditions. 

Precaution Combustible can react with oxidizers Uses Chemical intermediate raw material for n-octylpyrrolidone (a solvent for agric. chems., org. pigments), corrosion inhibitors, lubricant additives, biocides, surfactants... 

In addition to their antiknock properties, organic lead compounds possess bactericidal properties and motor fuels with lead are known to inhibit bacterial growth during storage in contact with water. With the disappearance of lead-based compounds, it is necessary to incorporate biocides from the cyclic imine family, (piperidine, pyrrolidine, hexamethyleneimine), alkylpropylene diamines or imidazolines (Figure 9.2). 

Examples of biocide agents used as motor fuel additives. 

In addition to its ptincipal use in biocide formulations (94), glutaialdehyde has been used in the film development and leather tanning industries (95). It may be converted to 1,5-pentanediol [111 -29-5J or glutaric acid [110-94-1]. 

Resistance to antimicrobial agents is of concern as it is well known that bacterial resistance to antibiotics can develop. Many bacteria already derive some nonspecific resistance to biocides through morphological features such as thek cell wall. Bacterial populations present as part of a biofilm have achieved additional resistance owkig to the more complex and thicker nature of the biofilm. A system contaminated with a biofilm population can requke several orders of magnitude more chlorine to achieve control than unassociated bacteria of the same species. A second type of resistance is attributed to chemical deactivation of the biocide. This deactivation resistance to the strong oxidising biocides probably will not occur (27). 

Papermaking additives can be categorized either as process additives or as functional additives. Process additives are materials that improve the operation of the paper machine, such as retention and drainage aids, biocides, dispersants, and defoamers they are primarily added at the wet end of the paper machine. Functional additives are materials that enhance or alter specific properties of the paper product, such as fillers (qv), sizing agents, dyes, optical brighteners, and wet- and dry-strength additives they may be added internally or to the surface of the sheet. 

The production of alkylphenols exceeds 450,000 t/yr on a worldwide basis. Alkylphenols of greatest commercial importance have alkyl groups ranging in size from one to twelve carbons. The direct use of alkylphenols is limited to a few minor appUcations such as epoxy-curing catalysts and biocides. The vast majority of alkylphenols are used to synthesize derivatives which have appUcations ranging from surfactants to pharmaceuticals. The four principal markets are nonionic surfactants, phenoUc resins, polymer additives, and agrochemicals. 

Monofunctional, cyclohexylamine is used as a polyamide polymerization chain terminator to control polymer molecular weight. 3,3,5-Trimethylcyclohexylamines ate usehil fuel additives, corrosion inhibitors, and biocides (50). Dicyclohexylamine has direct uses as a solvent for cephalosporin antibiotic production, as a corrosion inhibitor, and as a fuel oil additive, in addition to serving as an organic intermediate. Cycloahphatic tertiary amines are used as urethane catalysts (72). Dimethylcyclohexylarnine (DMCHA) is marketed by Air Products as POLYCAT 8 for pour-in-place rigid insulating foam. Methyldicyclohexylamine is POLYCAT 12 used for flexible slabstock and molded foam. DM CHA is also sold as a fuel oil additive, which acts as an antioxidant. StericaHy hindered secondary cycloahphatic amines, specifically dicyclohexylamine, effectively catalyze polycarbonate polymerization (73). 

Tackifiers are used to increase the tackiness and the setting speed of adhesives. They increase tackiness by softening the poly(vinyl acetate) polymer in the wet and the dry adhesive film. Tackifiers are usually rosin or its derivatives or phenoHc resins. Other additives frequently needed for specific apphcation and service conditions are antifoams, biocides, wetting agents, and humectants. 

Chlorine is desirable as a bulk pretreatment biocide for inlet water, but its subsequent removal upstream of the membrane is absolutely necessary ana difficult. NaHSO,3 is a common additive to dechlorinate before membranes. It is customarily added at 3-5 mg/1, an excess over the stoichiometric requirement. NH3 is sometimes added to convert the chlorine to chloramine, a much less damaging biocide. Heavy metals present in seawater seem to amplify the damaging effects of chlorine and other oxidants. 

Metalworking fluids contain mineral oils (refer to p. 80) or synthetic lubricants they are used neat or in admixture with water. They may contain small amounts of biocides, stabilizers, emulsifiers, coiTosion inhibitors, fragrances and extreme pressure additives. The formulations render them suitable for application to metal being worked, generally from a recirculatory system, to provide lubrication, corrosion protection, swarf removal and cooling of the tool and machined surface. 

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