A-Cellulose

Fig. 2a. Examples of caibohydiate polymers with intemnit and branch position differences (a) cellulose (b) flaxseed gum (c) guaran (d) C-6 hydroxyl ...

Neste patented an industrial route to a cellulose carbamate pulp (90) which was stable enough to be shipped into rayon plants for dissolution as if it were xanthate. The carbamate solution could be spun into sulfuric acid or sodium carbonate solutions, to give fibers which when completely regenerated had similar properties to viscose rayon. When incompletely regenerated they were sufficientiy self-bonding for use in papermaking. The process was said to be cheaper than the viscose route and to have a lower environmental impact (91). It has not been commercialized, so no confirmation of its potential is yet available. 

Hollow Fiber with Sorbent Walls. A cellulose sorbent and dialy2ing membrane hoUow fiber was reported in 1977 by Enka Glan2stoff AG (41). This hoUow fiber, with an inside diameter of about 300 p.m, has a double-layer waU. The inner waU consists of Cuprophan ceUulose and is very thin, approximately 8 p.m. The outer waU, which is ca 40-p.m thick, consists mainly of sorbent substance bonded by ceUulose. The advantage of such a fiber is that it combines the principles of hemodialysis with those of hemoperfusion. Two such fibers have been made one with activated carbon in the fiber waU, and one with aluminum oxide, which is a phosphate binder (also see Dialysis). 

Composite-Based Laminates. Grade CEM-1 are laminates with continuous-filament glass cloth surfaces and a cellulose core, all with a flame-resistant epoxy resin binder. With good punching practice, sheets up to and including 2.4 mm (0.094 in.) in thickness may be punched at temperatures not less than 23°C (73°F). These laminates meet UL94 V-0 when tested in accordance with UL94. 

Fiber Slurry Pipelines. Pipelines to carry suspensions of wood, paper, sludge, etc, have found commercial acceptance. Most of them are less than 15 km long but have diameters of up to 500 mm. These slurries are often concentrated and display viscous plastic properties, although particle sizes may vary special pumps are used. One such hydrotransport system carries a cellulose slurry by pipeline from the plant to a paper plant near Heidenau, Germany. The 250-mm dia pipeline carries 60 t/d over the 3-km distance to thickeners. In Sweden, a 3.7-km, 500-mm dia pipeline moves cellulose by... 

The one-pass system consists of a feed tank, filter, pump, and membrane system (Fig. 6). The feed tank contains whiskey at approximately 100° proof. It is filtered through a cellulose filter and then pumped into the membrane system where the separation takes place. Dupont B-10 A ram id hoUow fiber membranes are used in series or parallel and are able to withstand the high pressures, 689—1034 kPa (6.8—10 atm), necessary to achieve separation. 

Plant stmctural material is the polysaccharide cellulose, which is a linear P (1 — 4) linked polymer. Some stmctural polysaccharides iacorporate nitrogen iato thek molecular stmcture an example is chitin, the material which comprises the hard exoskeletons of kisects and cmstaceans. Chitki is a cellulose derivative whereki the OH at C-2 is replaced by an acetylated amino group (—NHCOCH ). Microbial polysaccharides, of which the capsular or extracellular (exopolysaccharides) are probably the most important class, show more diversity both ki monomer units and the nature of thek linkages. 

EthylceUulose [9004-57-3], a cellulose either (qv), as prepared commercially, ie, of high DS, is thermoplastic and has alow density (1.14 g/cm ). It forms films of good thermostabiUty and excellent flexibiUty and toughness. EthylceUulose is used in lacquers, inks, and adhesives and is combined with waxes and resins in the preparation of hot-melt plastics. It is also used as a pharmaceutical tablet binder. 

Fig. 1. A segment of a cellulose chain composed of four P-D-glucopyianose residues (ceUotetiaose), showing (a) the chemical bonds and election clouds around the atoms. The molecule has the twofold hehcal conformation typical of many models of crystalline cellulose, (b) The (Haworth) stmctural formula...

In one process to produce highly activated cellulose for acetylation, cellulose is treated with NaOH (mercerization) followed by a hydroxyalkylating agent, eg, ethylene oxide or propylene oxide, to give a cellulose hydroxyalkyl ether with a DS of 0.05—0.3 (76). The resulting water-insoluble material is highly reactive to conventional acetic anhydride—sulfuric acid acetylation. 

This includes organic fibrous materials on a cellulose base such as paper, pressboard, cotton, cotton cloth and natural silk etc., impregnated with lacquers or immersed in an insulating liquid. The impregnation or immersion ensures that the oxygen content of the air does not affect... 

Hydroxynaphthol Blue tri-Na salt [63451-35-4] M 620.5, m dec on heating, pKE,t <0. Crude material was treated with hot EtOH to remove soluble impurities, then dissolved in 20% aqueous MeOH and chromatographed on a cellulose powder column with propanol EtOH water (5 5 4) as eluent. The upper of three zones was eluted to give the pure dye which was ppted as the monosodium salt trihydrate by adding cone HCl to the concentrated eluate [Ito and Ueno zfna/ysr 95 583 1970. ... 

Porphyrin a (from ox heart) [5162-02-1] M 799.0, m dec on heating. Purified on a cellulose powder column followed by extraction with 17% HCl and fractionation with HCl. [Morell et al. Biochem J 78... 

Therefore a fully substituted derivative would have a degree of substitution of 3.0 whilst a cellulosic material in which on average 1.8 hydroxyl groups per glucose unit had been replaced would have a degree of substitution of 1.8. Commercial derivatives usually have a degree of substitution of less than 3.0, the actual value chosen being determined by the end-use. 

The nitration bath normally contains sulphuric acid as a condensing agent and a typical bath for producing a cellulose nitrate with a nitrogen content of 11 % would be... 

Reaction of alkali cellulose with carbon disulphide to produce a cellulose xanthate which forms a lyophilic sol with caustic soda. This may be extruded into a coagulating bath containing sulphate ions which hydrolyses the xanthate back to cellulose. This process is known as the viscose process and is that used in the manufacture of rayon. 

Figure 24.9. Effect of cure time on some properties of M-F mouldings. Cure temperature cellulose filled 295-308°F mineral filled 300-320°F O glass-filled material, asbestos-filled material, A cellulose-filled material (a) Cross-breaking strength (b) tensile strength (c) impact strength (d) impact strength (e) water absorption (rag), boiling water 30 min (f) cold water 24 h, 23°C ...

M. Tanaka and H. Yamazaki, Dkect detemination of pantoprazole enantiomers in human serum by reversed-phase liigh peifomance liquid chi omatography using a cellulose-based cliiral stationaiy phase and column-switching system as a sample cleanup procedure , Aim/. Chem. 68 1513-1516(1996). 

Cellit, n. cellite (a cellulose acetate), cellonieren, v.t. treat with Cellon-Lack. Cellon-Lack, m. a cellulose acetate Lacquer. T. N. 

In this context, the enantiomeric pair containing the eutomer of cyclothiazide can be resolved by HPLC on cellulose-derived coated CSPs. Nevertheless, the poor solubility of this compound in solvents compatible with this type of support makes this separation difficult at preparative scale. This operation was achieved with a cellulose carbamate fixed on allylsilica gel using a mixture of toluene/acetone as a mobile phase [59]. 

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