Plastic properties

It is very important, from one hand, to accept a hypothesis about the material fracture properties before physical model building because general view of TF is going to change depending on mechanical model (brittle, elasto-plastic, visco-elasto-plastic, ete.) of the material. From the other hand, it is necessary to keep in mind that the material response to loads or actions is different depending on the accepted mechanical model because rheological properties of the material determine type of response in time. The most remarkable difference can be observed between brittle materials and materials with explicit plastic properties. 

Figure 4. Explicit plastic properties material AE responses as count velocity N and logarithm spectrum log(S) characteristics of the process.

Fiber Slurry Pipelines. Pipelines to carry suspensions of wood, paper, sludge, etc, have found commercial acceptance. Most of them are less than 15 km long but have diameters of up to 500 mm. These slurries are often concentrated and display viscous plastic properties, although particle sizes may vary special pumps are used. One such hydrotransport system carries a cellulose slurry by pipeline from the plant to a paper plant near Heidenau, Germany. The 250-mm dia pipeline carries 60 t/d over the 3-km distance to thickeners. In Sweden, a 3.7-km, 500-mm dia pipeline moves cellulose by... 

Di-2-EthylhexylPhthalate. In Western Europe, di-2-ethylhexyl phthalate [117-81-7] (DEHP), also known as dioctyl phthalate (DOP), accounts for about 50% of all plasticizer usage and as such is generally considered as the industry standard. The reason for this is that it is in the mid-range of plasticizer properties. DEHP (or DOP) is the phthalate ester of 2-ethyIhexanol, which is normally manufactured by the dimerization of butyraldehyde (eq. 2), the butyraldehyde itself being synthesized from propylene (see Butyraldehydes). 

Poly(ethylene terephthalate). PET is a crystalline material and hence difficult to plasticize. Additionally, since PET is used as a high strength film and textile fiber, plasticization is not usually required although esters showing plasticizing properties with PVC may be used in small amounts as processing aids and external lubricants. Plasticizers have also been used to aid the injection mol ding of PET, but only at low concentrations. 

A neutral bacterial endoprotease can be used to weaken the gluten in wheat flour, if necessary, or to provide the plastic properties required ia a dough used for biscuits. 

Chemical nature Isolation of casein from milk Production of casein plastics Properties of casein Applications Miscellaneous Protein Plastics Derivatives of Natural Rubber Gutta Percha and Related Materials Shellac... 

Habermehl, D., Orywal, F., and Beyer, H. D., Plastic properties of coal. In Chemistry cf Coat Utilization, Second Supplementary Volume, ed. M. A. Elliot. John Wiley and Sons, Inc., New York, 1981, PP-317 368... 

Australia, is the doyen of materials scientists who study the elastic and plastic properties of minerals under hydrostatic pressure and also phase stability under large shear stresses (Paterson 1973). J.-P. Poirier, in Paris, a professor of geophysics, was trained as a metallurgist one of his special skills is the use of analogue materials to help understand the behaviour of inaccessible high-pressure polymorphs, e.g., CaTi03 perovskite to stand in for (Mg, FelSiOi in the earth s mantle (Poirier 1988, Besson el al. 1996). 

Fig. 2. Schematic of energy dissipation in a commonly used peel test. The energy dissipation can occur in the adhesive and/or the adherends. The extent of energy dissipation depends on the elasto-plastic properties of the adhesive and the adherends under the test conditions as well as the local stresses and strains near the crack tip.

Plasticity Property of plastics that permits the material to undergo deformation permanently and continuously without rupture from a force that exceeds the yield value of the material. 

To any one concerned with the production of plasticized resins, compatibility has long meant the ability of two or more materials to mix with each other to form a homogeneous composition of useful desired plastic properties [44,45]. A plasticizer, therefore, can be defined as a material that will soften and make inherently rigid and even brittle polymers flexible. Plasticizers are also sometimes... 

Polyphosphates are also an important class of organophosphorus polymers. In addition to their flame-retardant characteristics, they possess attractive plasticizing properties and can be used as polymeric additives to other polymers [123-128]. In general, polyphosphates can be prepared by interfacial [119,129], melt [130], or solution polycondensation [131,132a,b]. Kricheldorf and Koziel [133] prepared polyphosphates from silylated bisphenols. 

Zhong et al. [12] also studied the plasticizing properties of the PVC/TPU blending system by measuring the torque (TQ) during plasticating. 

The basic alloy at atmospheric pressure and T = 20°C demonstrated the per cent elongation <5 = 31% and the per cent reduction ip = 65% while plastic properties of the hydrogenated alloy were close to zero. But an opposite relation was observed in tensile tests under a pressure of 6.5 kbar. The plastic properties of the hydrogenated alloy increased to <5 = 33% and /> = 83% at P = 6.5 kbar and T = 20°C while those of the basic alloy changed only slightly (Fig. 11). 

Montmorillonite clays absorb water readily, swell greatly and confer highly plastic properties to a soil. Thus soil stress (Section 14.8) occurs most frequently in these soils and less commonly in predominantly kaolinitic types. Similarly, a soil high in bentonite will show more aggressive corrosion than a soil with a comparable percentage of kaolinite. A chalky soil usually shows low corrosion rates. Clay mineralogy and the relation of clays to corrosion deserves attention from corrosion engineers. Many important relationships are not fully understood and there is need for extensive research in this area. 

Viscoelastic and rate theory To aid the designer the viscoelastic and rate theories can be used to predict long-term mechanical behavior from short-term creep and relaxation data. Plastic properties are generally affected by relatively small temperature changes or changes in the rate of loading application. 

In conclusion regarding creep testing, it can be stated that creep data and a stress-strain diagram indicate whether plain plastic properties can lead to practical product dimensions or whether a RP has to be substituted to keep the design within the desired proportions. For long-term product use under continuous load, plastic materials have to consider creep with much greater care than would be the case with metals. 

In addition to the broad categories of TPs and TSs, TPs can be further classified in terms of their structure, as either crystalline, amorphous, or liquid crystalline. Other classes (terms) include elastomers, copolymers, compounds, commodity resins, engineering plastics, or neat plastics. Additives, fillers, and reinforcements are other classifications that relate directly to plastics properties and performance. 

Fig. 6-9 Example of how alloying affects plastic properties curves reflect four different blends.

Fig. 6-10 ABS terpolymer properties are shown influencing individual constituent plastic properties.

The plastics properties catalogue includes single-point data, multi-point data, processing data, product description texts and customer service information. You can select plastic products for your specific application by using the query options. The main feature of the CAMPUS philosophy is comparable data. The properties are based on the international standards ISO 10350 for Single-Point data and ISO 11403-1, -2 for Multi-Point data. CAMPUS is available in English, German, Spanish, French and Japanese. 

CAMPUS , the database of Bayer plastic properties can also be downloaded from this web page. 

Asbestos It is not the name of a distinct mineral species but is a commercial term applied to fibrous varieties of several silicate minerals such as amosite and crocido-lite. These extremely fine fibers are useful as fillers and/or reinforcements in plastics. Property performances include withstanding wear and high temperatures, chemical resistance, and strengths with high modulus of elasticity. When not properly handled or used, like other fibrous materials, they can be hazardous. 

As a result of simultaneous introduction of elastic, viscous and plastic properties of a material, a description of the actual state functions involves the history of the local configuration expressed as a function of the time and of the path. The restrictions, which impose the second law of thermodynamics and the principle of material objectivity, have been analyzed. Among others, a viscoplastic material of the rate type and a strain-rate sensitive material have been examined. 

But neutralized phosphorous acid monoesters of alcohols were found to have detergent and plasticizing properties [60,74]. They can be obtained by reaction of phosphorous trichloride and fatty alcohols in equimolar ratios followed by saponification of the unreacted chlorine atoms of the dichlorophosphites with a base see Eqs. (26) and (27). 

An application of fire retardants in plastics solves the problem of plastics flammability efficiently but usually creates problems with plastics processing and with plastics properties. In this paper we intend to evaluate various solutions to these problems. 

---