Wetting external

As long as fuel cells are using liquid electrolytes like phosphoric acid or concentrated caustic potash, the catalyst utilization is usually not limited by incomplete wetting of the catalyst. Provided the amount of electrolyte is sufficiently high, the hydrophilic porous particles are not only completely flooded but due to their expressed hydrophilicity are wetted externally by an electrolyte film that together with the whole electrolyte-filled hydrophilic pore system establishes the ionic contact of an electrode to the respective counterelectrode. 

Theory and practice were closely entwined for the Arabic alchemists of the eighth and ninth centuries. They asserted that every substance contained its opposite, in a hidden, or occult, way. Silver was cold and dry externally, but hot and wet internally. Gold was hot and wet externally, but cold and dry internally. In order to make gold one therefore needed to exchange the internal and external qualities of silver. 

The term Z-aws represents the ratio of the actively wetted external catalyst area per unit volume of reactor,while ag represents the gas-to-liquid mass transfer interfacial area per unit volume of reactor. 

External surface area of particle per unit volume, m /m. Wetted external area of particles per unit volume of reactor, m /m. ... 

For the case of HDM reaction, liquid catalyst wetting efficiency was used first in an att pt to obtain the apparent kinetic reaction rate coefficient, but no effect of space velocity was observed on k pp as compared with the approach without using wetting efficiency factor. This behavior was attributed to the minimization of external mass-transfer gradients as was mentioned in the experimental section. Dudukovid (1977) has pointed out that if kinetic regime prevails, there is no marked influence of the degree of wetted external area as is confirmed in this approach. 

Hydrolysis of benzyl cyanide to phenylacetamide. In a 1500 ml. three-necked flask, provided with a thermometer, reflux condenser and efficient mechanical stirrer, place 100 g. (98 ml.) of benzyl]cyanide and 400 ml. of concentrated hydrochloric acid. Immerse the flask in a water bath at 40°. and stir the mixture vigorously the benzyl cyanide passes into solution within 20-40 minutes and the temperature of the reaction mixture rises to about 50°, Continue the stirring for an additional 20-30 minutes after the mixture is homogeneous. Replace the warm water in the bath by tap water at 15°, replace the thermometer by a dropping funnel charged with 400 ml. of cold distilled water, and add the latter with stirring crystals commence to separate after about 50-75 ml. have been introduced. When all the water has been run in, cool the mixture externally with ice water for 30 minutes (1), and collect the crude phenylacetamide by filtration at the pump. Remove traces of phenylacetic acid by stirring the wet sohd for about 30 minutes with two 50 ml. portions of cold water dry the crystals at 50-80°. The yield of phenylacetamide, m.p. 154-155°, is 95 g. RecrystaUisation from benzene or rectified spirit raises the m.p. to 156°. 

An emulsion system in which the propellant is in the external or continuous phase is shown in Figure 2b. As the Hquefied propellant vaporizes, it escapes direcdy into the atmosphere, leaving behind droplets of the formulation which are emitted as a wet spray. This system is typical of many water-based aerosols or w/o emulsions. 

This carbon dioxide-free solution is usually treated in an external, weU-agitated liming tank called a "prelimer." Then the ammonium chloride reacts with milk of lime and the resultant ammonia gas is vented back to the distiller. Hot calcium chloride solution, containing residual ammonia in the form of ammonium hydroxide, flows back to a lower section of the distiller. Low pressure steam sweeps practically all of the ammonia out of the limed solution. The final solution, known as "distiller waste," contains calcium chloride, unreacted sodium chloride, and excess lime. It is diluted by the condensed steam and the water in which the lime was conveyed to the reaction. Distiller waste also contains inert soHds brought in with the lime. In some plants, calcium chloride [10045-52-4], CaCl, is recovered from part of this solution. Close control of the distillation process is requited in order to thoroughly strip carbon dioxide, avoid waste of lime, and achieve nearly complete ammonia recovery. The hot (56°C) mixture of wet ammonia and carbon dioxide leaving the top of the distiller is cooled to remove water vapor before being sent back to the ammonia absorber. 

Docusate calcium is used both as a fecal softening agent and an emulsifier, ie, a wetting or dispersing agent for external preparations (see Emulsions). 

Plasticization, whether internal (by copolymerization) or external (with additives), is also extremely important for proper performance at the time of apphcation. The ease of coalescence and the wetting characteristics of the polymer emulsion particles are related to their softness and the chemical nature of the plasticizer. 

Based on dryer cost alone, indirect-heat dryers are more expensive to build and install than direct-heat dryers designed for the same duty. As environmental concerns and resulting restrictions on process emissions increase, however, indirect-heat dryers are more attractive because they employ purge gas only to remove vapor and not to transport heat as well. Dust and vapor recovery systems for indirect-heat dryers are smaller and less cosdy to supply heat for drying, gas throughput in direct-heat dryers is 3—10 kg/kg of water evaporated indirect-heat dryers require only 1—1.5 kg/kg of vapor removed. System costs vary directly with size, so whereas more money may be spent for the dryer, much more is saved in recovery costs. Wet scmbbers ate employed for dust recovery on indirect-heat dryers because dryer exit gas usually is close to saturation. Where dry systems are employed, all external surfaces must be insulated and traced to prevent vapor condensation inside. 

Example 7 Radiation in Gases Flue gas containing 6 percent carbon dioxide and 11 percent water vapor by volume (wet basis) flows through the convection bank of an oil tube stiU consisting of rows of 0.102-m (4-in) tubes on 0.203-m (8-in) centers, nine 7.62-m (25-ft) tubes in a row, the rows staggered to put the tubes on equilateral triangular centers. The flue gas enters at 871°C (1144 K, 1600°F) and leaves at 538°C (811 K, 1000°F). The oil flows in a countercurrent direction to the gas and rises from 316 to 427°C (600 to 800°F). Tube surface emissivity is 0.8. What is the average heat-input rate, due to gas radiation alone, per square meter of external tube area ... 

Vertical Pumps In the chemical industiy, the term vertical process pump (Fig. 10-40) generally applies to a pump with a vertical shaft having a length from drive end to impeller of approximately 1 m (3.1 ft) minimum to 20 m (66 ft) or more. Vertical pumps are used as either wet-pit pumps (immersed) or dry-pit pumps (externally mounted) in conjunction with stationaiy or mobile tanlcj... 

Aluminum is not embrittled by low temperatures and is not subject to external corrosion when exposed to normal atmospheres. At 200°C (400°F) its strength is less than half that at room temperature. It is attacked by alkahes, by traces of copper, nickel, mercuiy, and other heaw-metal ions, and by prolonged contact with wet insiilation. It suffers from galvanic corrosion when coupled to copper, nickel, or lead-... 

Circffiation and heat transfer in this type of evaporator are strongly affected by the liquid level. Highest heat-transfer coefficients are achieved when the level, as indicated by an external gauge glass, is only about halfway up the tubes. Shght reductions in level below the optimum result in incomplete wetting of the tube walls with a consequent increased tendency to foul and a rapid reduction in capacity. When this type of evaporator is used with a liquid that can deposit salt or scale, it is customary to operate with the liquid level appreciably higher than the optimum and usually appreciably above the top tube sheet. 

External Conditions The principal external variables involved in any drying study are temperature, humidity, air flow, state of subdivision of the solid, agitation of the solid, method of supporting the solid, and contact between hot surfaces and wet solid. Alf these variables will not necessarily occur in one problem. 

Spray Dryers A spray diyer consists of a large cyhndrical and usu ly vertical chamber into which material to be dried is sprayed in the form of small droplets and into which is fed a large volume of hot gas sufficient to supply the heat necessary to complete evaporation of the liquid. Heat transfer and mass transfer are accomphshed by direct contact of the hot gas with the dispersed droplets. After completion of diying, the cooled gas and solids are separated. This may be accomplished partially at the bottom of the diying chamber by classification and separation of the coarse dried particles. Fine particles are separated from the gas in external cyclones or bag collectors. When only the coarse-particle fraction is desired for fini ed product, fines may be recovered in wet scrubbers the scrubber liquid is concentrated and returned as feed to the diyer. Horizontal spray chambers are manufactured with a longitudinal screw conveyor in the bottom of the diying chamber for continuous removal of settled coarse particles. 

Figure 16-49 [Engineering Data Book, 10th ed., Gas Processors Slippers Association, Tulsa, 1988, Sec. 20, p. 22] depicts the flow scheme for a typical two-bed TSA dryer system showing the auxiliary equipment associated with regeneration. Some of the diy product gas is externally heated and used couutercurreutly to heat and desorb water from the adsorber not currently drying feed. The wet, spent regeneration gas is cooled the water is condensed out and the gas is recycled to feed for recovery.

Eliminate turned-down vents from safety relief valves, i.e., upside down U. Possible accidental ignition of releases from such vents wiU likely result in flame impingement on the top external surface of the tank, above the internal wetted surface. BLEXT Some means to handle rainwater from a desirable upward vertical vent have been listed by Bodurtha (ibid., April 1988). Moreover, a safety relief valve must function properly when required and must be sized properly to help prevent an explosion. 

Environment Internal Untreated river water External Wet steam, pH 9.0-9.6... 

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