Thermoplastic ductility

The use of elastomeric modifiers for toughening thermoset resias generally results ia lowering the glass transition temperature, modulus, and strength of the modified system. More recendy, ductile engineering thermoplastics and functional thermoplastic oligomers have been used as modifiers for epoxy matrix resias and other thermosets (12). 

In most cases thermoplastic components are designed for use at room temperature. It might appear, therefore, that data on the impact properties at this temperature (approximately 20°C) would provide sufficient information for design. However, this approach would be rather naive since even indoors, temperatures may vary by an amount which can have a significant effect on impact behaviour. For components used outdoors of course, the situation can be much worse with conditions varying from sub-zero to tropical. In common with metals, many plastics exhibit a transition from ductile behaviour to brittle as the temperature is reduced. 

Moore, D.R., Hooley, C.J. and Whale, M. Ductility factors for thermoplastics. Plastics and Rubber Proc. and Appl. 1(1981) p 121-127. 

Thermoplastic 0.9-1.2 Marginal Yes Cloudy 1500-3000 700-1000 Ductile Easy Molded parts... 

Kikuchi Y., Eukui T., Okada T., and Inoue T. Origin of rubber elasticity in thermoplastic elastomers consisting of crossUnked rubber particles and ductile matrix, J. Appl. Polym. Sci., Appl. Polym. Symp., 50, 261, 1992. 

The ductility of GRT-polyethylene blends drastically decreases at ground rubber concentration in excess of 5%. The inclusion of hnely ground nitrile rubber from waste printing rollers into polyvinyl chloride (PVC) caused an increase in the impact properties of the thermoplastic matrix [76]. Addition of rubber powder that is physically modihed by ultrasonic treatment leads to PP-waste ethylene-propylene-diene monomer (EPDM) powder blends with improved morphology and mechanical properties [77]. 

Creep leads ultimately to rupture, referred to as creep-rupture, stress-rupture or static fatigue. Creep-rupture of thermoplastics can take three different forms brittle failure at low temperatures and high strain rates ductile failure at intermediate loads and temperatures and slow, low energy brittle failure at long lifetimes. It is this transition back to brittle failure that is critical in the prediction of lifetime, and it is always prudent to assume that such a transition will occur [1], A notch or stress concentration will help to initiate failure. 

If a ductile matrix is reinforced with brittle fibers as in most thermoplastic and metal matrix composites, the matrix forms bridges in the plane of the broken fibers and the work of matrix shearing / ms is given by (Cooper and Kelly, 1967 Tetelman, 1969 Cooper, 1970)... 

The failure processes in thermoplastics composites with aligned glass fibers of sub-critical transfer length have been characterized (Lauke and Schultrich, 1983, 1986a, b Lauke et al., 1985 Lauke and Pompe, 1988) in terms of matrix fracture mode which is determined mainly by the ductility of the matrix material, loading rate and temperature. The total specific work of fracture, / t, is expressed as the sum... 

Thermoplastic structural foams with bulk densities not less than 50% of the solid resin densities are considered. Cellular morphology, uniform-density cell behaviour, the I-beam concept in designing, core-density profile and the role of the skin, mechanical properties, and ductile-brittle transitions are discussed. 63 refs. 

Many engineering thermoplastics such as nylon, high-impact PS, polyesters, and toughened plastics exhibit responses similar to those shown in the next two curves in Figure 3.3, designated ductile. Here the stress achieves a maximum called a yield stress at a specific strain. As strain increases beyond... 

Several flexible polymers, such as natural rubber (NR) synthetic rubber (SR) polyalkyl acrylates copolymers of acrylonitrile, butadiene, and styrene, (ABS) and polyvinyl alkyl ethers, have been used to improve the impact resistance of PS and PVC. PS and copolymers of ethylene and propylene have been used to increase the ductility of polyphenylene oxide (PPO) and nylon 66, respectively. The mechanical properties of several other engineering plastics have been improved by blending them with thermoplastics. 

Thermosets are generally used in advanced composites due to their excellent thermal and dimensional stability, high modulus, and good mechanical properties. Because thermoset resins are inherently brittle, however, some applications require improved fracture resistance. Toughening of thermosets has been achieved through various methods, such as incorporation of reactive liquid rubber [1-9], elastomer [10], or rigid thermoplastics [11-25], and IPN formation with ductile component [26]. 

Polycarbonates are an unusual and extremely useful class of polymers. The vast majority of polycarbonates are based on bisphenol A [80-05-7] (BPA) and sold under the trade names Lexan (GE), Makrolon (Bayer), Calibre (Dow), and Panlite (Idemitsu). BPA polycarbonates [25037-45-0]> having glass-transition temperatures in the range of 145—155°C, are widely regarded for optical clarity and exceptional impact resistance and ductility at room temperature and below. Other properties, such as modulus, dielectric strength, or tensile strength are comparable to other amorphous thermoplastics at similar temperatures below their respective glass-transition temperatures, T. Whereas below their Ts most amorphous polymers are stiff and britde, polycarbonates retain their ductility. 

Mechanical Properties. The room temperature modulus and tensile strength are similar to those of other amorphous thermoplastics, but the impact strength and ductility are unusually high. Whereas most amorphous polymers arc glass-like and brittle below their glass-transition temperatures, polycarbonate remains ductile to about — 10°C. The stress-strain curve for polycarbonate typical of ductile materials, places it in an ideal position for use as a metal replacement. Weight savings as a metal replacement are substantial, because polycarbonate is only 44% as dense as aluminum and one-sixth as dense as steel. 

STYRENE-MALEIC ANHYDRIDE. A thermoplastic copolymer made by the copolymerization of styrene and maleic anhydride. Two types of polymers are available—impact-modified SMA terpolymer alloys (Cadon ) and SMA copolymers, with and without rubber impact modifiers (Dylark ). These products are distinguished by higher heat resistance than the parent styrenic and ABS families. The MA functionality also provides improved adhesion to glass fiber reinforcement systems. Recent developments include lerpolymer alloy systems with high-speed impact performance and low-temperature ductile fail characteristics required by automotive instrument panel usage. 

Thus, the understanding of thermosets fracture needs the complete description of the yielding and the influence of both experimental variables, (T, e), on the one hand, and the relationship with structural parameters, on the other hand. Unfortunately, few results are available in the literature dealing with the ductile-brittle transition of thermosets. Very often it is stated that thermosets are more brittle than thermoplastics but this depends only on the location of the test temperature compared with the ductile-brittle transition temperature. 

In the case of thermosets toughened with thermoplastics particles (Sec. 13.4), this mechanism may be of a considerable importance because of the intrinsic toughness and/or ductility of these particles. 

In most thermoplastics, transitions from ductile to brittle behaviour may be induced by increasing the test speed. For the reasons already invoked in the introduction, this is of particular concern in iPP, whose impact proper-... 

Brittleness is found with semi-crystalline polymers below their glass-rubber transition Tg. An example is PP, which becomes brittle at about T -10 °C. PE retains its ductile nature down to very low temperatures. Other polymers have a Tg of some tens of °C above room temperature, such as polyamides and thermoplastic polyesters. Various mechanisms are responsible for a reasonable impact strength at room temperature for polyamides this is, for instance, the absorption of water also secondary transitions in the glassy region may play a role. 

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