Textile fibers rayon

Robert Boyer and H.R. Drackett with soya bean protein fibre tow. From Anon. 1944. Drackett Co. produces new soy bean textile fiber. Rayon Textile Monthly, 85 (37). 

Williams, S. and Tonn, W.H. (1941), Qualitative methods of identifying soybean fibers in mixtures of casein fiber, wool, or other textile fiber , Rayon Textile Monthly, XXII, 11, 63-64. 

Well, we can burn it to provide heat. A wood fire is mostly burning cellulose. And we can wear it. Textiles made from linen, cotton and other plant fibers are just cellulose, and another textile fiber, rayon, is made from processed cellulose. And we can write on it - cellulose is the main component of paper, and of cardboard... 

Originally, the word rayon was appHed to any ceUulose-based man-made fiber, and therefore included the cellulose acetate fibers. However, the definition of rayon was clarified in 1951 and includes textiles fibers and filaments composed of regenerated cellulose and excludes acetate. In Europe the fibers are now generally known as viscose the term viscose rayon is used whenever confusion between the fiber and the cellulose xanthate solution (also called viscose) is possible. 

Asahi Chemical Industries (ACl, Japan) are now the leading producers of cuprammonium rayon. In 1990 they made 28,000 t/yr of filament and spunbond nonwoven from cotton ceUulose (65). Their continuing success with a process which has suffered intense competition from the cheaper viscose and synthetic fibers owes much to their developments of high speed spinning technology and of efficient copper recovery systems. Bemberg SpA in Italy, the only other producer of cuprammonium textile fibers, was making about 2000 t of filament yam in 1990. 

A rather impressive Hst of materials and products are made from renewable resources. For example, per capita consumption of wood is twice that of all metals combined. The ceUulosic fibers, rayon and cellulose acetate, are among the oldest and stiU relatively popular textile fibers and plastics. Soy and other oilseeds, including the cereals, are refined into important commodities such as starch, protein, oil, and their derivatives. The naval stores, turpentine, pine oil, and resin, are stiU important although their sources are changing from the traditional gum and pine stumps to tall oil recovered from pulping. 

Textile fibers are made from chemurgic materials such as cotton, rayon, linen, and wool (qv). 

Uses/Sources. Wood contains 50-70% cellulose cotton and other textile fibers of plant origin contain 65-95% rayon is prepared by dissolving natural cellulose and then precipitating it from solution, with some loss of crystallinity. Cellulose is made into cellophane film and is used to form fibers, resins, coatings and gums. 

Rayon is defined by the Textile Fiber Products Identification Act as a manufactured fiber composed of regenerated cellulose, as well as manufactured... 

Although fibers can be classified in numerous ways, in terms of present-day technology, they are fundamentally classified as(l) natural libers, and (2) synthetic libers. The principal natural fibers are cotton, wool. and. to a much lesser extent, silk. liax. and mohair. Synthetic tihers have made inroads into the use of all natural fibers, bul the greatest impact has occurred in connection with the latter three libers. Cotton continues to be a major textile fiber, measured in terms of billions of pounds used per year. Colton is one of the most versalile of all libers and blends well with synthetics. This is also true of wool, bul lo a somewhat lesser extent. Synthetic Fibers. Introduced in 1910 as a substitute for silk, rayon was the first artificial or synthetic fiber. Rayon, of course, differs completely in chemical constitution from silk. Rayon typifies most reconstituted or synthetic fibers, which perform almost as well and. in a number of respects, far better than their natural counterparts Some of the more recently developed synthetic libers have lilile if any resemblance to naturally available fibers and thus enlirely new types of end-producls with previously unobtainable end-qualities are available,... 

Keywords Coupling agents textile fibers bigeneric fibers rayon nylon. 

A defect of regular rayon fabric in the absence of a cross-linking finish is its solubility in alkali with consequent loss of strength and dimensional stability. These defects have been largely overcome in the high performance rayons. Mitchell and Daul (43) reported that regular textile grade rayon staple fiber accounts for 70-80% of the output of the rayon industry. 

Azoic dyes. Azo dyes contain at least one azo group (—N=N—) attached to one or often two aromatic rings. They are produced in textile fibers (usually cotton, rayon, and polyester), by diazotization of a primary aromatic amine followed by coupling of the resulting diazonium salt with an electron-rich nucleophile (azo coupling). A variety of hues can be obtained... 

The world textile industry is one of the largest consumers of dyestuffs. An understanding of the chemistry of textile fibers is necessary to select an appropriate dye from each of the several dye classes so that the textile product requirements for proper shade, fastness, and economics are achieved. The properties of some of the more commercially important natural and synthetic fibers are briefly discussed in this section. The natural fibers may be from plant sources (such as cotton and flax), animal sources (such as wool and silk), or chemically modified natural materials (such as rayon and acetate fibers). The synthetic fibers include nylon, polyester, acrylics, polyolefins, and spindex. The various types of fiber along with the type of dye needed are summarized in Table 8.2. 

For the purpose of conversion to textile fibers, dispersions or solutions of cellulose or its derivatives are achieved by various means, in order to make possible the extrusion of the fiber-forming material through the small orifices of the spinning jets. Wood pulps prepared for these and similar uses (such as the manufacture of cellophane) are known as dissolving pulps. The manufacture of dissolving pulps is a highly developed art, with processes protected by patents or, more effectively, within company files. The purification of sulfite pulps to a degree suitable for manufacture of textile rayon (90 to 94% alpha-cellulose), tire cord (94 to 9.5% alpha-cellulose), and cellulose acetate (9.5 to 90% alpha-cellulose) requires some kind of... 

TextUe filaments of cellulose acetate are classified as rayon, that term having been adopted for all manufactured textile fiber or yarn produced... 

Textile Organon, Textile Economics Bureau, 10 East 40th St., New York, monthly with annual review issue, 1930-. Production, consumption, foreign trade, and prices of natural and synthetic fibers and textiles. Formerly Rayon Organon (1930-1951). 

The viscose process is used for the production of textile fibers, known as viscose rayon, and transparent packaging film, known as cellophane (the name is coined from ceZZulose and diaphane, which is French for transparent). 

Cellulose, which is found in plant walls, is the most abundant raw material on Earth. Millions of pounds of this biorenewable polymer are produced every year. The total worldwide consumption of cellulosic fibers in 1998 was 4817 million pounds [1]. Cellulose is plentiful, inexpensive, and biodegradable. It is capable of producing a number of fibrous products with excellent properties whose utility extends into numerous end uses and industries. Cellulose is an excellent source of textile fibers, for both the commodity and the high-end, fashion-oriented markets. A common example is rayon. In addition, cellulose provides fibers for industrial end uses requiring strong, tough fibers. A common example is fibers used in tire cord. 

The name rayon was officially adopted in 1924 by the National Retail Dry Goods Association. Prior to this, the fiber was called artificial silk, wood-silk, or viscose silk. On October 26, 1937, the Federal Trade Commission (FTC) officially defined rayon as a textile fiber or yarn produced chemically from cellulose or with a cellulose base. This definition covered cuprammonium and viscose rayon as well as acetate fiber. To avoid confusion in the trade, FTC rules were adopted on December 11, 1951, which defined rayon as man-made textile fibers and filaments composed of regenerated cellulose. A separate definition was adopted for acetate, man-made textile fibers and filaments composed of cellulose acetate. ... 

Camille and Henry Dreyfus developed the first commercial process to manufacture cellulose acetate in 1905 and commercialized the spinning of cellulose acetate fibers in 1924 in the United States. At that time, the only other human-made fiber was viscose rayon, which was still in its early stages of commercialization. The main textile fibers were natural fibers cotton, wool, silk, and flax. Cellulose triacetate textile fiber was commercialized later in the 1950s. The tremendous technical effort by the Dreyfus Brothers resulted in more than 300 patents describing such significant inventions as the dry-spinning process and disperse dyeing. 

In contrast to cotton cellulose, the pulp produced still contains a small percentage of low-molar-mass foreign polyoses, mostly pentosans. Further, some carbonyl and carboxyl groups always remain. The fibers are 1-3 mm long and so usually cannot be spun to textile fibers. Thus, sheet pulp is produced by sieving on long sieve trays and fibers are then produced by the viscose or cuprosilk processes whereby rayon is obtained. 

Figure 38-14. Stress-strain curves for some textile fibers and filaments. o,p is the specific stress used in the textile industry. C = cotton, R = rayon, W = wool.

Textile fibers (cotton, silk, wool, hair, rayon, nylon, polyester, aramid, etc.) Structural materials (lumber, composites, poly(oxymethylene), PVC, nylon, etc.) Rastios (polyethylene, polypropylene, polytetrafluoroethylene, polyoxide, etc.) Adhesives (glues, epoxies, polyvinyl alcohol, synthetic rubber, segmented polyurethanes, etc.) Biological materials (the basic molecules, carbohydrates, proteins, and DNA)... 

In 1924, the name rayon was adopted but, it did include other cellulosic products such as cuprammonium and acetate fibers and the definition was subsequently amended in 1951 to man-made textile fibers and filaments composed of regenerated cellulose. 

The natural polymers mentioned above are synthesized and grown into fibers by nature. Cotton, wool and silk are some examples. Wood is produced similarly, but not being in a form suitable for use as a textile fiber, it must be chemically modified to produce an appropriate solution, which can then be extruded into a fiber. Rayon and cellulose acetate are examples of this pro-cess.1 Synthetic materials, on the other hand, must be first polymerized into chains, by finking small molecules together end to end, and then extruded into fibers. Chains are built by either a condensation or an addition process. Nylon and polyester are examples of polymers synthesized by condensation, whereas polyethylene, polypropylene, acrylic and polytetrafluoroethylene (Teflon ) are some examples of polymers prepared by the addition process. 

Both rayon and acetate rayon are made from chemically modified cellulose and were the first commercially important synthetic textile fibers. In the production of rayon, cellulose fibers are treated with carbon disulfide, CSg, in aqueous sodium hydroxide. In this reaction, some of the —OH groups on a ceUulose fiber are converted to the sodium... 

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