Cellulose acetate fiber

Dyes for dyeing and printing polyester and cellulose acetate fibers fast blue and red shades... 

Dyes for polyesters or cellulose acetate fiber-, deep blue to greenish blue shades... 

Most of the acetic acid is produced in the United States, Germany, Great Britain, Japan, France, Canada, and Mexico. Total annual production in these countries is close to four million tons. Uses include the manufacture of vinyl acetate [108-05-4] and acetic anhydride [108-24-7]. Vinyl acetate is used to make latex emulsion resins for paints, adhesives, paper coatings, and textile finishing agents. Acetic anhydride is used in making cellulose acetate fibers, cigarette filter tow, and ceUulosic plastics. 

Eastman Goal Chemicals. In 1983 Eastman Chemical Co. became the first chemical producer in the United States to return to coal as a raw material for large-scale manufacture of industrial chemicals (35). In that year, Eastman started manufacturing acetic anhydride from coal. Acetic anhydride is a key intermediate for production of coatings, ceUulosic plastics, and cellulose acetate fibers. Acetic anhydride from other sources also is used in the manufacture of pharmaceuticals, starches and sweeteners, and flavors and fragrances. 

Fig. 13. Cross sections of cellulose acetate fiber from (a) circular and (b) triangular spinneret holes.

Originally, the word rayon was appHed to any ceUulose-based man-made fiber, and therefore included the cellulose acetate fibers. However, the definition of rayon was clarified in 1951 and includes textiles fibers and filaments composed of regenerated cellulose and excludes acetate. In Europe the fibers are now generally known as viscose the term viscose rayon is used whenever confusion between the fiber and the cellulose xanthate solution (also called viscose) is possible. 

Phenylenediamines are used in a variety of other appHcations, such as corrosion inhibitors, cross-linking agents for epoxy resins, toners for electrostatic image development (35), and to improve wrinkle resistance of cellulose acetate fibers (36). 

Oxidation has also been cited as occurring in the cure of polymethyUiydrosiloxane [9004-73-3] (PMHS) on cellulose acetate fibers. Investigation of the cured, cross-linked siUcone shows no evidence of the Si—H bond. The same compound under an atmosphere of nitrogen does not cure and retains the Si—H bonds (99). 

The appearance of synthetic fibers in the 1920s accelerated the further development of anthraquinone dyes. Soon after British Celanese succeeded in commerciali2ing cellulose acetate fiber in 1921, anthraquinone disperse dyes for this fiber were invented by Stepherdson (British Dyestuffs Corp.) and Celatenes (Scottish Dyes) independendy. Anthraquinone disperse dyes for polyester fiber were developed after the introduction of this fiber by ICI and Du Pont in 1952. These dyes were improved products of the disperse dyes that had been developed for cellulose acetate fiber 30 years before. 

In 1923, the first disperse dye was developed for dyeing cellulose acetate fibers. However, in recent years the most important appHcation of disperse dyes has been to dye polyester fibers. Accompanied by the rapid growth of polyester fibers after World War II, disperse dyes have currendy achieved the largest production among all dye classes in terms of quantity (106). 

A process for the production of cellulose acetate fiber produces a waste stream containing mainly air but with a small quantity of acetone vapor. The flowrate of air is 300 kmol h-1 and that of acetone is 4.5 kmolh-1. It is proposed to recover the acetone from the air by absorption into water followed by distillation of the acetone-water mixture. The absorber requires a flow of water 2.8 times that of the air. 

The process flowsheet for a cellulose acetate fibers process is shown in Figure 19.12. Solvent is removed from the fibers in a dryer by recirculating air. The air is cooled before it enters an absorber where the solvent is absorbed in water. The solvent-water mixture is separated in a distillation column and... 

Figure 19.12 Flowsheet of a process for the manufacture of cellulose acetate fiber.

Acetate A general name for processes for making cellulose acetate fibers. Cellulose is acetylated, dissolved in acetone, and spun into fibers by injecting through orifices into heated chambers. Cellulose mono-acetate is made by acetylating with a mixture of acetic acid, acetic anhydride, and sulfuric acid as the catalyst. Cellulose tri-acetate is made in a similar fashion, but using perchloric acid as the catalyst, and dry-spinning from a solution in ethanol/ methylene chloride. Cellulose tri-acetate fibers were first made commercially by Courtaulds in London in 1950. 

Drying equipment, 10 154 Drying gases, commercial gas absorption process for cellulose acetate fiber production, l 26t Drying index, 9 144 Drying mechanisms, 9 102-116. 

The textiles printing industry has an appreciable interest in P.Y.17 and applies it in the form of pigment preparations. Where its fastness properties satisfy the specifications and where the use requirements are not too demanding, the pigment is also utilized for spin dyeing purposes. Manufacturer recommendations include media such as polyacrylonitrile and cellulose acetate fibers, on which 1/3 SD pigment prints exhibit a lightfastness which is equal to step 5 on the Blue Scale. 

Mark s inclination based on his research at the Fiber Research Institute was that "colloidal" substances such as cellulose and rubber were of high molecular weight. Work began with this cornerstone concept. In the beginning research was mostly concerned with testing viscose and cellulose acetate fibers. Before long a great deal of research was conducted on materials subsequently called addition polymers. 

As a solvent, acetone is used in varnishes, lacquer, cellulose acetate fiber, cellulose nitrate (an explosive), and as a carrier solvent for acetylene in cylinders. Acetylene is stored at about 225 psi but is so explosively reactive that as an extra precaution the cylinder is filled with asbestos wool soaked in acetone. Acetylene is extremely soluble in acetone, and the asbestos keeps it from sloshing around when the cylinder is half empty. Acetone also is used in smaller volumes for the manufacture of pharmaceuticals and chloroform (the anesthetic). 

Urea-formaldehyde resins Cellulose nitrate automobile lacquers Cellulose acetate fibers Alkyd polyester (Kienle)... 

Cellulose acetate fibers are defined by the Textile Fiber Products Identification Act as manufactured fibers in which the fiber-forming substance is cellulose acetate in which not less than 92% of the hydroxyl groups are acetylated. Cellulose triacetate is employed to make many tricot fabrics and sportswear. Cellulose triacetate textile is shrink- and wrinkle-resistant and easily washed. 

Armstrong, and Rutherford have reported extensive studies on the vapor phase grafting of vinyl monomers to cellulosic fibers both mutual and pre-irradiation methods have been used (97, 120). Again, water or another swelling agent was found to be necessary for effective grafting to rayon and cotton for all the monomers studied. In the case of cellulose acetate water was helpful but not necessary except for styrene. Acetic acid and methanol vapors were also found to be effective promotors of vapor phase grafting to cotton and cellulose acetate fibers. 

FIBERS ACETATE. Cellulose acetate fiber, or acetate. is a chemical derivative of the naturally occurring polymer cellulose. Two types of acetate fibers are produced ... 

One of the first cases of the application of membrane bioreactors in food processes was the production of milk with low lactose content. (3-galactosidase was entrapped into cellulose acetate fibers to carry out the hydrolysis of milk and whey lactose [2] recently the system was improved by the use of microfiltration and by UV irradiation of the enzyme solution to avoid growth of micro-organisms [45]. 

M. Raheel, History of cellulose acetate fibers , pp. 142-168, in Manmade Fibers Their Origin and Development. Proceedings of an international symposium, ed. R. B. Seymour and R. S. Porter, Elsevier, London, 1993. 

Cellulose acetate forms strong, transparent films and has enjoyed many applications such as photographic film, transparent tape, and blister packaging. It can also be spun into satin fibers. Satin not only means a somewhat shiny fabric woven from cellulose acetate fiber, but also refers to something with a soft texture, which the acetate fiber has. 

Modification of cotton textiles by chemical plating of their surfaces with cobalt (II) or nickel (II) salts produced metallized fibers and fabrics with high electrical conductivity and the capability to transport and dissipate thermal energy (109). The heat capacity of cellulose acetate fibers was increased by treatment with epoxy compounds (110). 

Rogovin, Z. A., Kostrov, Yu. A., Cellulose Acetate Fibers, Man-Made... 

Fig. 13.97. Disazo disperse black dye synthesis conducted inside cellulose acetate fibers.

S g CD SNAM Progetti Streptomyces Sp. Cells are entrapped in cellulose acetate fibers 32... 

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