System kerosene

Burns and Ramshaw [35] Glass chip reactor Reacting system Kerosene/acetic acid/water + NaOH... 

Teflon Y-junction and capillary tubing Nonreacting system Kerosene/acetic acid/water... 

Liquid-liquid system in microreactors Burns and Ramshaw (2001) Slug flow Reacting system Kerosene-acetic acid-water + NaOH dn — 380 pm acetic acid, org — 0.65 M CNaOH,aq 0.1-0.4 M u = 0-35mms Order of magnitude of 0.5 s ... 

Impinging streams Non-reacting system Kerosene-acetic acid-water 0.05-0.3... 

FIGURE 15.24 Effect of seawater content in microemulsion formation (WIV) for the system kerosene + aqueous phase + surfactant + butan-l-ol. CIS ratio = 2 all diagrams show a WrV region, a biphasic region and a region containing excess solid surfactant (S) with microemulsion. 

Whenever unvented combustion occurs iadoors or when venting systems attached to combustion units malfunction, a variety of combustion products win be released to the iadoor environment. Iadoor combustioa units include nonelectric stoves and ovens, furnaces, hot water heaters, space heaters, and wood-burning fireplaces or stoves. Products of combustion include CO, NO, NO2, fine particles, aldehydes, polynuclear aromatics, and other organic compounds. Especially dangerous sources are unvented gas and kerosene [8008-20-6] space heaters which discharge pollutants directly into the living space. The best way to prevent the accumulation of combustion products indoors is to make sure all units are properly vented and properly maintained. 

Chemistry. Chemical separation is achieved by countercurrent Hquid— Hquid extraction and involves the mass transfer of solutes between an aqueous phase and an immiscible organic phase. In the PUREX process, the organic phase is typically a mixture of 30% by volume tri- -butyl phosphate (solvent) and a normal paraffin hydrocarbon (diluent). The latter is typically dodecane or a high grade kerosene (20). A number of other solvent or diluent systems have been investigated, but none has proved to be a substantial improvement (21). 

High molecular weight primary, secondary, and tertiary amines can be employed as extractants for zirconium and hafnium in hydrochloric acid (49—51). With similar aqueous-phase conditions, the selectivity is in the order tertiary > secondary > primary amines. The addition of small amounts of nitric acid increases the separation of zirconium and hafnium but decreases the zirconium yield. Good extraction of zirconium and hafnium from ca 1 Af sulfuric acid has been effected with tertiary amines (52—54), with separation factors of 10 or more. A system of this type, using trioctylarnine in kerosene as the organic solvent, is used by Nippon Mining of Japan in the production of zirconium (55). 

Combustion. The primary reaction carried out in the gas turbine combustion chamber is oxidation of a fuel to release its heat content at constant pressure. Atomized fuel mixed with enough air to form a close-to-stoichiometric mixture is continuously fed into a primary zone. There its heat of formation is released at flame temperatures deterruined by the pressure. The heat content of the fuel is therefore a primary measure of the attainable efficiency of the overall system in terms of fuel consumed per unit of work output. Table 6 fists the net heat content of a number of typical gas turbine fuels. Net rather than gross heat content is a more significant measure because heat of vaporization of the water formed in combustion cannot be recovered in aircraft exhaust. The most desirable gas turbine fuels for use in aircraft, after hydrogen, are hydrocarbons. Fuels that are liquid at normal atmospheric pressure and temperature are the most practical and widely used aircraft fuels kerosene, with a distillation range from 150 to 300 °C, is the best compromise to combine maximum mass —heat content with other desirable properties. For ground turbines, a wide variety of gaseous and heavy fuels are acceptable. 

NASA is also considering a more advanced aircraft such as Mach 5 to cut Pacific travel time to about three hours, but in this case kerosene fuel is no longer acceptable, and Hquefted natural gas or Hquefted hydrogen would be needed to provide the necessary cooling and stabiUty. However, a completely new fueling system would be required at every international airport to handle these cryogenic fluids. 

Ce(IV) extracts more readily iato organic solvents than do the trivalent Ln(III) ions providing a route to 99% and higher purity cerium compounds. Any Ce(III) content of mixed lanthanide aqueous systems can be oxidi2ed to Ce(IV) and the resultiag solutioa, eg, of nitrates, contacted with an organic extractant such as tributyl phosphate dissolved in kerosene. The Ce(IV) preferentially transfers into the organic phase. In a separate step the cerium can be recovered by reduction to Ce(III) followed by extraction back into the aqueous phase. Cerium is then precipitated and calcined to produce the oxide. 

A modem petroleum refinery is a complex system of chemical and physical operations. The cmde oil is first separated by distillahon into fractions such as gasoline, kerosene, and fuel oil. Some of the distillate fractions are converted to more valuable products by cracking, polymerization, or reforming. The products are treated to remove undesirable components, such as sulfur, and then blended to meet the final product specifications. A detailed analysis of the entire petroleum production process, including emissions and controls, is obviously well beyond the scope of this text. 

From a practical standpoint, coal, because of its abundance, has received the most attention as a source for synthetic fuels. As early as 1807, a coal-gas system was used to light the streets of London, and until the 1930s, when less expensive and safer natural gas started to flow through newly constructed pipelines, gas piped to homes in the Eastern United States was derived from coal. Kerosene, originally a byproduct from the coking of coal tor metallurgical applications, can be considered the first synthetic lic -uid fuel made in quantity. But once crude oil became cheap and abundant, there was little serious research on synthetic liquid fuels in the industrial world until the Energy Crisis of 1973. The main exceptions to... 

Decreases with increasing wettability of liquid on plate surface. Kerosene, hexane, carbon tetrachloride, butyl alcohol, glycerine-water mixtures all wet the test plates better than pure water. The critical tray stability data of Hunt et al., [33] is given in Table 8-21 for air-water, and hence the velocities for other systems that wet the tray better than water should be somewhat lower than those tabulated. The data of Zenz [78] are somewhat higher than these tabulated values by 10-60%. 

With the oil/water/surfactant droplet system which was used, no investigations could be performed because of strong foaming. However, studies with water/kerosene emulsions are known from the literature. The results of Yoshida... 

Much higher shear forces than in stirred vessels can arise if the particles move into the gas-liquid boundary layer. For the roughly estimation of stress in bubble columns the Eq. (29) with the compression power, Eq. (10), can be used. The constant G is dependent on the particle system. The comparison of results of bubble columns with those from stirred vessel leads to G = > 1.35 for the floccular particle systems (see Sect. 6.3.6, Fig. 17) and for a water/kerosene emulsion (see Yoshida and Yamada [73]) to G =2.3. The value for the floe system was found mainly for hole gas distributors with hole diameters of dL = 0.2-2 mm, opening area AJA = dJ DY = (0.9... 80) 10 and filled heights of H = 0.4-2.1 m (see Fig. 15). 

The hydrodynamics of the moving drop are difficult to calculate, particularly the flow characteristics within the droplet itself. However, this technique is still used widely, because it is a simple and straightforward method. It was recently applied to study the stripping-extraction kinetics of Mn(II) in an aqueous-kerosene system [50,51]. The effect of anionic surfactants on the kinetics of extraction of lactic acid from an aqueous phase by Alamine 336 in a toluene phase was also studied by this technique [52]. 

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