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Sufficient

The detailed techniques presented here are based on particular models for the vapor phase (Hayden-O Connell) and for the liquid phase (UNIQUAC). However, our discussion of these techniques is sufficiently general to allow the use of other models, whenever the user prefers to do so. [Pg.2]

Since the accuracy of experimental data is frequently not high, and since experimental data are hardly ever plentiful, it is important to reduce the available data with care using a suitable statistical method and using a model for the excess Gibbs energy which contains only a minimum of binary parameters. Rarely are experimental data of sufficient quality and quantity to justify more than three binary parameters and, all too often, the data justify no more than two such parameters. When data sources (5) or (6) or (7) are used alone, it is not possible to use a three- (or more)-parameter model without making additional arbitrary assumptions. For typical engineering calculations, therefore, it is desirable to use a two-parameter model such as UNIQUAC. [Pg.43]

When there are sufficient data at different temperatures, the temperature dependence of the parameters is reflected in the confidence ellipses (Bryson and Ho, 1969 Draper and Smith,... [Pg.44]

If there is sufficient flexibility in the choice of model and if the number of parameters is large, it is possible to fit data to within the experimental uncertainties of the measurements. If such a fit is not obtained, there is either a shortcoming of the model, greater random measurement errors than expected, or some systematic error in the measurements. [Pg.106]

C. These values are sufficiently accurate for present purposes... [Pg.139]

FORMAT (68H0L INEAR IZED FUNCTION DOES NOT SUFFICIENTLY APPROXIMATE ITRUE UNCTION,5X,3HIT =, 12,5X, 3HAL=, G15.5)... [Pg.247]

These rules are both necessary and sufficient to ensure that the target is achieved, providing the initialization rule is adhered to that no individual heat exchanger should have a temperature difference smaller than... [Pg.169]

Short-term exposure. This is the maximum concentration to which workers can be exposed for a period of up to 15 minutes continuously without suffering from (a) intolerable irritation, (b) chronic or irreversible tissue change, or (c) narcosis of sufficient degree to increase accident proneness, impair self-rescue, or materially reduce efficiency, provided that no more than four excursions per day are permitted, with at least 60 minutes between exposure periods, and provided the daily time-weighted value is not exceeded. [Pg.260]

This problem is solved in the reactor shown in Fig. 10.6. Ethylene and chlorine are introduced into circulating liquid dichloroethane. They dissolve and react to form more dichloroethane. No boiling takes place in the zone where the reactants are introduced or in the zone of reaction. As shown in Fig. 10.6, the reactor has a U-leg in which dichloroethane circulates as a result of gas lift and thermosyphon effects. Ethylene and chlorine are introduced at the bottom of the up-leg, which is under sufficient hydrostatic head to prevent boiling. [Pg.286]

Inertial collectors. In inertial collectors, an object is placed in the path of the gas. An example is shown in Fig. 11.1. While the gas passes around the shutters, particles with sufficiently high inertia impinge on them and are removed from the stream. Only particles in excess of 50/um can reasonably be removed. Like gravity settlers, inertial collectors are widely used as prefilters. [Pg.302]

CifiHijClNj. White plates m.p. 125 C. Diazepam is one of several benzodiazepines which are very widely used as minor tranquillizers for allaying anxiety, as hypnotics or, in sufficiently high dosage given intravenously, as pre-anaesthetic sedatives. [Pg.132]

C2H3N. Colourless liquid with strong ammoniacal smell b.p. 56 C. Miscible with water and strongly basic. Prepared commercially from 2-aminoelhanol. Pure dry aziridine is comparatively stable but it polymerizes explosively in the presence of traces of water. Carbon dioxide is sufficiently acidic to promote polymerization. [Pg.138]

One outstanding feature of enzymes is that many of them are highly specific. Those that act on carbohydrates are particularly so, the slightest change in the stereochemical configuration of the molecule being sufficient to make a particular enzyme incompatible and unable to elTect hydrolysis. [Pg.159]

High explosives. Those explosives which normally burn without undue violence when ignited in an open space, but which can be detonated by a sufficiently large sudden mechanical or explosive shock. [Pg.171]

Uquidus curve The freezing point of a molten mixture of substances varies with the composition of the mixture. If the freezing points are plotted as a function of the composition, the line joining the points is called a liquidus curve. Such mixtures usually freeze over a range of temperature. If the temperature at which the last traces of liquid just solidify (assuming that sufficient time has been allowed for equilibrium to be established) are plotted against composition the resulting line is called a solidus curve. [Pg.241]

The variation of Bq causes all ions to pass sequentially in front of the exit slit behind which is positioned the photomultiplier detector. The pressure in the apparatus is held at 10 torr in order to achieve mean free paths of ions sufficiently high that all ions emitted from the source are collected. [Pg.48]

Nevertheless, a molecule possesses sufficient vibrations so that all its frequencies taken together can be used to characterize it. In this sense the infrared spectrum is generally considered to be a molecule s fingerprint."... [Pg.57]

Although continuous wave NMR is sufficient for naturally abundant nuclei with strong magnetic moments such as hydrogen, fluorine and phosphorous, the study of low abundance nuclei and/or weak magnetic moments such as carbon 13 or silicon 29 requires pulse NMR. [Pg.65]

This method follows the ASTM D 1159 and D 2710 procedures and the AFNOR M 07-017 standard. It exploits the capacity of the double olefinic bond to attach two bromine atoms by the addition reaction. Expressed as grams of fixed bromine per hundred grams of sample, the bromine number, BrN, enables the calculation of olefinic hydrocarbons to be made if the average molecular weight of a sufficiently narrow cut is known. [Pg.83]

The method of contributing groups does not apply with sufficient accuracy for the following calculations ... [Pg.93]

Sufficiently accurate thermodynamic models used for calculating these equilibria are not available In simulation programs. It Is generally not recommended to use the models proposed. Only a specific study based on accurate experimental results and using a model adapted to the case will succeed. [Pg.171]

Imposing a minimum density is justified by the need to obtain sufficient maximum power for the engine, by means of an injection pump whose flow is controlled by regulating the volume. [Pg.213]

As we have shown previously, obtaining both good cold operation characteristics and sufficient cetane numbers constitutes the principal objective for the refiner in the formulation of diesel fuel. To this is added the need for deep desulfurization and, perhaps in the future, limitations placed on the chemical nature of the components themselves, e.g., aromatics content. [Pg.223]

For jet fuels, the elimination of free water using filters and coalescers by purging during storage, and the limit of 5 ppm dissolved water are sufficient to avoid incidents potentially attributable to water contamination formation of micro-crystals of ice at low temperature, increased risk of corrosion, growth of micro-organisms. [Pg.250]

The implementation of very effective devices on vehicles such as catalytic converters makes extremely low exhaust emissions possible as long as the temperatures are sufficient to initiate and carry out the catalytic reactions however, there are numerous operating conditions such as cold starting and... [Pg.258]

D is basically a succession of 2D or 3D surveys repeated at intervals of time during which it is expected that some production effect has occurred, of sufficient magnitude to effect the acoustic impedance contrast seen by the propagating waves. For example, this oould be changes in the water or gas saturation, or changes in pressure. [Pg.20]


See other pages where Sufficient is mentioned: [Pg.83]    [Pg.179]    [Pg.364]    [Pg.18]    [Pg.22]    [Pg.63]    [Pg.163]    [Pg.170]    [Pg.211]    [Pg.216]    [Pg.342]    [Pg.351]    [Pg.361]    [Pg.362]    [Pg.375]    [Pg.400]    [Pg.418]    [Pg.73]    [Pg.190]    [Pg.191]    [Pg.219]    [Pg.228]    [Pg.252]    [Pg.317]   
See also in sourсe #XX -- [ Pg.45 , Pg.47 , Pg.48 , Pg.49 , Pg.50 , Pg.61 , Pg.62 , Pg.67 , Pg.69 , Pg.70 , Pg.77 , Pg.79 ]




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