Exit slit

The variation of Bq causes all ions to pass sequentially in front of the exit slit behind which is positioned the photomultiplier detector. The pressure in the apparatus is held at 10 torr in order to achieve mean free paths of ions sufficiently high that all ions emitted from the source are collected. 

The first requirement is a source of infrared radiation that emits all frequencies of the spectral range being studied. This polychromatic beam is analyzed by a monochromator, formerly a system of prisms, today diffraction gratings. The movement of the monochromator causes the spectrum from the source to scan across an exit slit onto the detector. This kind of spectrometer in which the range of wavelengths is swept as a function of time and monochromator movement is called the dispersive type. 

When dispersing elements are used, the resolution of the speetrometer is detennined by the entranee slit widtir, the exit slit width, the foeal length and the dispersing element itself Resolving power is defined as... 

There are otlier teclmiques for mass separation such as tire quadmpole mass filter and Wien filter. Anotlier mass spectrometry teclmique is based on ion chromatography, which is also capable of measuring tire shapes of clusters [30, 31]. In tills metliod, cluster ions of a given mass are injected into a drift tube witli well-defined entrance and exit slits and filled witli an inert gas. The clusters drift tlirough tills tube under a weak electric potential. Since the... 

Radiation exits the monochromator and passes to the detector. As shown in Figure 10.12, a polychromatic source of radiation at the entrance slit is converted at the exit slit to a monochromatic source of finite effective bandwidth. The choice of... 

Another approach to multielemental analysis is to use a multichannel instrument that allows for the simultaneous monitoring of many analytes. A simple design for a multichannel spectrometer consists of a standard diffraction grating and 48-60 separate exit slits and detectors positioned in a semicircular array around the diffraction grating at positions corresponding to the desired wavelengths (Figure 10.50). 

A simple spectrometer that we have used successfully is shown in Figure 2. Electrons from an electron microscope hairpin tungsten filament are focused with an Einzel lens onto the monochromator entrance slit, pass through the monochromator and exit slit, and are focused on the sample s surface by additional electrostatic... 

Figura 3 Grating spectrometers commonly used for ICP-OES (a) monochromator, in which wavelength is scanned by rotating the grating while using a singie photomultiplier tube (PMT) detector (b) polychromator, in which each photomultiplier observes emission from a different wavelength (40 or more exit slits and PMTs can be arranged along the focal plane) and (c) spectrally segmented diode-array spectrometer.

Direct-reading polychromators (Figure 3b) have a number of exit slits and photomultiplier tube detectors, which allows one to view emission from many lines simultaneously. More than 40 elements can be determined in less than one minute. The choice of emission lines in the polychromator must be made before the instrument is purchased. The polychromator can be used to monitor transient signals (if the appropriate electronics and software are available) because unlike slew-scan systems it can be set stably to the peak emission wavelength. Background emission cannot be measured simultaneously at a wavelength close to the line for each element of interest. For maximum speed and flexibility both a direct-reading polychromator and a slew-scan monochromator can be used to view emission from the plasma simultaneously. 

Fig. 4-7. Diffraction of a divergent beam from a broad sample by a large crystal. Collimation of this beam requires the Soller slit system shown. This system is equivalent to simple slits at A and B with separators provided to make certain that only parallel rays leave the exit slit.

A modern laser Raman spectrometer consists of four fundamental components a laser source, an optical system for focusing the laser beam on to the sample and for directing the Raman scattered light to the monochromator entrance slit, a double or triple monochromator to disperse the scattered light, and a photoelectric detection system to measure the intensity of the light passing through the monochromator exit slit (Fig. 7). 

A detachable monochromator (19) developed by Spex Industries, was another approach in minimizing stray light. It is a modified Czerny-Turner spectrograph which can be coupled to the exit slit of a double monochromator and function as a variable bandpass, variable frequency filter. This accessory, while providing the versatility of a triple monochromator, does not add much mechanical and optical complexity and can be removed when not wanted. 

Fig 4 is a diagram of an electron impact 1 source. The sample vapor is admitted into the ion source thru the slit in the back of the chamber and it passes thru a collimated electron beam b . On impact of electrons with the neutral molecules, positive ions (to a small extent negative ions) are produced. A small positive potential ( repeller potential ) between the back wall V of the ion source and first accelerator plate d , expels tile positive ions toward the accelerating region and at the same time attracts the negative ions which are then discharged at repeller plate c . The positive ions are accelerated by the potential difference applied to plates d and e , pass thru the exit slit T and continue toward the collector... 

To prevent withdrawal of the ions thus produced by penetration of the main accelerating field, either a small positive bias is applied to plate 6 or alternatively (31) the exit slit from the ionization chamber is covered by a transparent wire mesh. The ions are withdrawn from the ionization chamber by a voltage pulse of proper sign applied either to the repeller plate (plate 3) or to the ion withdrawal plate (plate 6). 

The cross-sections for the reactions of primary and secondary ionic species with the gas in the source chamber of the spectrometer were determined by the beam model (38). Reactions of primary ions with gas molecules as the ions move under the action of the electric field from the plane of formation toward the ion exit slit will attenuate the beam in exponential fashion, so that the intensity Ip at the exit slit will be ... 

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