Stratosphere source gases

Stratospheric source gases - A variety of gases transport chlorine into the stratosphere. These gases are emitted from natural sources and human activities. For chlorine, human activities account for most that reaches the stratosphere. The CFCs are the most abundant of the chlorine-containing gases released in human activities. Methyl chloride is the most important natural source of chlorine ... 

Locally, the stratospheric albedo modification scheme, even when conducted at remote tropical island sites or from ships, would be a messy operation. An alternative may be to release a S-containing gas at the earth s surface, or better from balloons, in the tropical stratosphere. A gas one might think of is COS, which may be the main source of the stratospheric sulfate layer during low activity volcanic periods (Crutzen 1976), although this is debated (Chin/Davis 1993). However, about 75 % of the COS emitted will be taken up by plants, with unknown long-term ecological consequences, 22 % is removed by reaction with OH, mostly in the troposphere, and only 5 % reaches the stratosphere to produce SO2 and sulfate... 

Nitrous oxide is important not only as a greenhouse gas but, as discussed in Chapter 12, as the major natural source of NC/ in the stratosphere, where it is transported due to its long tropospheric lifetime (Crutzen, 1970). The major sources of N20 are nitrification and denitrification in soils and aquatic systems, with smaller amounts directly from anthropogenic processes such as sewage treatment and fossil fuel combustion (e.g., see Delwiche, 1981 Khalil and Rasmussen, 1992 Williams et al., 1992 Nevison et al., 1995, 1996 Prasad, 1994, 1997 Bouwman and Taylor, 1996 and Prasad et al., 1997). The use of fertilizers increases N20 emissions. For pastures at least, soil water content at the time of fertilization appears to be an important factor in determining emissions of N20 (and NO) (Veldkamp et al., 1998). 

A few comments on nitrous oxide Nitrous oxide (NzO) is a gas produced mainly through natural sources. However, generally, motor vehicles and combustion processes contribute to its formation in urban areas. Unfortunately, it is involved adversely in the two global environmental problems it contributes to the greenhouse effect and penetrates into the stratosphere, destroying the ozone layer. 

The concentration of nitrous oxide (N2O) in the atmosphere is increasing. This is a concern, since N2O has been identified as a greenhouse gas and as a source of ozoneconsuming NO in the stratosphere. A significant source of N2O to the atmosphere is production of adipic acid (AA), which is used in the production of nylon. Adipic acid is formed from reaction of cyclohexanol with nitric acid (HNO3) according to the scheme in Fig. 13.13. 

Globally, the oxides of nitrogen, NO (nitric oxide), NO2 (nitrogen oxide), and N2O (nitrous oxide), are key species involved in the chemistry of the troposphere and stratosphere. NO and N2O are produced mostly by microbial soil activity, whereas biomass burning is also an important source of NO. Nitric oxide is a species involved in the photochemical production of ozone in the troposphere, is involved in the chemical produaion of nitric acid, and is an important component of acid precipitation. Nitrous oxide plays a key role in stratospheric ozone depletion and is an important greenhouse gas, with a global warming potential more than 200 times that of CO2. 

Nitrous oxide (N2O) is a potent greenhouse gas (approximately 200 times more effective than CO2 on a molar basis) that has also been implicated in stratospheric ozone depletion (Kim and Craig, 1990 Yoshida et al., 1989) (see Bange, Chapter 2, this volume). Currendy, N2O accounts for about 5.5% of the enhanced radiative forcing attributed to all gases in the atmosphere (IPCC, 2007). Furthermore, while the atmospheric inventory of N2O is increasing, its sources are not well understood causing a renewed interest in the role of marine ecosystems as a potential source for N2O. 

Carbonyl sulfide is also the most abundant reduced sulfur gas in Earth s troposphere, but for completely different reasons. Volcanic sources of OCS are negligible by comparison with biogenic emissions, which are important sources of several reduced sulfur gases (e.g., OCS, H2S, (CH3)2S, (CH3)2S2, and CH3SH) in the terrestrial troposphere. Many of these gases are ultimately converted into sulfate aerosols in the troposphere, but OCS is mainly lost by transport into the stratosphere, where it is photochemically oxidized to SO2 and then to sulfuric acid aerosols, which form the Junge layer at —20 km in Earth s stratosphere. 

Westrich H. R. and Gerlach T. M. (1992) Magmatic gas source for the stratospheric SO2 cloud from the June 15, 1991 emption of Mount Pinatubo. Geology 20, 867-870. Williams S. N. (1983) PUnian airfall deposits of basaltic... 

The first global CH4 budgets were compiled by Ehhalt (1974) and Ehhalt and Schmidt (1978), who used available published information to estimate emissions of CH4 to the atmosphere. They considered paddy fields, freshwater sources (lakes, swamps, and marshes), upland fields and forests, tundra, the ocean, and enteric fermentation by animals as biogenic sources. Anthropogenic sources included industrial natural gas losses and emission from coal mining, and were considered to be free. Observations of CH4 placed an upper limit on anthropogenic sources. Oxidation by the OH radical, as well as loss to the stratosphere by eddy diffusion and Hadley circulation, were presumed to be methane sinks. In spite of lack of data, this work correctly identified the major atmospheric sources and did... 

Nitrous oxide (N2O) is a long-lived (120 yr) trace component of the atmosphere (Prinn et al., 1990). It is a climate-active gas as it has a radiative forcing 300 times that of CO2, although N2O presently contributes only 5% to the total greenhouse effect (Schimel, 1996). N2O also acts as a source of nitric oxide in the stratosphere and therefore participates in the catalytic removal of ozone (Crutzen, 1970). It is produced as a reaction intermediate in both microbial denitrification and nitrification processes and at greater rates under conditions of low O2 (Law and Owens, 1990) (see Chapter 6.11 by Emerson and Hedges for more details). 

Methane is highly flammable and is therefore an explosion and fire hazard the lower explosive limit is 5-15% by volume. Extreme care must be taken to keep areas of high concentration free from ignition sources, such as sparks from static electricity. Explosion-proof equipment should be used in these areas. Many people believe that methane is an important greenhouse gas, and that the apparent threefold increase in atmospheric concentrations over the last 200 years affects the stratospheric ozone layer and the oxidizing capacity of the atmosphere. 

The most abundant carbon-containing compound in the stratosphere and mesosphere is carbon dioxide (CO2). By interacting with infrared radiation, this gas plays an important role in the thermal budget of the atmosphere, and the 30% increase in its concentration resulting mainly from fossil fuel burning has provided a significant forcing to the climate system of about 1.5 Wm 2 (IPCC, 2001). Carbon dioxide does not play any substantial role in the chemistry of the atmosphere except in the lower thermosphere, where its photolysis is an important source of carbon monoxide (CO). This latter gas, which is also released at the Earth s surface by incomplete combustion (pollution) and is partially transported to the stratosphere, is converted to CO2 by reaction with the hydroxyl radical (OH). 

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