SRMs

Analysis sheet for Simulated Rainwater (SRM 2694a). Adapted from NIST Special Publication 250 Standard Reference Materials Catalog 1995-96, p. 54 U.S. Department of Commerce, Technology Administration, National Institute of Standards and Technology. 

This SRM was developed to aid in the analysis of acidic rainwater by providing a stable, homogeneous material at two levels of acidity. 

Analysis of Standards The analysis of a standard containing a known concentration of analyte also can be used to monitor a system s state of statistical control. Ideally, a standard reference material (SRM) should be used, provided that the matrix of the SRM is similar to that of the samples being analyzed. A variety of appropriate SRMs are available from the National Institute of Standards and Technology (NIST). If a suitable SRM is not available, then an independently prepared synthetic sample can be used if it is prepared from reagents of known purity. At a minimum, a standardization of the method is verified by periodically analyzing one of the calibration standards. In all cases, the analyte s experimentally determined concentration in the standard must fall within predetermined limits if the system is to be considered under statistical control. 

SRM. selected reaction monitoring SSMS. spark source mass spectrometry... 

The exchange energy coefficient M characterizes the energy associated with the (anti)paraHel coupling of the ionic moments. It is direcdy proportional to the Curie temperature T (70). Experimental values have been derived from domain-width observations (69). Also the temperature dependence has been determined. It appears thatM is rather stable up to about 300°C. Because the Curie temperatures and the unit cell dimensions are rather similar, about the same values forM may be expected for BaM and SrM. 

The intrinsic properties may be modified by substitution (31). Ba can be fuUy replaced by Sr or Pb and partly by Ca (<40 mol %). CaM, stabilized with 0.03 mol % La202, is also possible. The intrinsic properties of these M-ferrites vary somewhat and other factors such as sintering behavior and price of raw materials often dictate the commercial viabiUty. Large-scale production is concentrated on BaM and SrM. High quaUty magnets are generally based on SrM, and somewhat lower priced magnets are based on BaM. 

National Institute of Standards and Technology (NIST). The NIST is the source of many of the standards used in chemical and physical analyses in the United States and throughout the world. The standards prepared and distributed by the NIST are used to caUbrate measurement systems and to provide a central basis for uniformity and accuracy of measurement. At present, over 1200 Standard Reference Materials (SRMs) are available and are described by the NIST (15). Included are many steels, nonferrous alloys, high purity metals, primary standards for use in volumetric analysis, microchemical standards, clinical laboratory standards, biological material certified for trace elements, environmental standards, trace element standards, ion-activity standards (for pH and ion-selective electrodes), freezing and melting point standards, colorimetry standards, optical standards, radioactivity standards, particle-size standards, and density standards. Certificates are issued with the standard reference materials showing values for the parameters that have been determined. 

Physical or artifactual standards are used for comparison, caUbration, etc, eg, the national standards of mass, length, and time maintained by the National Institute of Standards and Technology (NIST) or the standard reference materials (SRMs) collected and distributed by NIST. Choice of the standard is determined by the property it is supposed to define, its ease of measurement, its stabiUty with time, and other factors (see Fine chemicals). 

Analytical standards imply the existence of a reference material and a recommended test method. Analytical standards other than for fine chemicals and for the NIST series of SRMs have been reviewed (6). Another sphere of activity ia analytical standards is the geochemical reference standards maintained by the U.S. Geological Survey and by analogous groups ia France, Canada, Japan, South Africa, and Germany (7). 

Laser based mass spectrometric methods, such as laser ionization (LIMS) and laser ablation in combination with inductively coupled plasma mass spectrometry (LA-ICP-MS) are powerful analytical techniques for survey analysis of solid substances. To realize the analytical performances methods for the direct trace analysis of synthetic and natural crystals modification of a traditional analytical technique was necessary and suitable standard reference materials (SRM) were required. Recent developments allowed extending the range of analytical applications of LIMS and LA-ICP-MS will be presented and discussed. For example ... 

The set of Glass Standard Reference Material NIST SRM 610 - 614 was used for quantification of amount up to 45 trace elements in the synthetic oxide single crystals and natural quartzites. 

The helical-lobe compressor is further divided into a dry and a flooded form. The dry fonn uses timing gears to hold a prescribed timing to tlie relative motion of the rotors the flooded form uses a liquid media to keep the rotors from touching. The helical-lobe compressor is the most sophisticated and versatile of the rotary compressor group and operates at the highest rotor tip Mach number of any of the compressors in the rotary family. This compressor is usually referred to as the screw compressor or the SRM compressor. ... 

The next significant event in the evolution of the SRM compressor was the application of a Holroyd rotor cutting machine to the production of the rotors. Prior to this event, producing the rotors was both slow and costly. In 1952, the first special Holroyd machine was delivered to How-den Company, a licensee in the U.K., who later contributed to the development of the oil-flooded compressor. 

The development and subsequent patent of the oil-flooded compressor was the result of a joint effort on the part of Howden and SRM. The oil-... 

Lars Schibbye became chief engineer of SRM in 1950 and contributed to the technical advancement of the compressor. Most. significant was the invention of the asymmetric rotor profile, which was introduced commercially by Sullair in the U.S. in 1969. The asymmetric rotor profile reduces the leakage path area and sealing line length resulting in increased efficiency. 

The more recent developments have been in the area of manufacture, Rune Nilson of SRM worked with the machine tool manufacturers to develop precision carbide form cutting tools. These permit the rotors to be cut in two to three passes with high accuracy, The machining time has been reduced significantly. 

Figure 4-6. Pressure ratio vs. volumetric efficiency for an SRM compressor.

Ingram, Walter B., Notes on SRM Compressor History, unpublished. 

SRM compressor, 7 Stage pitch, 149 Stage,. uial. 226 Stage, cenirilugal, 134 Stagger ariL Ie, 227 Staggered... 

As an example of a standardless bulk analysis by SNMS, a measurement of the complex Ni-based Hasteloy metal (NIST SRM 2402) is presented in Figure 3 and Table 1, in which the composition determined from ion-current ratios (not RSF corrected) is compared to the certified chemical composition. 

NAA is a quantitative method. Quantification can be performed by comparison to standards or by computation from basic principles (parametric analysis). A certified reference material specifically for trace impurities in silicon is not currently available. Since neutron and y rays are penetrating radiations (free from absorption problems, such as those found in X-ray fluorescence), matrix matching between the sample and the comparator standard is not critical. Biological trace impurities standards (e.g., the National Institute of Standards and Technology Standard Rference Material, SRM 1572 Citrus Leaves) can be used as reference materials. For the parametric analysis many instrumental fiictors, such as the neutron flux density and the efficiency of the detector, must be well known. The activation equation can be used to determine concentrations ... 

Gel permeation ehromatography (GPC)/normal-phase HPLC was used by Brown-Thomas et al. (35) to determine fat-soluble vitamins in standard referenee material (SRM) samples of a fortified eoeonut oil (SRM 1563) and a eod liver oil (SRM 1588). The on-line GPC/normal-phase proeedure eliminated the long and laborious extraetion proeedure of isolating vitamins from the oil matrix. In faet, the GPC step permits the elimination of the lipid materials prior to the HPLC analysis. The HPLC eolumns used for the vitamin determinations were a 10 p.m polystyrene/divinylbenzene gel eolumn and a semipreparative aminoeyano eolumn, with hexane, methylene ehloride and methyl tert-butyl ether being employed as solvent. 

Figure 12.23 SFC-SFC analysis, involving a rotaiy valve interface, of a standard coal tar sample (SRM 1597). Two fractions were collected from the first SFC separation (a) and then analyzed simultaneously in the second SFC system (h) cuts a and h are taken between 20.2 and 21.2 min, and 38.7 and 40.2 min, respectively. Peak identification is as follows 1, tii-phenylene 2, chrysene 3, henzo[g/ i]perylene 4, antliracene. Reprinted from Analytical Chemistry, 62, Z. Juvancz et al, Multidimensional packed capillary coupled to open tubular column supercritical fluid chromatography using a valve-switcliing interface , pp. 1384-1388, copyright 1990, with permission from the American Chemical Society.

A solid propellant is a mechanical (heterogeneous) or a chemical (homogeneous, or colloidal) mixture of solid-state fuel and oxidizer-rich chemicals. Specially-formed charges of solid propellant (grains) arc placed in the combustion chamber of the solid rocket motor (SRM) at a production facility. Once assembled, the engine does not require additional maintenance, making it simple, reliable and easy to use. 

Potassium Dinitroazidophenolate (called Potassium Dinitrophenylazide by McNutt). K0,N3.CgH2(N02)2. It was proposed as an ingredient of primer mixts suitable for small srms and artillery ammo, commercial blasting caps, etc. Typical mixts suggested were 1)K Dinitroazidophenolate 16, Basic Pb Styphnate 15, Ba nitrate 40, Sb silicide 29% 2) K Dinitroazidophenolate 17, Basic Pb Styphnate 18, Ba nitrate 35, Pb thiocyanide 5, ground glass 25%... 

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