Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Special characters

Special characters , " - and " (blank) indicate rings and substitution... [Pg.24]

A year later, a novel method of encoding chemical structures via typewriter input (punched paper tape) was described by Feldmann [42]. The constructed typewriter had a special character set and recorded on the paper tape the character struck and the position (coordinates) of the character on the page. These input data made it possible to produce tabular representations of the structure. [Pg.44]

Blending to increase the alcohol (or other component) or to impart a special character to other wines or even other products, eg, whiskey... [Pg.367]

Butane LPO conducted in the presence of very high concentrations of cobalt catalyst has been reported to have special character (2,205,217—219). It occurs under mild conditions with reportedly high efficiency to acetic acid. It is postulated to involve the direct attack of Co(III) on the substrate. Various additives, including methyl ethyl ketone, -xylene, or water, are claimed to be useful. [Pg.343]

The first extension of this model, which accounts for the special character of the amphiphiles, has been the three-component model introduced by Schick and Shih in 1987 [171]. They simply add an additional triplet interaction... [Pg.658]

Note Decimal codes 00 to 31 and 127 and higher represent nonprintable control characters and special character codes. [Pg.111]

Here, the relative stability of the anion radical confers to the cleavage process a special character. Thus, at a mercury cathode and in organic solvents in the presence of tetraalkylammonium salts, the mechanism is expected16 to be an ECE one in protic media or in the presence of an efficient proton donor, but of EEC type in aprotic solvents. In such a case, simple electron-transfer reactions 9 and 10 have to be associated chemical reactions and other electron transfers (at the level of the first step). Those reactions are shown below in detail ... [Pg.1006]

Whether they are called surfaces or interfaces, when the zones between parts of a structure are "thin"— from a fraction of a micrometer (the limit of the ordinary microscope) down to molecular dimensions—the matter in them assumes a character that is somewhat different from that seen when the same matter is in bulk form. This special character of a molecular population arranged as an interfacial zone is manifested in such phenomena as surface tension, surface electronic states, surface reactivity, and the ubiquitous phenomena of surface adsorption and segregation. And the stmcturing of multiple interfaces may be so fine that no part of the resulting material has properties characteristic of any bulk material the whole is exclusively made up of transition zones of one kind or another. [Pg.168]

Symbol consecutive chain lengths Special Characters Description Equation where nsed... [Pg.618]

Note that the EXCEL engine specification is optional, because SAS would read the .xls extension in the physical filename and assume it indicates a Microsoft Excel file. Also note that the xlsfile libref refers to the entire Excel workbook. In the subsequent PROC PRINT, the normal ranges must be specified so SAS will know which Excel worksheet to read. The data set/worksheet name in the PROC PRINT looks odd because of the existence of a special character, which is normally not allowed as part of a data set name. [Pg.58]

The noteworthy point is a shortening of C-C bond distance as compared to the aliphatic C-C bond distance which is 1.54 A. This shortening manifests itself in the development of special character of the bonds. Since the sp orbitals of carbon now cannot overlap as effectively as they do in alkanes where perfect end-on overlap occurs the bonds in cyclopropane becomes bent and weak and also lead to an angle strain and so the molecule has greater potential energy. So this bent or banana bond accounts for the most of the ring strain. [Pg.173]

The dWi are Gaussian white noise processes, and their strength a is related to the kinetic friction y through the fluctuation-dissipation relation.72 When deriving integrators for these methods, one has to be careful to take into account the special character of the random forces employed in these simulations.73 A variant of the velocity Verlet method, including a stochastic dynamics treatment of constraints, can be found in Ref. 74. The stochastic... [Pg.17]

Already, at an early stage of the studies on the captodative effect, Viehe s group (Lahousse et ai, 1984) measured relative rates for the addition of t-butoxyl radicals to 4,4 -disubstituted 1,1-diphenylethylenes and to substituted styrenes. This study did not reveal a special character of captodative-substituted olefins in such reactions. It might be that the stability of the radical to be formed does not influence the early transition state of the addition step. The rationalization of the kinetic studies mentioned above in terms of the FMO model indicates, indeed, an early transition state for these reactions, with the consequence that product properties should not influence the reactivity noticeably. [Pg.170]

In a systematic study of the addition of cyclohexyl radicals to a-substi-tuted methyl acrylates, Giese (1983) has shown that the captodative-substituted example fits the linear correlation line of log with o-values as perfectly as the other cases studied. Thus, no special character of the captodative-substituted olefin is displayed. More recently, arylthiyl radicals have been added to disubstituted olefins in order to uncover a captodative effect in the rate data (Ito et aL, 1988). Even though a-A, A -dimethyl-aminoacrylonitrile reacts fastest in these additions, this observation cannot per se be interpreted as the manifestation of a captodative effect. Owing to the lack of rate data for the corresponding dicaptor- and didonor-substituted olefins, it is not possible to postulate a special captodative effect. The result confirms only that the A, A -dimethylamino-group, as expected from its a, -value, enhances the addition rate. In the sequence a-alkoxy-, a-chloro-, a-acetoxy- and a-methyl-substituted acrylonitriles, it reacts fastest. [Pg.170]

The Special Character of Oxyethylene Groups in Alkyl Ether Sulfates ... [Pg.8]

The chemical data presented clearly show the special character of alpine running waters compared to those in the midland and lowlands. The high water flow in these systems and the low anthropogenic activities produce only a small impact from pollution of nutrients and results mostly in their good chemical status. This... [Pg.116]

Like the journal article abstract, most conference abstracts have strict word limitations (typically between 150 and 200 words). Adherence to this limit is expected your abstract will likely be rejected if the limit is exceeded. Many other formatting specifications must also be followed. For example, most instructions include rules for formatting your title, author list, graphics, and special characters (e.g., pm, a, <, m ). The reason for such specificity is that your abstract, if accepted, will be printed (as is) in conference proceedings. Adherence to these guidelines by all authors ensures that the proceedings appear uniform and professional. [Pg.274]

Label all axes. A common format is to use unbolded font and to capitalize only the first letter of words (e.g., Reaction Time, not REACTION TIME). Place units in parentheses, using standard abbreviations (e.g., min, s) and special characters (e.g., a, p, m, Cb). Place labels outside and parallel to the axes. [Pg.527]

Real problems are likely to be considerably more complex than the examples that have appeared in the literature. It is for this reason that the computer assumes a particular importance in this work. The method of solution for linear-programming problems is very similar, in terms of its elemental steps, to the operations required in matrix inversions. A description ot the calculations required for the Simplex method of solution is given in Charnes, Cooper, and Henderson s introductory book on linear programming (C2). Unless the problem has special character-... [Pg.365]

This website offers a variety of resume-writing services. The most basic (and least expensive ) helps you create an ASCII or electronic resume that you can post to job boards or e-mail to employers that do not accept attachments. This pared-down resume style includes no fonts, graphics, or special characters instead, it emphasizes content and is scanner friendly. In addition, as part of this service, the company combines the content of your new electronic resume with its professional Web layouts to create a compelling Internet-based resume located at the company s Web address. The company will return to you an electronic, ASCII, or Web resume within 48 hours of your providing your resume information. [Pg.146]

Metal nanoparticles have been intensively studied due to their potential for both fundamental and applied research. They give a possibility to examine the material properties in transient conditions between the bulk material and separated atoms. Some phenomena, such as surface plasmon resonance transitions, electron-electron or electron-phonon scattering have special character in metal nanoparticles. [Pg.545]

Although the principal isotopes of Cl, Br, and 1 have magnetic properties, because of the special character of all of these isotopes, they act in organic compounds as though they were nonmagnetic. [Pg.296]

One of our informants attributed the interest of the group in personal development to its special character. [Pg.429]

Epilogue - The Special Character of Noble Metal Porphyrin Entities... [Pg.60]

The pure substances would be too irritant, but their action is graded by their slow liberation and by the presence of colloid extractives. The most common of these substances are emodin and chrysophanic acid. Numerous isomers of these are possible (15 for emodin alone). The special character of the different drugs is probably due to differences in these isomers, in the stability of their glucosidal combination, and to the presence of other associated substances (tannin in rhubarb). [Pg.160]

In different species or races, or even breeds developed by deliberate selection, whether they be fish, other animal or plant, the metabolism may assume a special character and rate depending on the specific ensemble of enzymatic reactions. For instance, the three races of anchovy described in this account differ in the ratio between their rates of protein biosynthesis and neutral lipid accumulation (Figure 78, page 225). What is most remarkable is that each of the processes is based on similar biochemical reactions, but the environments are different, as are the responses of the fish to them. [Pg.230]


See other pages where Special characters is mentioned: [Pg.238]    [Pg.361]    [Pg.168]    [Pg.619]    [Pg.463]    [Pg.54]    [Pg.165]    [Pg.312]    [Pg.296]    [Pg.302]    [Pg.319]    [Pg.10]    [Pg.349]    [Pg.92]    [Pg.51]    [Pg.47]    [Pg.358]    [Pg.617]    [Pg.618]    [Pg.42]    [Pg.36]    [Pg.555]   


SEARCH



© 2024 chempedia.info