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Electron / electronic

Number Electron Electron Electron Electron Electron Electron Electron Electron Electron Electron... [Pg.120]

In molecules with more than one unpaired electron, electron-electron interactions can have a significant role in the stabilization of the system. Bond formation that results from direct overlap is highly favorable and, thus is an overriding consideration in all low-spin polyradicals, even to the extent that the system sometimes adopts a strained, closed-shell state as opposed to a polyradical. In cases in which bonding cannot occur, indirect interactions that are usually insignificant, such as electron exchange and spin-polarization, can have significant impact. The presence of these interactions is often reflected in the thermochemical properties. [Pg.209]

U = 2 (kinetic) + 2 (proton-proton) - 4 (proton-electron) + (electron-electron)... [Pg.35]

The precise mathematical form of E " T for the Schrodinger equation will depend on the complexity of the structure being modelled. Its operator H will contain individual terms for all the possible electron-electron, electron-nucleus and nucleus-nucleus interactions between the electrons and nuclei in the structure needed to determine the energies of the components of that structure. Consider, for example, the structure of the hydrogen molecule with its four particles, namely two electrons at positions and r2 and two nuclei at positions R and R2. The Schrodinger Equation (5.5) may be rewritten for this molecule as ... [Pg.107]

M anufac t urer / Supplier Electronics Electronics Electronics... [Pg.294]

Equation 6.22 predicts that electronic conductivity is dependent on the electron relaxation time. However, it suggests no physical mechanisms responsible for controlling this parameter. Since electrons exhibit wave-particle duahty, scattering events could be suspected to play a part. In a perfect crystal, the atoms of the lattice scatter electrons coherently so that the mean-free path of an electron is infinite. However, in real crystals there exist different types of electron scattering processes that can limit the electron mean-free path and, hence, conductivity. These include the collision of an electron with other electrons (electron-electron scattering), lattice vibrations, or phonons (electron-phonon scattering), and impurities (electron-impurity scattering). [Pg.258]

In condensed matter the d and f electron states give rise to a large variety of properties due to their possibility of being either atomic-like states or band-like states with small changes in chemical composition, temperature, pressure, etc. Both types of states are discussed both from the theoretical (and computational) point of view and from the observed spectroscopic, electric and magnetic properties point of view with special emphasis in f electrons. Electron-electron correlation is shown to play a dominant role in these series of phenomena. [Pg.246]

The electron-electron, electron-nucleus, and nucleus-nucleus distances r j, and respectively, are defined in terms of the and r, position vectors. [Pg.216]

I valence — j bonding 1 - I non bonding electrons / electrons/ electrons... [Pg.43]

Free Carrier Scattering (electron-electron. electron-hole)... [Pg.285]

The operator V corresponds to the electrostatic interaction of all the particles (nucleus-nucleus, nucleus-electron, electron-electron) ... [Pg.68]

For the benzene molecule, we could answer questions like What is the mean value of the carbon-carbon, carbon-proton, proton-proton, electron-electron, electron-proton, and electron-carbon distances in the benzene molecule in its ground and excited states Note that because all identical particles are indistinguishable, the carbon-proton distance pertains to any carbon and any proton, and so on. To discover that the benzene molecule is essentially a planar hexagonal object would be very difficult. What could we say about a protein A pile of paper with such numbers would give us the trae (though non-relativistic) picture of the benzene molecule, but it would be useless, just as a map of the world with 1 1 scale would be useless for a tourist. It is just too exact. If we relied on this, progress in the investigation of the molecular world... [Pg.276]


See other pages where Electron / electronic is mentioned: [Pg.12]    [Pg.90]    [Pg.202]    [Pg.66]    [Pg.66]    [Pg.65]    [Pg.65]    [Pg.243]    [Pg.65]    [Pg.144]    [Pg.13]    [Pg.215]    [Pg.12]    [Pg.237]    [Pg.127]    [Pg.346]    [Pg.250]    [Pg.121]    [Pg.12]    [Pg.136]    [Pg.137]    [Pg.281]    [Pg.526]    [Pg.289]    [Pg.812]    [Pg.73]    [Pg.637]    [Pg.37]    [Pg.417]    [Pg.2]    [Pg.15]    [Pg.546]    [Pg.376]    [Pg.4]    [Pg.96]    [Pg.541]   
See also in sourсe #XX -- [ Pg.256 ]




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