Solid pesticide

The condition for uptake of the pesticide by the plant is given by its persistence or system characteristics. The most persistent pesticides are particularly organometallic (most of them organomercury) compounds or derivatives of chlorinated hydrocarbons. Depending on the concentration in the soil, they can be identified especially in root crops, carrot, radish, beet, potatoes and plants giving oil. The rate of uptake of these substances by plants are different even in the case of substances with a similar persistence [29, 30]. The uptake can also be different in the case of identical plants [31]. Solid pesticides penetrate more easily into agricultural products from sandy and clay soils [32]. 

Physical Description White or gray, odorless solid, [pesticide]... 

Physical Description Colorless to white, odorless, crystalline solid, [pesticide] [Note Forms hydrazoic acid (HN3) in water.] ... 

Solid Active Ingredients - Some pesticide applications require a particular physical form, generally to conform with application equipment available to the grower. Granules, for example, are commonly used as the means to apply insecticides to com. A solid active ingredient can be dissolved in a solvent and then absorbed by a carrier. This is, however, often not economical. The alternative used by the pesticide industry is to use a mineral as a substrate onto which the solid pesticide is adhered. High absorbency here is not required, and in fact can be detrimental. 

Size reduction of solid pesticide products can be accomplished with either mechanical energy or fluid energy mills (Perry, 1973). The choice depends on the physical behavior of the product, on the fineness of grind which must be achieved, and the concentration of active ingredient in the end-use product. 

Combustion in an incinerator is the only practical way to deal with many waste streams.This is particularly true of solid and concentrated wastes and toxic wastes such as those containing halogenated hydrocarbons, pesticides, herbicides, etc. Many of the toxic substances encountered resist biological degradation and persist in the natural environment for a long period of time. Unless they are in dilute aqueous solution, the most effective treatment is usually incineration. 

Two examples from the analysis of water samples illustrate how a separation and preconcentration can be accomplished simultaneously. In the gas chromatographic analysis for organophosphorous pesticides in environmental waters, the analytes in a 1000-mL sample may be separated from their aqueous matrix by a solid-phase extraction using 15 mb of ethyl acetate. After the extraction, the analytes are present in the ethyl acetate at a concentration that is 67 times greater than that in... 

This publication provides several examples of the use of solid-phase extractions for separating analytes from their matrices. Some of the examples included are caffeine from coffee, polyaromatic hydrocarbons from water, parabens from cosmetics, chlorinated pesticides from water, and steroids from hydrocortisone creams. Extracted analytes maybe determined quantitatively by gas (GC) or liquid chromatography (LG). 

A solvent free, fast and environmentally friendly near infrared-based methodology was developed for the determination and quality control of 11 pesticides in commercially available formulations. This methodology was based on the direct measurement of the diffuse reflectance spectra of solid samples inside glass vials and a multivariate calibration model to determine the active principle concentration in agrochemicals. The proposed PLS model was made using 11 known commercial and 22 doped samples (11 under and 11 over dosed) for calibration and 22 different formulations as the validation set. For Buprofezin, Chlorsulfuron, Cyromazine, Daminozide, Diuron and Iprodione determination, the information in the spectral range between 1618 and 2630 nm of the reflectance spectra was employed. On the other hand, for Bensulfuron, Fenoxycarb, Metalaxyl, Procymidone and Tricyclazole determination, the first order derivative spectra in the range between 1618 and 2630 nm was used. In both cases, a linear remove correction was applied. Mean accuracy errors between 0.5 and 3.1% were obtained for the validation set. 

Mancozeb is a dithiocarbamate pesticide with a very low solubility in organic and inorganic solvent. In this work we have developed a solvent free, accurate and fast photoacoustic FTIR-based methodology for Mancozeb determination in commercial fungicides. The proposed procedure was based on the direct measurement of the solid samples in the middle infrared region using a photoacoustic detector. A multivariate calibration approach based on the use of partial least squares (PLS) was employed to determine the pesticide content in commercially available formulations. 

Influence of speed and duration of aspiration on concentrating from air of pesticides as aerosol and vapors are investigated. Optimum conditions of concentrating on solid sorbents and paper filters are speed of 5 1/min during 20 minutes. 

Alkyl sulphoxides occur widely in small concentrations in plant and animal tissues. No gaseous sulphoxides are known and they tend to be colourless, odourless, relatively unstable solids soluble in water, ethyl alcohol and ether. They are freely basic, and with acids form salts of the type (R2S0H) X. Because sulphoxides are highly polar their boiling points are high. Their main use is as solvents for polymerization, spinning, extractions, base-catalysed chemical reactions and for pesticides. 

The main purpose of pesticide formulation is to manufacture a product that has optimum biological efficiency, is convenient to use, and minimizes environmental impacts. The active ingredients are mixed with solvents, adjuvants (boosters), and fillers as necessary to achieve the desired formulation. The types of formulations include wettable powders, soluble concentrates, emulsion concentrates, oil-in-water emulsions, suspension concentrates, suspoemulsions, water-dispersible granules, dry granules, and controlled release, in which the active ingredient is released into the environment from a polymeric carrier, binder, absorbent, or encapsulant at a slow and effective rate. The formulation steps may generate air emissions, liquid effluents, and solid wastes. 

Applicabdity Limitations Photolysis is appropriate for difficult-to-treat chemicals (e.g., pesticides, dioxins, chlorinated organics), nitrated wastes, and those chemicals in media which permits photolyzing the waste. The waste matrix can often shield chemicals from the light (e.g., ultraviolet light absorbers, suspended solids, solid wastes). The photolysis process typically requires pretreatment to remove suspended materials, and the by-products formed may be more toxic than the parent molecules. 

Applicability This process is applicable to liquid (pumpable) organic wastes and finely divided, fluidizable sludges. It may be particularly applicable to the processing of liquid wastes with a high chlorine, pesticide, PCB or dioxin content. Sludges must be capable of being fluidized by the addition of a liquid. Waste streams must be free of (or preprocessed to remove) solids, which prevent satisfactory atomization. 

COPPER-BASED PESTICIDE, FLAMMABLE, LIQUID, TOXIC, n.o.s., flash 2776 COPPER-BASED PESTICIDE, FLAMMABLE, LIQUID, TOXIC, n.o.s., flash 3009 COPPER-BASED PESTICIDE, LIQUID, TOXIC, n.o.s. 3010 COPPER-BASED PESTICIDE, SOLID, TOXIC, n.o.s. 2775 CORROSIVE LIQUIDS, FLAMMABLE, n.o.s. 2920... 

ORGANOCHLORINE PESTICIDES, FLAMMABLE, LIQUID, TOXIC, n.o.s., ORGANOCHLORINE PESTICIDES, LIQUID, TOXIC, n.o.s. ORGANOCHLORINE PESTICIDES, SOLID, TOXIC, n.o.s. 

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