Shear Strength Characterization

Those stmctural variables most important to the tensile properties are polymer composition, density, and cell shape. Variation with use temperature has also been characterized (157). Flexural strength and modulus of rigid foams both increase with increasing density in the same manner as the compressive and tensile properties. More specific data on particular foams are available from manufacturers Hterature and in References 22,59,60,131 and 156. Shear strength and modulus of rigid foams depend on the polymer composition and state, density, and cell shape. The shear properties increase with increasing density and with decreasing temperature (157). 

Jones, O.E. and Graham, R.A., Shear Strength Effects on Phase Transition Pressures Determined from Shock Compression Experiments, in Accurate Characterization of the High Pressure Environment (edited by Lloyd, E.C., National Bureau of Standards Special Publication 326, US Government Printing Office, Washington, DC, 1971, pp. 229-242. 

BRs were found to have a rate-sensitive mechanical response with very low tensile and shear strengths [63]. The stress-strain curves of the adhesives were characterized by an initial elastic response followed by a region of large plastic flow. 

Metal ion modified polyimide films have been prepared to obtain materials having mechanical, electrical, optical, adhesive, and surface chemical properties different from nonmodified polyimide films. For example, the tensile modulus of metal ion modified polyimide films was increased (both at room temperature and 200 0 whereas elongation was reduced compared with the nonmodif ied polyimide (i). Although certain polyimides are )cnown to be excellent adhesives 2) lap shear strength (between titanium adherends) at elevated temperature (275 0 was increased by incorporation of tris(acetylacetonato)aluminum(III) (2). Highly conductive, reflective polyimide films containing a palladium metal surface were prepared and characterized ( ). The thermal stability of these films was reduced about 200 C, but they were useful as novel metal-filled electrodes ( ). 

The interaction of two substrates, the bond strength of adhesives are frequently measured by the peel test [76]. The results can often be related to the reversible work of adhesion. Due to its physical nature such a measurement is impossible to carry out for particulate filled polymers. Even interfacial shear strength widely applied for the characterization of matrix/fiber adhesion cannot be used in particulate filled polymers. Interfacial adhesion of the components is usually deduced indirectly from the mechanical properties of composites with the help of models describing composition dependence. Such models must also take into account interfacial interactions. 

In-Plane Shear Properties. The basic lamina in-plane shear stiffness and strength is characterized using a unidirectional hoop-wound (90°) 0.1 -m nominal internal diameter tube that is loaded in torsion. The test method has been standardized under the ASTM D5448 test method for in-plane shear properties of unidirectional fiber-resin composite cylinders. D5448 provides the specimen and hardware geometry necessary to conduct the test. The lamina in-plane shear curve is typically very nonlinear [51]. The test yields the lamina s in-plane shear strength, t12, in-plane shear strain at failure, y12, and in-plane chord shear modulus, G12. 

Two different polyacrylonitrile precursor carbon fibers, an A fiber of low tensile modulus and an HM fiber of intermediate tensile modulus were characterized both as to their surface chemical and morphological composition as well as to their behavior in an epoxy matrix under interfacial shear loading conditions. The fiber surfaces were in two conditions. Untreated fibers were used as they were obtained from the reactors and surface treated fibers had a surface oxidative treatment applied to them. Quantitative differences in surface chemistry as well as interfacial shear strength were measur-ed. 

Here we have conducted experiments to develop an understanding of how the commercial size interacts with the matrix in the glass fiber-matrix interphase. Careful characterization of the mechanical response of the fiber-matrix interphase (interfacial shear strength and failure mode) with measurements of the relevant materials properties (tensile modulus, tensile strength, Poisson s ratio, and toughness) of size/matrix compositions typical of expected interphases has been used to develop a materials perspective of the fiber-sizing-matrix interphase which can be used to explain composite mechanical behavior and which can aid in the formulation of new sizing systems. 

The experiments consisted of three parts. In the first part, the characterization of minerals was explained by using x-ray diffractometer and electron microscope studies. Also, it was performed electrokinetic s studies of suspension. The effect of particle shape and size on the vacuum and pressure filtration of minerals has been investigated in the second part of the study. At the last part, the comparison of the particle shape and size effect on shear strength of the mineral filter cakes was performed. 

In this chapter, an overview of performance characterization of FRP-wood bonded interfaces by conventional and fracture mechanics tests [4- 7] is presented. Modified ASTM standard tests (ASTM D2559 and D905) are first used to study the service performance and shear strength of the bond under moisture and/or mechanical loads, and then a contoured or tapered double cantilever beam specimen [8] is used to evaluate the fracture toughness of bonded interfaces under dry and wet conditions and cyclic loading. 

By contrast, peelable or removable labels use adhesives with relatively low tack and shear strengths. On removal, no residue must remain on the surface from which the label was removed. Some removable labels use a water-soluble adhesive, permitting easy cleaning of the surface. These labels are used for temporary labeling or where they will frequently be replaced. Freezer labels use adhesives that have very good low-temperature flexibility to allow labels to be applied and remain adhered at temperatures down to —20°C or lower. They are characterized by very low glass temperatures, typically in the range —60 to —80°C. 

However, many European standards exist for the assessment of adhesives for structural purposes such as glulam beams for evident safety reasons. These standards allow to characterize in the most efficient way the adhesive properties such as, for example, shear strength according to EN 302-1 (2004) [2] or creep behaviour according to EN 15416-3 (2008) [3]. 

Continuous scans of modulus versus temperature utilizing the DuPont Dynamic Mechanical Analyzer (DMA) has provided a comparison of the high temperature service capabilities of radiation-cured experimental formulations of a vinyl-modified epoxy resin. Shell Epocryl-12. These scans were compared to data obtained when the same materials were applied as adhesives on aluminum test panels, radiation-cured with an electron beam, and lap shear strength tested at discrete temperatures. The DMA instrument utilizes a thin rectangular specimen for the analysis, so specimens can be cut from blocks or from flat sheets. In this case the specimens were cured as sheets of resin-saturated graphite-fibers. The same order of high temperature stability was obtained by each method. However, the DMA method provided a more complete characterization of temperature performance in a much shorter test time and thus, it can be very useful for quick analyses of formulation and processing variables in many types of materials optimization studies. The paper will present details of this study with illustrations of the comparisons. 

A primary method used to characterize adhesives is the lap shear test. A diagram of the test is shown in Fig. 27.1 and is described in Standard Test Method ASTM D1002 [4]. The specimen is usually 1 in. (2.54 cm) wide. The lap shear test places the adhesive in normal as weU as shear stress [5]. This type of test is used for many types of adhesives, with the exception of pressure-sensitive adhesives (PSAs, defined below). In the tables presented later, lap shear strength is presented in units of mega Pascal (MPa) and pounds per square inch (psi). The latter is shown in parenthesis. The temperature of the test will always be room temperature. 

---