Scientific interest

The Ag (100) surface is of special scientific interest, since it reveals an order-disorder phase transition which is predicted to be second order, similar to tire two dimensional Ising model in magnetism [37]. In fact, tire steep intensity increase observed for potentials positive to - 0.76 V against Ag/AgCl for tire (1,0) reflection, which is forbidden by symmetry for tire clean Ag(lOO) surface, can be associated witli tire development of an ordered (V2 x V2)R45°-Br lattice, where tire bromine is located in tire fourfold hollow sites of tire underlying fee (100) surface tills stmcture is depicted in tlie lower right inset in figure C2.10.1 [15]. 

As a furtlier example for tire meaning of ex situ investigations of emersed electrodes witli surface analytical teclmiques, results obtained for tire double layer on poly crystalline silver in alkaline solutions are presented in figure C2.10.3. This system is of scientific interest, since tliin silver oxide overlayers (tliickness up to about 5 nm) are fonned for sufficiently anodic potentials, which implies tliat tire adsorjDtion of anions, cations and water can be studied on tire clean metal as well as on an oxide covered surface [55, 56]. For tire latter situation, a changed... 

Materials that contain defects and impurities can exhibit some of the most scientifically interesting and economically important phenomena known. The nature of disorder in solids is a vast subject and so our discussion will necessarily be limited. The smallest degree of disorder that can be introduced into a perfect crystal is a point defect. Three common types of point defect are vacancies, interstitials and substitutionals. Vacancies form when an atom is missing from its expected lattice site. A common example is the Schottky defect, which is typically formed when one cation and one anion are removed from fhe bulk and placed on the surface. Schottky defects are common in the alkali halides. Interstitials are due to the presence of an atom in a location that is usually unoccupied. A... 

Other Spinning Processes. The following examples are of scientific interest but have not been employed on an industrial scale. 

There is growing commercial importance and escalating scientific interest in PVDF. The World Patent database, including the United States, Hsts 678 patents that cite the term poly(vinyHdene fluoride) for the period 1963—1980 and 2052 patents for the period 1981—1992 Chemical Abstracts files covering the years 1967—1992 contain 5282 references for the same term. Thirty years ago there was only one commercial producer of PVDF in the world now there are two in the United States, two in Japan, and three in Europe. 

The term laser is an acronym constmcted from light amplification by stimulated emission of radiation. The first operating laser was produced in 1960 (1). This laser, which used a crystal of mby [12174A9-17, chromium-doped alumina, Al202 Cr, and emitted a pulsed beam of collimated red light, immediately aroused scientific interest. 

Platinum was found in conjunction with gold after the Spanish conquest of South America. It was referred to as platina, or Htde silver. It was regarded as an unwanted impurity in the silver and gold, and was often discarded. However, scientific interest in platinum gradually grew and in 1741 the first samples of New World platinum were brought to England for scientific examination. 

Catalysis is done by an acidic solution of the stabilized reaction product of stannous chloride and palladium chloride. Catalyst absorption is typically 1—5 p-g Pd per square centimeter. Other precious metals can be used, but they are not as cost-effective. The exact chemical identity of this catalyst has been a matter of considerable scientific interest (19—21,23). It seems to be a stabilized coUoid, co-deposited on the plastic with excess tin. The industry trends have been to use higher activity catalysts at lower concentrations and higher temperatures. Typical usage is 40—150 ppm of palladium at 60°C maximum, and a 30—60-fold or more excess of stannous chloride. Catalyst variations occasionally used include alkaline and non-noble metal catalysts. 

The scientific interests of Anatoly K. Babko ranged widely, especially in regard to fundamental aspects of analytical chemistry, applications of organic reagents in inorganic analysis, chemistry of complex compounds (including heteropolyacids), analytical applications of complex compounds in photometry, luminescence and chemiluminescence, ion chromatography, and liquid-liquid extraction. 

Some 20 years after the pressure for the creation of the new interdisciplinary laboratories was first felt, one of the academics who became involved very early on. Prof. Rustum Roy of Pennsylvania State University, wrote eloquently about the underlying ideal of interdisciplinarity (Roy 1977). He also emphasised the supportive role played by some influential industrial scientists in that creation, notably Dr. Guy Suits of GE, whom we have already encountered, and Dr. William Baker of Bell Laboratories who was a major force in pushing for interdisciplinary materials research in industry and academe alike. A magisterial survey by Baker (1967), under the title Solid State Science and Materials Development, indicates the breadth and scope of his scientific interests. 

Toughening of a polymer-polymer interface with random copolymers can sometimes be more effective than with diblocks, providing the polymers are not too incompatible [80]. This is of industrial, as well as of scientific, interest as random copolymers are usually cheaper to produce. 

In shock-compression science the scientific interest is not so much in the study of waves themselves but in the use of the waves as a means to probe solid materials. As inertial responses to the loading, the waves contain detailed information describing the mechanical, physical, and chemical properties and processes in the unusual states encountered. Physical and chemical changes may be probed further with optical, electrical, or magnetic measurements, but the behaviors are intimately intertwined with the mechanical aspects of the waves. 

Very recently, the scientific interests of several leading theoretical laboratories have turned to studies of quenched-annealed fluids. To the best of our knowledge, there has not been a comprehensive review of the theoretical studies of quenched-annealed fluid systems. Our intention in this chapter is to fill, at least partially, an existing vacuum. Evidently, it is impossible to discuss the state of the art in this rapidly developing area in every detail in a single paper with restricted dimensions. We will omit, for example, the discussion of the fundamentals of the replica method for lattice systems, referring the reader to a monograph [1]. 

In presence of acids or other metal ions the five-unit macrocyclc of superphthalocyanines can be contracted to produce metal-free phlhalocyanine or metal phthalocyanines, respectively. This reaction might be more of scientific interest than of synthetic value. Nevertheless, one example is shown below. 

Hydrolysis of macrolides by products of the ere genes detected in enterobacteria is only of scientific interest, while esterases VGB-A and VGB-B encoded by the vgb type genes mediate clinically relevant resistance in staphylococci to the B compound (quinupristin) of the streptogramin combination quinu-pristin-dalfopristin. 

Rarely has any research area so continuously been in the focus of scientific interest as organosilicon chemistry. A rapidly increasing number of publications, review articles, and scientific conferences reflects this development. The initiating factor was the spectacular discovery of stable molecules with SiSi double bonds, disilaethenes (disilenes) by R. West and S. Masamune in 1981 and 1982 [1-7]. 

The scientific interest in cereal /1-glucans arose partly from the problems they cause in brewing and animal-feed industries in the case of barley [318] and partly from the health benefits, such as cholesterol reduction [319-321], regulation of postgrandial seriun glucose levels in humans and animals [319,322], and immunostimulatory activity [323,324]. Some of these activities have been observed with both oat and barley )6-glucans [325]. 

During the last decade, the larch AG, known as larch gum in food applications, has produced emerging commercial and scientific interest, which follows closely upon recent reports related to the beneficial physiological effects of the commercial larch AG and its immunomodulatory properties [379,380]. 

One of the main limitations of conventional AO is anisoplanatism most objects of scientific interest are too faint to act as their own reference source for AO correction, and it would be useful to use bright nearby objects, preferably stars, which act as point sources. However, the light from the object of interest which is intercepted by the telescope passes through a part of the turbulence which is different from that traversed by the light from the reference star. This leads to a decorrelation between the wavefront measurements obtained with the reference star and that which should be applied to correct the wavefronts... 

The scientific interest in porphyrin ligands (Fig. 5) derives in part from their ability to accommodate a large series of different elements, often in various oxidation states. On the other hand porphyrins are planar molecules with a delocalized 18 Ti-electron system and a diatropic ring current [25], which makes them interesting for the design of new materials with applications in photochemistry [25-27]. 

In this review I have traced the experiences of my research associates and myself as we explored the role of boranes in chemistry. Initially diborane was a very rare substance, made in milligram quantities in only a few laboratories throughout the world and explored purely for its scientific interest. 

The synthesis of nanoparticles has been intensively pursued not only for their fundamental scientific interest, but also for many technological applications [1]. For many of these applications, the synthesis of monodisperse nanoparticles (standard deviations a < 5%) with controlled particle sizes is of key importance, because the electrical, optical, and... 

Fellow at St John s College and was awarded the Humphreys Research prize. At Cambridge, Nigel was a Research Fellow of the Royal Commission for the Exhibition of 1851 and Royal Society University Research Fellow. He was elected a Fellow of the Royal Society of Chemistry in 1997. Aged 36, Nigel is now Professor at Leicester University and Lister Institute Research Fellow. He is a recipient of the Colworth Medal of the Biochemical Society. His scientific interests include mechanistic and quantum enzymology his recreational interests include Victorian and College philately. 

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