Rubber types components

As an example, let us consider a typical response produced by stretching a sample of a vulcanised rubber. The components of the stress that we have to consider are the normal stresses axx, [Pg.15]

Recent systematic studies on the relation between network structure and substituents in kraft lignin, steam exploded, have shown that the lignin containing networks can be modified in new ways, cf. e.g. (80). Also the toughening of glassy, structural thermosets can be achieved by incorporating a variety of polyether and rubber-type soft segment components in the polymer network structure. 

Rubbers have physical characteristics and a chemical composition that precludes their successful identification by infrared spectroscopy due to their inherent elasticity and highly filled composition. In contrast, no such difficulties are encountered with Py-GC. Crime scene rubber evidence from automotive tires and rubber vehicle components is found in hit-and-run cases and in soles of shoes worn by offenders in offenses against property. Discrimination of vehicle bumper rubbers by Py-GC has been reported. Volatile and polymeric components of rubbers and other polymers have been analyzed by Py-GC and the inorganic residue recovered for subsequent analysis. The technique may also be used to quantitate rubber blends by measuring the ratios of characteristic pyrolysis products. Figure 8.8 shows examples of the pyrograms of three common types of rubber. 

Differences in viscosity values and solubility parameters between NR and polar synthetic rubbers usually produce immiscible blends. Table 9.1 shows the solubility parameters of some relevant rubber types.The morphology of such blends is determined by the mixing procedure followed, the rheological properties and the degree of compatibility of the components involved. Investigating the morphology of the blend delivers significant information... 

Rubbers are aiso discussed in this section because in the usual applications there are blends of some rubber types (e.g., NR, NBR, SBR) and inorganic components (e.g., carbon black or silica). 

A major dry natural rubber type is ribbed smoked sheet. For this the coagulum is passed between pairs of even-speed steel rollers that squeeze the water out. The final set of rollers has channels cut in them so that the sheet emerging from them has a ribbed surface. The ribbed surface facilitates drying. This rubber is dried in smokehouses. The ribbed sheets are hung over poles mounted on trolleys. Rubber tree wood fires produce the smoke, which dries the rubber and gives the rubber some age resistance from its components such as cresols. Drying takes 48 to 96 hours, with entrance temperatures at about 40 °C and exit temperatures at about 60 °C. Some ribbed sheet rubber is dried in hot air out of contact with smoke. This produces a lighter colored rubber, which commands a premium and is referred to as air-dried sheets. 

Tests for the resistance to microbiological attack of rubbers in water contact applications are examined, with reference to standards in the UK and Germany. The influence of rubber type, additives and vulcanisation processes on microbiological resistance is discussed, and requirements for rubber components in contact with potable water are also reviewed. 5 refs. 

Silicone rubbers may be classified by crosslinking method, viscosity and vulcanisation temperature. Differentiation can be made between hot and cold (room temperature vulcanisation (RTV) rubber types. Within each of these two groups are found single-component and two-component systems, grouped by viscosity range. The viscosity of the rubber (fluid-mouldable, pasty, plastic-firm) determines the processing method and influences the characteristics of the vulcanised material. Figure 7.3 depicts the classification of silicones. 

Economics and price of the final article often dictate a specific type of mbber that can be used. The expected usable life for the product is controlled by many factors including end customer awareness, competitive situation in the marketplace, safety, reUabiUty, and other factors. Rubber is almost always used as a functional part of another system. For example tires, hoses, belts, O-rings, and numerous mbber components are used in manufacturing automobiles and tmcks. The overall life of the vehicle as well as its performance level often control or direcdy relate to the service life or quaUty level of the mbber parts. 

Rubber-Modified Copolymers. Acrylonitrile—butadiene—styrene polymers have become important commercial products since the mid-1950s. The development and properties of ABS polymers have been discussed in detail (76) (see Acrylonitrile polymers). ABS polymers, like HIPS, are two-phase systems in which the elastomer component is dispersed in the rigid SAN copolymer matrix. The electron photomicrographs in Figure 6 show the difference in morphology of mass vs emulsion ABS polymers. The differences in stmcture of the dispersed phases are primarily a result of differences in production processes, types of mbber used, and variation in mbber concentrations. 

Material characteristics, both chemical and physical, should be considered, especially flowabihty. Abrasiveness, friability, and lump size are also important. Chemical effects (e.g., the effect of oil on rubber or of acids on metal) may dictate the structural materials out of which conveyor components are fabricated. Moisture or oxidation effects from exposure to the atmosphere may be harmful to the material being conveyed and require total enclosure of the conveyor or even an artificial atmosphere. Obviously, certain types of conveyors lend themselves to such special requirements better than others. 

Because the polybutadiene component is liable to oxidation, ABS materials are embrittled on prolonged exposure to sunlight. By replacing polybutadiene rubber with other elastomers that contain no main chain double bonds it has been possible to produce blends generally similar to ABS but with improved weathering resistance. Three particular types that have achieved commercial status are ... 

Synthetic resins are extensively used, e.g., in surface finishes, in the fabrication and repair of boat and motor vehicle bodies, in the manufacture of laminated boards, for electrical components, in pattern making and in paints and varnishes. Non-rubber adhesives made from fish glues and from cotton derivatives (e.g. cellulose acetate) tend not to be sensitizing but, depending upon composition and the manner of use, many other types may pose significant dermatitic and fume hazards. 

Plastics, such as PE, PP, polystyrene (PS), polyester, and nylon, etc., and elastomers such as natural rubber, EPDM, butyl rubber, NR, and styrene butadiene rubber (SBR), etc., are usually used as blend components in making thermoplastic elastomers. Such blends have certain advantages over the other type of TPEs. The desired properties are achieved by suitable elasto-mers/plastic selection and their proportion in the blend. 

It is possible to distinguish between SBR and butyl rubber (BR), NR and isoprene rubber (IR) in a vulcan-izate by enthalpy determination. In plastic-elastomer blends, the existence of high Tg and low Tg components eases the problems of experimental differentiation by different types of thermal methods. For a compatible blend, even though the component polymers have different Tg values, sometimes a single Tg is observed, which may be verified with the help of the following equation ... 

The pneumatic tire has the geometry of a thin-wallcd toroidal shell. It consists of as many as fifty different materials, including natural rubber and a variety ot synthetic elastomers, plus carbon black of various types, tire cord, bead wire, and many chemical compounding ingredients, such as sulfur and zinc oxide. These constituent materials are combined in different proportions to form the key components of the composite tire structure. The compliant tread of a passenger car tire, for example, provides road grip the sidewall protects the internal cords from curb abrasion in turn, the cords, prestressed by inflation pressure, reinforce the rubber matrix and carry the majority of applied loads finally, the two circumferential bundles of bead wire anchor the pressnrized torus securely to the rim of the wheel. 

With the shear-type coupling, the elastomeric element may be clamped or bonded in place, or fitted securely to the hubs. The compression-type couplings may be fitted with projecting pins, bolts, or lugs to connect the components. Polyurethane, rubber, neoprene, or cloth and fiber materials are used in the manufacture of these elements. 

These materials are reviewed elsewhere in this book except RTV. The RTV (room temperature vulcanization) silicone plastic is a very popular type. It solidifies by vulcanization or curing at room temperature by chemical reaction, made up of two-part components of silicones and other elas-tomers/rubbers. RTV are used to withstand temperatures as high as 290° C (550°F) and as low as —160° C (—250°F) without losing their strength. Their rapid curing makes them... 

The investigations on boundary lubrication used to focus on the friction elements made of metallic materials, and of steel in particular. This is, of course, due to the fact that a great majority of machines are built from metal and steel, but it is also because the hydrocarbon-based oils have been proven to be an extraordinarily good lubricant for metal surfaces. Unfortunately, the conventional oils are not so effective to lubricate the components made of other materials, like ceramics, rubbers, silicon, etc., so that the study on new types of lubricants suitable for such materials has attracted great attention in recent years. 

There are two approaches to the combining of scrap rubber and plastics. The initial interest was to use the cmmb in minor proportions to toughen the plastics improving impact strength and reduce the overall cost. A more recent interest is to develop a type of thermoplastic elastomer (TPE) wherein the mbber is the major component bonded together by thermoplastics, which can be processed and recovered as thermoplastics. 

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