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Tire structure

In all of these oxide phases it is possible that departures from the simple stoichiometric composition occur dirough variation of the charges of some of the cationic species. Furthermore, if a cation is raised to a higher oxidation state, by the addition of oxygen to tire lattice, a conesponding number of vacant cation sites must be formed to compensate tire structure. Thus in nickel oxide NiO, which at stoichiomen ic composition has only Ni + cations, oxidation leads to Ni + ion formation to counterbalance the addition of extra oxide ions. At the same time vacant sites must be added to the cation lattice to retain dre NaCl sUmcture. This balanced process can be described by a normal chemical equation thus... [Pg.225]

Tire and NMR spectral data demonstrated the existence of 121 in the amino form (in CDCI3) (91H727) and 122 as the thione (in DMSO) (95H497). Tire structure of 122 (R = NHCOPh) was also confirmed by X-ray structural data (95H497). [Pg.89]

The pneumatic tire has the geometry of a thin-wallcd toroidal shell. It consists of as many as fifty different materials, including natural rubber and a variety ot synthetic elastomers, plus carbon black of various types, tire cord, bead wire, and many chemical compounding ingredients, such as sulfur and zinc oxide. These constituent materials are combined in different proportions to form the key components of the composite tire structure. The compliant tread of a passenger car tire, for example, provides road grip the sidewall protects the internal cords from curb abrasion in turn, the cords, prestressed by inflation pressure, reinforce the rubber matrix and carry the majority of applied loads finally, the two circumferential bundles of bead wire anchor the pressnrized torus securely to the rim of the wheel. [Pg.1140]

The inner liner forms the vital internal membrane which holds the inflation medium at an elevated pressure within the structure of the tire. In early days the liner was a separate tube of natural or butyl, or more particularly, XIIR compound as an integral part of the tire structure. Adhesion levels of butyl compounds can be critically low requiring an insulating or barrier layer of an NR compound to act as an interface between the liner and the casing. [Pg.451]

Limited formation of mixed crystals occurs when the two components have different structures, as for example in the case of indium and cadmium. Mixed crystals containing much indium and little cadmium have tire structure of indium, while those containing little indium and much cadmium have the cadmium structure. At intermediate compositions a gap is observed, i.e. there are no homogeneous mixed crystals, but Instead a mixture of crystals rich in indium and crystals rich in cadmium is formed. This situation can even... [Pg.35]

Mechanisms. Studies of model reactions473-476 and of electronic, Raman,456 477 478 ESR,479/480 and NMR spectra and kinetics481 have contributed to an understanding of these enzymes.459 461 464 482 483 For these copper amine oxidases the experimental evidence suggests an aminotransferase mechanism.450 453 474 4743 d Tire structure of the E.coli oxidase shows that a single copper ion is bound by three histidine imidazoles and is located adjacent to the TPQ (Eq. 15-53). Asp 383 is a conserved residue that may be the catalytic base in Eq. 15-53.474b A similar mechanism can be invoked for LTQ and TTQ. [Pg.817]

Tire Structural Organization of Striated Muscle Stress-Prone Pigs... [Pg.1088]

It is clear that all the data must fit the structure and vice versa. If not, the assigned structure is probably not correct. It is important to let the data indicate the structure and not make the data fit a preconceived structure. Often the chemistry will suggest a structure and the data will support that structure. However, that need not always be so, and it is necessary to always check that tire data fit tire structure. New chemistry is often discovered precisely because expected products are not supported by structural data. Consequently new structures resulting from new chemistry are revealed. [Pg.377]

Tire structure of a transition state resembles the structure of lire nearest stable species. Transition states for endergonic steps structurally resemble products, and transition states for exergonic steps structurally resemble reactants. [Pg.198]

The first step in the catabolism of most amino adds involves the removal of the -amino group. Removal of this group results in conversion of the amino acid to the corresponding keto add. Tire structures of a number of amino acids and their corresponding keto acids are shown in Table S.2. For example, this table lists pyruvate as the keto add version of alanine and a-keloglutarate as the keto acid of glutamate. [Pg.425]

Tire structure of Knecht compound has been examined by T. CTbanski ar Zyszczyhski [541. On the basis of infra red spectra they came to a conclusii that the cellulose moiety of the Knecht Compound is partly oxidized and shov the presence of a carbonyl group similar to that of oxycellulose (Vol. II, p. 321... [Pg.535]

According to reports Po et al. [31] and Amoco [32], tlie reaction rate of PEN is lower tlian other polyesters. Considerations about this fact lead to tlie assumption tliat tire structure-dependent reactivities of die acid and glycol components and dieir mobilities are responsible for the individual reaction rates of these polymers. Based on unpublished data, rigid or voluminous co-monomers result in reduced reactivities during melt polycondensation and SSP. The mobility of die component, as a result of its sttucture and stiffness, seems to explain this observation. [Pg.214]

Another possible feature of tire structures is associated with the entrapment of sediments. In certain configurations the nature and geometric properties of the tires may, for example, enhance the accretion of sand along and on a beach. [Pg.189]

To increase stability and reduce sliding of the whole structure, a key-in struc-tme may be used. It is suggested that key-in is used to insert the tire structure into the riverbed and walls of the channel. The dimension of key-in portion is... [Pg.198]

Tire structures used for shore and harbor protection fall into two categories. Floating tire breakwaters are built in locations offshore to attenuate incoming waves for harbor protection. Revetments type structures located directly on the shorehne are built to dissipate wave energy remaining at the shore. [Pg.201]

In surface water applications, the issue of physical integrity and aesthetics of hydraulic structures must be addressed as scrap tires are widely accepted as a suitable construction material. Poor deployment and construction practices may, however, lead to tires washing off after storms and result in environmental problems. The stabihty and integrity of a scrap tire structure must be maintained to prevent structural failure. This problem can be solved by improved design and construction with sufficient fastening and anchoring. [Pg.208]

In essence, a tire is a composite of complex elastomer formulations, fibers, textiles, and steel cord. The term tire structure defines the number, location, and dimensions of the various components used in a tire s composition. The primary components that govern the performance of a tire are the casing plies, bead construction, belts, sidewall, inner liner, and tread. Chafers, flippers, and overlays, which are strips of rubberized fabric located in the bead and crown area of the tire, are termed secondary components because they protect the primary components by minimizing stress concentrations (Ford and Charles, 1988 Davison, 1969). [Pg.658]


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See also in sourсe #XX -- [ Pg.625 ]




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