Alloys resistance

It is extensively used for making stainless steel and other corrosion-resistant alloys such as Invar(R), Monel(R), Inconel(R), and the Hastelloys(R). Tubing made of copper-nickel alloy is extensively used in making desalination plants for converting sea water into fresh water. 

Health and Safety Factors. Unlike fluoroacetic acid, trifluoroacetic acid presents no unusual toxicity problems. However, owing to its strong acidity, its vapors can be irritating to tissue, and the Hquid acid can cause deep bums if allowed to contact the skin. The acid can be safely stored in containers made of glass or common corrosion-resistant alloys and metals such as stainless steel or alurninum. 

Molten ETFE polymers corrode most metals, and special corrosion-resistant alloys ate recommended for long-term processiag equipmeat short-term prototype mas are possible ia standard equipment. 

Aqueous formaldehyde is corrosive to carbon steel, but formaldehyde in the vapor phase is not. AH parts of the manufacturing equipment exposed to hot formaldehyde solutions must be a corrosion-resistant alloy such as type-316 stainless steel. Theoretically, the reactor and upstream equipment can be carbon steel, but in practice alloys are required in this part of the plant to protect the sensitive silver catalyst from metal contamination. 

Heating elements operating <760°C are almost always of a chrome—nickel resistance alloy and are ia the form of ribbon, cast alloy, open wire cods, or sheathed constmction. Several alloys are suitable ia this temperature range and all are satisfactory if properly appHed. In general, the more expensive alloys are used when physical space limitations dictate higher watts per area dissipation from the element. 

Hastelloy Corrosion Resistant Alloys, Haynes International, Inc., Kokomo, Ind., 1987 to 1993. 

Porcelain enameling requires the use of frits and melting temperatures of 550 °C or below. Enamels are appHed over chemical conversion coatings that are compatible with the frit. AHoy selection is important to obtain good spall resistance. Alloys 1100, 3003, and 6061 are employed most extensively among wrought products and alloy 356 for castings. 

Wood is widely used as a stmctural material in the chemical industry because it is resistant to a large variety of chemicals. Its resistance to mild acids is far superior to that of steel but not as good as some of the more expensive acid-resistant alloys. Wood tanks used to store cold, dilute acid have a relatively long service life. However, increasing concentration or temperature causes the wood tank to deteriorate rapidly (6). 

Oxychlorination of Ethylene or Dichloroethane. Ethylene or dichloroethane can be chlorinated to a mixture of tetrachoroethylene and trichloroethylene in the presence of oxygen and catalysts. The reaction is carried out in a fluidized-bed reactor at 425°C and 138—207 kPa (20—30 psi). The most common catalysts ate mixtures of potassium and cupric chlorides. Conversion to chlotocatbons ranges from 85—90%, with 10—15% lost as carbon monoxide and carbon dioxide (24). Temperature control is critical. Below 425°C, tetrachloroethane becomes the dominant product, 57.3 wt % of cmde product at 330°C (30). Above 480°C, excessive burning and decomposition reactions occur. Product ratios can be controlled but less readily than in the chlorination process. Reaction vessels must be constmcted of corrosion-resistant alloys. 

Table 5. Compositions of Cobalt-Base Wear-Resistant Alloys, wt...

Alloy Compositions and Product Forms. The nominal compositions of various cobalt-base wear-resistant alloys are Hsted in Table 5. The six most popular cobalt-base wear alloys are Hsted first. SteUite alloys 1, 6, and 12, derivatives of the original cobalt—chromium—tungsten alloys, are characterized by their carbon and tungsten contents. SteUite aUoy 1 is the hardest, most abrasion resistant, and least ductile. 

The two corrosion-resistant alloys presented ia Table 5 rely on chromium and molybdenum for their corrosion resistance. The corrosion properties of IJ1 timet are also enhanced by tungsten. Both alloys are available ia a variety of wrought product forms plates, sheets, bars, tubes, etc. They are also available ia the form of welding (qv) consumables for joining purposes. 

Mechanical Properties. An advantage of the two corrosion-resistant alloys is that they may be strengthened considerably by cold working. MP35N alloy is iatended for use ia the work-hardened or work-hardened and aged condition, and the manufacturers have suppHed considerable data concerning the mechanical properties of the alloy at different levels of cold work. Some of these data are given ia Table 8. 

For most environments quantitative studies have been reported describing the corrosion rate of various materials including a number of corrosion-resistant alloys (30). For example. Table 4 gives weight losses suffered by corrosion-resistant alloys in a solution of 28% phosphoric acid [7664-38-2] 20—22% sulfuric acid [7664-93-9] and 1—15% duoride (36). 

Other than the wear problems, actual in-plant maintenance usually involves removal of wood, pieces of blasting wire, and other trash from the ports. When a reagentized feed is used, layers of oily reagents can build up on the spiral surface and sometimes require scrubbing for removal. With feeds containing oily reagents that attack rubber, ra-sion-resistant alloy spiral sections are used. 

Actually, in many cases strength and mechanical properties become of secondaiy importance in process applications, compared with resistance to the corrosive surroundings. All common heat-resistant alloys form oxides when exposed to hot oxidizing environments. Whether the alloy is resistant depends upon whether the oxide is stable and forms a protective film. Thus, mild steel is seldom used above 480°C (900°F) because of excessive scaling rates. Higher temperatures require chromium (see Fig. 28-25). Thus, type 502 steel, with 4 to 6 percent Cr, is acceptable to 620°C (I,I50°F). A 9 to 12 percent Cr steel will handle 730°C (I,350°F) 14 to 18 percent Cr extends the limit to 800°C (I,500°F) and 27 percent Cr to I,I00°C (2,000°F). 

Heat resistance and gas corrosion resistance depends on chemical, phase compositions and stmcture of an alloy. The local corrosion destmction (LCD) of heat resisting alloys (HRS), especially a cast condition, probably, is determined by sweat of alloying elements. 

Substituting more-resistant materials such as stainless steels and copper alloys for less-resistant alloys such as carbon steels... 

---