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Radical benzoyl peroxide

Such reactions can be initiated by free radicals, derived from compounds (initiators) such as benzoyl peroxide, ammonium persulphate or azobis-isobutyronitrile or by ionic mechanisms... [Pg.321]

Such a mechanism is supported by the fact that the reaction is accelerated by benzoyl peroxide and other radical-producing agents. It is now however considered that the function of the A -bromosuceinimide is to provide a constant, very low concentration of molecular bromine (Tedder et al,). [Pg.177]

These results show that in the phenylation of thiazole with benzoyl peroxide two secondary reactions enter in competition the attack of thiazole by benzoyloxy radicals, leading to a mixture of thiazolyl benzoates, and the formation of dithiazolyle through attack of thiazole by the thiazolyl radicals resulting from hydrogen abstraction on the substrate and from the dimerization of these radicals. This last reaction is less important than in the case of thiophene but more important than in the case of pyridine (398). [Pg.109]

Benzoyl peroxide has been the most common source of phenyl radicals. But in reaction with thiazoles the benzoyloxy radical abstracts a hydrogen atom from the thiazole nucleus or from a methyl group in the case of methylthiazoles, giving by-products such as dithiazolyls or 2.2 -dithiazolylethane (183). The results obtained with benzoyl peroxide are summarized in Tables III-23, III-24. and III-25. [Pg.364]

Benzoyl peroxide is a com monly used free radical ini tiator It has the formula O O... [Pg.442]

Polymerization of styrene is carried out under free radical conditions often with benzoyl peroxide as the initiator Figure 1111 illustrates a step m the growth of a poly styrene chain by a mechanism analogous to that of the polymerization of ethylene (Sec tion 6 21)... [Pg.449]

When initiator is first added the reaction medium remains clear while particles 10 to 20 nm in diameter are formed. As the reaction proceeds the particle size increases, giving the reaction medium a white milky appearance. When a thermal initiator, such as AIBN or benzoyl peroxide, is used the reaction is autocatalytic. This contrasts sharply with normal homogeneous polymerizations in which the rate of polymerization decreases monotonicaHy with time. Studies show that three propagation reactions occur simultaneously to account for the anomalous auto acceleration (17). These are chain growth in the continuous monomer phase chain growth of radicals that have precipitated from solution onto the particle surface and chain growth of radicals within the polymer particles (13,18). [Pg.278]

The reaction rate of fumarate polyester polymers with styrene is 20 times that of similar maleate polymers. Commercial phthaHc and isophthaHc resins usually have fumarate levels in excess of 95% and demonstrate full hardness and property development when catalyzed and cured. The addition polymerization reaction between the fumarate polyester polymer and styrene monomer is initiated by free-radical catalysts, commercially usually benzoyl peroxide (BPO) and methyl ethyl ketone peroxide (MEKP), which can be dissociated by heat or redox metal activators into peroxy and hydroperoxy free radicals. [Pg.317]

Whereas vinyl acetate [108-05-4] upon heating with benzoyl peroxide or other free-radical initators, forms solid polymers of high molecular... [Pg.80]

Benzoyl chloride is an important benzoylating agent. In this use the benzoyl radical is introduced into alcohols, phenols, amines, and other compounds through the Friedel-Crafts reaction and the Schotten-Baumaim reaction. Other significant uses are in the production of benzoyl peroxide [94-56-0], benzophenone [119-61-9], and in derivatives employed in the fields of dyes, resins, perfumes, pharmaceuticals, and as polymerization catalysts. [Pg.56]

Resin cement materials are provided as a two-part powder—Hquid product. The powder consists largely of poly(methyl methacrylate) to which various fillers (qv) maybe added. These include calcium carbonate [471-34-1], siHca [7631-86-9], barium carbonate [513-77-9], and calcium tungstate [7790-75-2]. An organic peroxide, eg, benzoyl peroxide, capable of generating free radicals is also present (see Initiators Peroxides, organic). [Pg.475]

Benzoyl peroxide is the source of the phenyl radicals, except for the first entry, where it is nitrosoacetanilide. [Pg.73]

The initiation stage may be activated by free-radical or ionic systems. In the following example a free-radical system will be discussed. In this case a material which can be made to decompose into free radicals on warming, or in the presence of a promoter or by irradiation with ultraviolet light, is added to the monomer and radicals are formed. Two examples of such materials are benzoyl peroxide and azodi-isobutyronitrile, which decompose as indicated in Figure 2.13. [Pg.25]

The peroxide decomposes at elevated temperatures to give free radicals, which then abstract a hydrogen atom from the methyl group. The radicals formed then combine to form a hydrocarbon linkage. Results obtained by reacting model systems with benzoyl peroxide and analysing the reaction products are consistent with this type of mechanism. ... [Pg.838]

The reaction between benzoyl peroxide and A,A-dimethylaniline has been the subject of many examinations over the years. The following mechanism of initiation is fairly well accepted in the polymerization of styrene. It seems likely that a similar mechanism is followed for other free-radical polymerizations (Scheme 5). [Pg.833]

Free-radical carboxymethylation of several aromatic compounds has been reported, " the -CHaCOOH radical being produced by the thermal decomposition of benzoyl peroxide in acetic acid. More recently the carboxymethylation of dibenzofuran brought about by the thermal decomposition of chloroacetylpolyglycolic acid (41) has... [Pg.160]

A careful study of the phenylation of quinoxaline with benzoyl peroxide, various benzenediazonium salts, and A -nitrosoacetanilide indicates that the 2-position is most reactive to phenyl radicals and that the 5-position is more reactive than the 6. The yields of 2-, 5-, and 6-phenylquinoxaline are in the ratio of 40 10 1, Benzoyl peroxide and A—nitrosoacetanilide are the most effective phenylating reagents. [Pg.212]

Peroxide initiators may also undergo primary radical transfer to produce unsaturated end groups, which may result in a less stable polymer. In the case of benzoyl peroxide, an additional possibility is initiation by phenyl radicals to give a polymer with terminal phenyl groups [Eq. (17)] ... [Pg.323]

In the presence of radical initiators such as benzoyl peroxide (BPO), azobisisobutyronitrile (AIBN), persulfates (S208 ), etc., grafting of vinyl monomers onto polymeric backbones involves generation of free radical sites by hydrogen abstraction and chain transfer processes as described below ... [Pg.483]

The effect of Fe(II) on grafting of 2-hydroxyethyl methacrylate onto polyester fibers in the presence of benzoyl peroxide was investigated [59]. It was found that increasing the iron ion concentration decreases the graft yield. This suggest that excess Fe(ll) ions participate in the generation of free radical species and the iron ions seem to contribute to the termination and, consequently, decrease the graft yield. [Pg.506]

Historically, ethylene potymerization was carried out at high pressure (1000-3000 atm) and high temperature (100-250 °C) in the presence of a catalyst such as benzoyl peroxide, although other catalysts and reaction conditions are now more often used. The key step is the addition of a radical to the ethylene double bond, a reaction similar in many respects to what takes place in the addition of an electrophile. In writing the mechanism, recall that a curved half-arrow, or "fishhook" A, is used to show the movement of a single electron, as opposed to the full curved arrow used to show the movement of an electron pair in a polar reaction. [Pg.240]

I Initiation The polymerization reaction is initiated when a few radicals are generated on heating a small amount of benzoyl peroxide catalyst to break the weak 0-0 bond. A benzoyloxy radical then adds to the C=C bond of ethylene to generate a carbon radical. One electron from the C=C bond pairs up with the odd electron on the benzoyloxy radical to form a C-O bond, and the other election remains on carbon. [Pg.240]

Side-chain bromination at the benzylic position occurs when an alkylbenzene is treated with /V-bromosuccinimide (NBS). For example, propylbenzene gives (l-bromopropyl)benzene in 97% yield on reaction tvith NBS in the presence of benzoyl peroxide, (PhC02)2f as a radical initiator. Bromination occurs exclusively in the benzylic position and does not give a mixture of products. [Pg.578]

The polymerization of vinyl monomers on the surface of silica can be induced also by free radical initiators such as azo-bis-isobutyronitrile (AIBN), di-tert-butylperoxide, benzoyl peroxide etc. The selection of initiator type and method of its introduction in polymerizable systems are determined by the nature of monomers and tasks of investigations. Usually, the following procedures are used ... [Pg.161]

Vinyl Acetate CH3COOCH=CH2 OH compds, HCN, Halides, Halogens, Mer-cap tans, Amine, Silanes Oxygen Vap in Air 2.6 to 13.4% > Ambient > Ambient Inhibitor—Methyl Ether of Hydroquinone or 3-5ppm Diphenylamine. Store in a dry, cool place shield from light impurities 20.9-21.5 402 427 Free-radical polymerization initiated by Benzoyl Peroxide... [Pg.822]

Benzoyl peroxide can help remove dead skin cells, which in turn prevents the pores from clogging up. It also kills the Propionibac-terium acnes bacterium that causes acne. It has anti-inflammatory effects and reduces oxygen free radicals and fatty acids on the skin. [Pg.165]


See other pages where Radical benzoyl peroxide is mentioned: [Pg.37]    [Pg.37]    [Pg.108]    [Pg.268]    [Pg.42]    [Pg.53]    [Pg.464]    [Pg.339]    [Pg.488]    [Pg.153]    [Pg.208]    [Pg.273]    [Pg.424]    [Pg.483]    [Pg.485]    [Pg.76]    [Pg.85]    [Pg.127]    [Pg.676]    [Pg.688]    [Pg.689]   
See also in sourсe #XX -- [ Pg.6 ]




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