Polystyrene plasticization

Benzene was prepared from coal tar by August W von Hofmann m 1845 Coal tar remained the primary source for the industrial production of benzene for many years until petroleum based technologies became competitive about 1950 Current production IS about 6 million tons per year m the United States A substantial portion of this ben zene is converted to styrene for use m the preparation of polystyrene plastics and films... 

The annual production of styrene in the United States is approximately 1 2 X 10 lb with about 65% of this output used to prepare polystyrene plastics and films Styrofoam coffee cups are made from polystyrene Polystyrene can also be produced m a form that IS very strong and impact resistant and is used widely m luggage television and radio cabinets and furniture... 

The acetone supply is strongly influenced by the production of phenol, and so the small difference between total demand and the acetone suppHed by the cumene oxidation process is made up from other sources. The largest use for acetone is in solvents although increasing amounts ate used to make bisphenol A [80-05-7] and methyl methacrylate [80-62-6]. a-Methylstyrene [98-83-9] is produced in controlled quantities from the cleavage of cumene hydroperoxide, or it can be made directly by the dehydrogenation of cumene. About 2% of the cumene produced in 1987 went to a-methylstyrene manufacture for use in poly (a-methylstyrene) and as an ingredient that imparts heat-resistant quaUties to polystyrene plastics. 

Table 16.5 Typical mechanical properties of compression-moulded polystyrene plastics as measured by appropriate ASTM tests...

Polystyrene Plastic derived from a resin produced by the polymer-... 

History. The first attempts to desensitize RDX were reported by Frankel and Carle ton (Refs 1 thru 5) who made use of polymeric materials such as polyurethanes to coat expl crysts by means of emulsion or soln techniques. The first true PB-RDX was developed in 1952 at the Univ of Califs Los Alamos Lab and consisted of RDX coated with polystyrene plasticized with DOP (Refs 6 21). Since then the Lawrence Livermore Lab has evolved a series of PBX formulations, many of which are listed in Tables 3,4 5. These compns are described in Ref 77... 

Pyrolysis for the Recycling of Polystyrene Plastic (PSP) Wastes in a Swirling Fluidized-Bed Reactor... 

In the present study, the pyrolysis of a waste polystyrene plastic (PSP) has beat investigated in a swirling fluidized-bed reactor to develop an effective reactor. Effects of the reaction time, temperature, ratio of the swirling gas and the gas velocity on the yields of an oil and a styrene monomer have been discussed. 

The waste polystyrene plastic (PSP) was melted at 250°C prior to being injected into the reactor, to create particles with a mean diameter of 2 mm. About fifty grams of feed material (waste PSP) was fed into the reactor at a given operating condition. The oil product or styrene monomer was obtained... 

Moody PBS None 50 pg/mL Nunc Maxisorb, polystyrene plastic None SuperBlock... 

Samples should be collected aseptically in nonpyrogenic containers. Reused depyrogenate glassware or sterile, disposable polystyrene plastics are recommended to minimize adsorption of endotoxin. 

Where w again represents weight fraction M is molecular weight and subscripts 1 and 2 refer to polymer and plasticizer, respectively. We use the notation, cp here to indicate that the constant may vary from one plasticizer to another. Figure 1 shows a plot of Tg vs. 1/ Mn for several polystyrene-plasticizer systems. If Mi is very much larger than M2, Equation 7 becomes... 

Examination of Plasticizer Behavior in the System Polystyrene-Plasticizer... 

We shall conclude with some remarks on the structure of glassy polymers. If one frequently speaks of glass structures, this does not mean that there exists one definite glass structure similar to a crystal. In a macromolecular solid-e.g., the polystyrene-plasticizer system, entirely different glasses are obtainable, the macroscopic composition of which is always the same (8). In Figure 10 the full... 

PES = Polyester-styrene copolymer NG = Nitroglycerine PS NGU - Polystyrene plasticizer with dioctylphthalate = Nitroguanidine PU = Polyurethane NC = Nitrocellulose ... 

Benzene is a volatile, colorless, highly flammable liquid that is consumed as a raw material for the manufacture of phenolic and polyester resins, polystyrene plastics, alkylbenzene surfactants, chlorobenzenes, insecticides, and dyes. It is hazardous both for its ignitability and toxicity (exposure to benzene causes blood abnormalities that may develop into leukemia). Naphthalene is the simplest member of a large number of multicychc aromatic hydrocarbons having two or more fused rings. It is a volatile white crystalline solid with a characteristic odor and has been used to make mothballs. The most important of the many chemical derivatives made from naphthalene is phthalic anhydride, from which phthalate ester plasticizers are synthesized. 

Polystyrene plastic tubes, pipette-tips (Becton Dickinson, NJ)... 

Our study is outlined in five parts, (a) Two polystyrene plastics were reinforced at different fiber contents alternately with polyester, asbestos, and glass fibers, (b) The mechanical/physical properties of the resultant monofiber-reinforced plastics were determined and compared, (c) Combinations of fibers were then used to fabricate multifiber-rein-forced structures to exploit simultaneously the particular advantages of the different reinforcements, (d) The effect of each fabrication stage on the molecular weight and molecular weight distribution of the matrix plastics was established and (e) a linear mathematical model was formulated to predict the properties of multifiber structures and forecasted values compared with corresponding values experimentally obtained from (c) above. 

The foregoing analysis summarizes the results obtained with the 50D3 polystyrene plastic. With the 817D9 material, although the impact... 

K-Resin SB Copolymer/Crystal Polystyrene Sheet Property Modification with High Impact Polystyrene, Plastics Technical Center Report 409, Chevron Phillips Chemical Co., Bartlesville, OK. 

Microcrystalline cellulose (Merck) appears to have been used most successfullybut even this support matrix should be used with continuous mixing to maintain adequate suspension. The inclusion of a nonionic detergent in the incubation mixture (0.5% v/v Tween-20 - 0.1% v/v Brij-35 ) helps to keep the particles dispersed and to reduce nonspecific binding. Other aproaches and matrices used with variable success have included conjugation to iron oxide particles coated with polymerized w-diaminobenzene, adsorption to individual polystyrene balls 6.4 mm in diameter, and adsorption to polystyrene plastic tubes. 

Mackowski, R., Majewski, S., Ostowski, K. Phenol-polystyrene plastic foams. Polim.-Tworz. Wielkoraasteczkowe 3, 107 (1978) (in Polish)... 

Separation of benzene/cyclohexane mixture is investigated most extensively. This is not surprising because separation of this mixture is very important in practical terms. Benzene is used to produce a broad range of valuable chemical products styrene (polystyrene plastics and synthetic rubber), phenol (phenolic resins), cyclohexane (nylon), aniline, maleic anhydride (polyester resins), alkylbenzenes and chlorobenzenes, drugs, dyes, plastics, and as a solvent. Cyclohexane is used as a solvent in the plastics industry and in the conversion of the intermediate cyclohexanone, a feedstock for nylon precursors such as adipic acid. E-caprolactam, and hexamethylenediamine. Cyclohexane is produced mainly by catalytic hydrogenation of benzene. The unreacted benzene is present in the reactor s effluent stream and must be removed for pure cyclohexane recovery. 

Qlhe polymer polyvinyl chloride is commonly called "vinyl." it is used to make flexible, waterproof objects. o Polystyrene plastic is inexpensive and easy to mold into parts for model cars and airplanes. 

Styrene is produced by the alkylation of benzene with ethylene followed by catalytic dehydrogenation. It is used in the manufacture of general-purpose and high-impact polystyrene plastics ( 50%), expanded polystyrene ( 7%), copolymer resins with acrylonitrile and butadiene ( 7%) or acrylonitrile only ( 1%), styrene-butadiene latex ( 6%) and synthetic rubber ( 5%), unsaturated polyester resins ( 6%), and as a chemical intermediate. 

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