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Dehydrogenation catalytic

Olefin—Paraffin Separation. The catalytic dehydrogenation of / -paraffins offers a route to the commercial production of linear olefins. Because of limitations imposed by equiUbrium and side reactions, conversion is incomplete. Therefore, to obtain a concentrated olefin product, the olefins must be separated from the reactor effluent (81—85), and the unreacted / -paraffins must be recycled to the catalytic reactor for further conversion. [Pg.300]

Butadiene Separation. Solvent extraction is used in the separation of butadiene (qv) [106-99-0] from other C-4 hydrocarbons in the manufacture of synthetic mbber. The butadiene is produced by catalytic dehydrogenation of butylene and the Hquid product is then extracted using an aqueous cuprammonium acetate solution with which the butadiene reacts to form a complex. Butadiene is then recovered by stripping from the extract. Distillation is a competing process. [Pg.79]

Other potential processes for production of formic acid that have been patented but not yet commerciali2ed include Hquid-phase oxidation (31) of methanol to methyl formate, and hydrogenation of carbon dioxide (32). The catalytic dehydrogenation of methanol to methyl formate (33) has not yet been adapted for formic acid production. [Pg.504]

L = P(CH3)3 or CO, oxidatively add arene and alkane carbon—hydrogen bonds (181,182). Catalytic dehydrogenation of alkanes (183) and carbonylation of bensene (184) has also been observed. Iridium compounds have also been shown to catalyse hydrogenation (185) and isomerisation of unsaturated alkanes (186), hydrogen-transfer reactions, and enantioselective hydrogenation of ketones (187) and imines (188). [Pg.182]

Butadiene. Although butadiene was produced in the United States in the eady 1920s, it was not until the start of Wodd War 11 that significant quantities were produced to meet the war effort. A number of processes were investigated as part of the American Synthetic Rubber Program. Catalytic dehydrogenation of / -butenes and / -butanes (Houdry process) and thermal cracking of petroleum hydrocarbons were chosen (12). [Pg.494]

Most synthetic camphor (43) is produced from camphene (13) made from a-piuene. The conversion to isobomyl acetate followed by saponification produces isobomeol (42) ia good yield. Although chemical oxidations of isobomeol with sulfuric/nitric acid mixtures, chromic acid, and others have been developed, catalytic dehydrogenation methods are more suitable on an iadustrial scale. A copper chromite catalyst is usually used to dehydrogenate isobomeol to camphor (171). Dehydrogenation has also been performed over catalysts such as ziac, iadium, gallium, and thallium (172). [Pg.425]

Synthetic methods for the production of citroneUal iaclude the catalytic dehydrogenation of citroneUol (110), the telomerization of isoprene (151), and the Utbium-catalyzed reaction of myrcene with secondary alkylamines (128). [Pg.425]

BASF. In the Badische process, cyclohexanone is produced by Hquid-phase catalytic air oxidation of cyclohexane to KA oil, which is a mixture of cyclohexanone and cyclohexanol, and is followed by vapor-phase catalytic dehydrogenation of the cyclohexanol in the mixture. Overall yields range from 75% at 10% cyclohexane conversion to 80% at 5% cyclohexane conversion. [Pg.429]

Cyclohexanone [108-94-17 is a colorless, mobile Hquid with an odor suggestive of peppermint and acetone. Cyclohexanone is used chiefly as a chemical iatermediate and as a solvent for resias, lacquers, dyes, and iasecticides. Cyclohexanone was first prepared by the dry distillation of calcium pimelate [19455-79-9] OOC(CH2 )5COO Ca , and later by Bouveault by the catalytic dehydrogenation of cyclohexanol. [Pg.425]

The synthesis of indazoles from their 4,5,6,7-tetrahydroderivatives (439) by means of sulfur or, better, by catalytic dehydrogenation over palladium on charcoal (67HC(22)l) can also be included here. [Pg.260]

Catalytic dehydrogenation of cumene, obtained by alkylation of benzene with propylene, will give a-methylstyrene (Figure 16.15). [Pg.453]

Spath and Lederer have published a simplified synthesis of harmaline consisting in treating the acetyl derivative of 6-methoxytryptamine (XXIX) with phosphorus pentoxide in boiling xylene, the harmaline thus produced being converted into harmine by catalytic dehydrogenation at 200°. [Pg.495]

Catalytic dehydrogenation using palladium/maleic acid has been used to convert tetrahydro-j8-earbolines of general structure 142 into the dihydro-jS Carbolinium salts (143) A similar transformation has been carried out by oxidation with iodine. ... [Pg.116]

Butadiene is obtained mainly as a coproduct with other light olefins from steam cracking units for ethylene production. Other sources of butadiene are the catalytic dehydrogenation of butanes and butenes, and dehydration of 1,4-butanediol. Butadiene is a colorless gas with a mild aromatic odor. Its specific gravity is 0.6211 at 20°C and its boiling temperature is -4.4°C. The U.S. production of butadiene reached 4.1 billion pounds in 1997 and it was the 36th highest-volume chemical. ... [Pg.37]

Butadiene could also be produced by the catalytic dehydrogenation of butanes or a butane/butene mixture. [Pg.103]

The catalytic dehydrogenation of propane is a selective reaction that produces mainly propene ... [Pg.172]

In the Monsanto/Lummus Crest process (Figure 10-3), fresh ethylbenzene with recycled unconverted ethylbenzene are mixed with superheated steam. The steam acts as a heating medium and as a diluent. The endothermic reaction is carried out in multiple radial bed reactors filled with proprietary catalysts. Radial beds minimize pressure drops across the reactor. A simulation and optimization of styrene plant based on the Lummus Monsanto process has been done by Sundaram et al. Yields could be predicted, and with the help of an optimizer, the best operating conditions can be found. Figure 10-4 shows the effect of steam-to-EB ratio, temperature, and pressure on the equilibrium conversion of ethylbenzene. Alternative routes for producing styrene have been sought. One approach is to dimerize butadiene to 4-vinyl-1-cyclohexene, followed by catalytic dehydrogenation to styrene ... [Pg.267]

Problem 16.21 Styrene, the simplest alkenylbenzene, is prepared commercially for use in plastics manufacture by catalytic dehydrogenation of ethylbenzene. How might you prepare styrene from benzene using reactions you ve studied ... [Pg.579]

The Nature of Active Centres and tbe Kinetics of Catalytic Dehydrogenation A. A. Balandin... [Pg.424]

Not only the linear Cl0-Cl8 a-olefins but also the linear C10-Cl8 olefins with internal double bonds, the so-called -v /-olefins, are of great importance in surfactant chemistry, n-a-Olefins and n-y-olefins have the same suitability for the manufacture of linear alkylbenzenes, the most important synthetic anionic surfactants, by alkylation of benzene. Nowadays medium molecular weight n- /-olefins are industrially produced by two processes the catalytic dehydrogenation of the corresponding n-alkanes [4,28] and the cometathesis of low and high molecular weight n-v /-olefins, obtained by double-bond isomerization of the isomeric n-a-olefins [29]. [Pg.17]

By catalytic dehydrogenation of suitable n-paraffin cuts, important /z-olefms are obtained for the synthesis of surfactants. The process is known as the Pacol process. The UOP developed process embraces the following process steps, which are described in more detail in this chapter (Fig. 9) ... [Pg.55]

The LAB production process (process 1) is mainly developed and licensed by UOP. The N-paraffins are partially converted to internal /z-olefins by a catalytic dehydrogenation. The resulting mixture of /z-paraffins and n-olefins is selectively hydrogenated to reduce diolefins and then fed into an alkylation reactor, together with an excess benzene and with concentrated hydrofluoric acid (HF) which acts as the catalyst in a Friedel-Crafts reaction. In successive sections of the plant the HF, benzene, and unconverted /z-paraffins are recovered and recycled to the previous reaction stages. In the final stage of distillation, the LAB is separated from the heavy alkylates. [Pg.671]


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