Pollution sources secondary pollutants

Primary pollutants are released directly into the atmosphere from a given source. Secondary pollutants are formed by chemical reactions occurring in the atmosphere. 

Air pollution can be considered to have three components sources, transport and transformations in the atmosphere, and receptors. The source emits airborne substances that, when released, are transported through the atmosphere. Some of the substances interact with sunlight or chemical species in the atmosphere and are transformed. Pollutants that are emitted directiy to the atmosphere are called primary pollutants pollutants that are formed in the atmosphere as a result of transformations are called secondary pollutants. The reactants that undergo transformation are referred to as precursors. An example of a secondary pollutant is O, and its precursors are NMHC and nitrogen oxides, NO, a combination of nitric oxide [10102-43-9] NO, and NO2. The receptor is the person, animal, plant, material, or ecosystem affected by the emissions. 

Examination of equation 5 shows that if there are no chemical reactions, (R = 0), or if R is linear in and uncoupled, then a set of linear, uncoupled differential equations are formed for determining poUutant concentrations. This is the basis of transport models which may be transport only or transport with linear chemistry. Transport models are suitable for studying the effects of sources of CO and primary particulates on air quaUty, but not for studying reactive pollutants such as O, NO2, HNO, and secondary organic species. 

There are two different types of air pollution problems in urban areas. One is the release of primary pollutants (those released directly from sources). The other is the formation of secondary pollutants (those that are formed through chemical reactions of the primary pollutants). 

Combustion processes are the most important source of air pollutants. Normal products of complete combustion of fossil fuel, e.g. coal, oil or natural gas, are carbon dioxide, water vapour and nitrogen. However, traces of sulphur and incomplete combustion result in emissions of carbon monoxide, sulphur oxides, oxides of nitrogen, unburned hydrocarbons and particulates. These are primary pollutants . Some may take part in reactions in the atmosphere producing secondary pollutants , e.g. photochemical smogs and acid mists. Escaping gas, or vapour, may... 

Nitrogen Dioxide (NO2) Is a major pollutant originating from natural and man-made sources. It has been estimated that a total of about 150 million tons of NOx are emitted to the atmosphere each year, of which about 50% results from man-made sources (21). In urban areas, man-made emissions dominate, producing elevated ambient levels. Worldwide, fossil-fuel combustion accounts for about 75% of man-made NOx emissions, which Is divided equally between stationary sources, such as power plants, and mobile sources. These high temperature combustion processes emit the primary pollutant nitric oxide (NO), which Is subsequently transformed to the secondary pollutant NO2 through photochemical oxidation. 

Table 1 indicates primary pollutant sources and waste modes, and Table 2 indicates the primary and secondary sources and associated pollutants. The primary sources of soil contamination include land disposal of solid waste sludge and waste-water industrial activities and leakages and spills, primarily of petroleum products. The solid waste disposal sites include dumps, landfills, sanitary landfills, and secured landfills. 

These gases are also classed as primary pollutants because they are emitted directly from the source and then react to produce secondary pollutant, such as acid rain (Speight, 1993). The emissions may include a number of biologically active substances that can pose a major health concern. These gases are classed as pollutants because (1) they may not be indigenous to the location or (2) they are ejected into the atmosphere in a greater-than-natural concentration and are, in the current context, the product of human activity. Thus, they can have a detrimental effect on the environment in part or in toto. 

The photochemical oxidants that are observed in the atmosphere are ozone, Oj, nitrogen dioxide, NOj and peroxyacetylnitrate (PAN). Several other substances, such as hydrogen peroxide, HjO, may be classified as photochemical oxidants, but their common presence in smog is not well established. The oxidants are secondary pollutants i.e., they are formed as a result of chemical reactions in the atmosphere. Primary pollutants are those emitted directly by pollution sources. 

The nickel—zinc (NiZn) system is attractive as a secondary cell because of its high energy density and low material cost and the low level of potential pollutants contained. The widespread use of nickel-zinc batteries, particularly as electric vehicle power sources, would be strongly enhanced by significantly extending the deep-discharge cycle life beyond the current level of 100—300 cycles. Considerable work has been done in the past to develop a suitable separator for nickel— and silver—zinc batteries. 272 An excellent discussion of separator development is contained in a comprehensive review. 2 ... 

Plant 000012 produces 3.9 x 10" kkg/year (8.7 x lO lb/year) of emulsion crumb rubber, primarily neoprene. The contact wastewater flow rate is approximately 8.45 m /day (2.25 X 10 gpd) and includes all air pollution control equipment, sanitary waste, maintenance and equipment cleanup, and direct contact wastewater. The treatment process consists of activated sludge, secondary clarification, sludge thickening, and aerobic sludge digestion. Noncontact wastewater, with a flow rate of approximately 1.31 x 10 m /day (3.46 x 10 gpd), is used on a once-through basis and is remrned directly to the river source. Contact wastewater is also returned to the surface stream after treatment. 

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