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Waste plutonium

All plutonium produced must be prevented from spreading into the environment. It is presently believed that the safest way is to store plutonium waste in deep underground facilities, and several such are now being constructed (8, 9, 12, 13). In the future, however, releases of various sizes must be anticipated, considering the large amounts of plutonium being handled. The hazards associated with such releases must be reliably assessed. [Pg.276]

Half-lives span a very wide range (Table 17.5). Consider strontium-90, for which the half-life is 28 a. This nuclide is present in nuclear fallout, the fine dust that settles from clouds of airborne particles after the explosion of a nuclear bomb, and may also be present in the accidental release of radioactive materials into the air. Because it is chemically very similar to calcium, strontium may accompany that element through the environment and become incorporated into bones once there, it continues to emit radiation for many years. About 10 half-lives (for strontium-90, 280 a) must pass before the activity of a sample has fallen to 1/1000 of its initial value. Iodine-131, which was released in the accidental fire at the Chernobyl nuclear power plant, has a half-life of only 8.05 d, but it accumulates in the thyroid gland. Several cases of thyroid cancer have been linked to iodine-131 exposure from the accident. Plutonium-239 has a half-life of 24 ka (24000 years). Consequently, very long term storage facilities are required for plutonium waste, and land contaminated with plutonium cannot be inhabited again for thousands of years without expensive remediation efforts. [Pg.832]

Knoll (40) in a study similar to that of Rhodes (33) demonstrated that percolation of organic acids through the soil did not influence the exchange characteristics of soil with respect to plutonium waste. However, hydroxyacetic acid removed 50% of the plutonium from soil and in the case of americium this value was raised to 100%. [Pg.56]

Gong, W. L., Lutze, W. Ewing, R. C. 2000. Zirco-nia ceramics for excess weapons plutonium waste. Journal of Nuclear Materials, 277, 239-249. [Pg.22]

Plutonium-contaminated waste, principally from weapons materials processing. There are two classes of plutonium wastes the transuranic, containing mostly plutonium and other transuranics, and the high-level wastes that contain significant heat-generating products, strontium, and cesium. [Pg.975]

The transport of plutonium wastes to the transuranic and high-level repositories will represent a major increase in the quantities of radioactive materials shipped therefore an extensive demographic study has been made to examine potential exposures of the public and to select routes to minimize such exposure.45,46... [Pg.981]

Composite materials are mechanical dispersions of radioactive solids, for instance ciystalline or vitreous radioactive phases in metal matrix [24], glass-encapsulated Ca-phosphate based ceramics [30] glass-bonded sodalite [31,32] glass-ceramics for plutonium waste immobilization [33] and so on. [Pg.464]

Plutonium wastes from the Los Alamos National Laboratory in northern New Mexico were trucked for the first time to the federal Waste Isolation Pilot Plant in Carlsbad in March 1999. The 600 pounds (270 kg) of waste consisted of plntonium-contaminated clothing and metal cans, packed in boxes and stainless steel containers. Most of the material was from the laboratory s mannfiicture of nuclear batteries used in NASAs deep space probes and will be buried in the depository carved out of ancient salt caverns about half a mile (0.8 km) below ground. [Pg.1030]

In addition, TOPO has the advantage of being able to sorb the hydrolytic plutonium polymer, which is a common component of plutonium waste streams, whereas anion exchange resins cannot do so [72]. Fortunately, American Cyanamid has introduced a low-cost alternative to TOPO, which also extracts plutonium polymer from nitric acid [73]. This material, called Cyanex 923, is a mixture of trialkyIphosphine oxides, and its low cost makes this approach for the recovery of plutonium more realistic. [Pg.240]

J. E. CUNE, A Relatively Simple and Precise Technique for the Assay of Plutonium Waste, ANCR-1055, p. 2 (February 1972). [Pg.387]

Plutonium (Pu) is an artificial element of atomic number 94 that has its main radioactive isotopes at 2 °Pu and Pu. The major sources of this element arise from the manufacture and detonation of nuclear weapons and from nuclear reactors. The fallout from detonations and discharges of nuclear waste are the major sources of plutonium contamination of the environment, where it is trapped in soils and plant or animal life. Since the contamination levels are generally very low, a sensitive technique is needed to estimate its concentration. However, not only the total amount can be estimated. Measurement of the isotope ratio provides information about its likely... [Pg.369]

Thorium, uranium, and plutonium are well known for their role as the basic fuels (or sources of fuel) for the release of nuclear energy (5). The importance of the remainder of the actinide group Hes at present, for the most part, in the realm of pure research, but a number of practical appHcations are also known (6). The actinides present a storage-life problem in nuclear waste disposal and consideration is being given to separation methods for their recovery prior to disposal (see Waste treati nt, hazardous waste Nuclear reactors, waste managet nt). [Pg.212]

The wastes from uranium and plutonium processing of the reactor fuel usually contain the neptunium. Precipitation, solvent extraction, ion exchange, and volatihty procedures (see Diffusion separation methods) can be used to isolate and purify the neptunium. [Pg.213]

Neutron-rich lanthanide isotopes occur in the fission of uranium or plutonium and ate separated during the reprocessing of nuclear fuel wastes (see Nuclearreactors). Lanthanide isotopes can be produced by neutron bombardment, by radioactive decay of neighboring atoms, and by nuclear reactions in accelerators where the rate earths ate bombarded with charged particles. The rare-earth content of solid samples can be determined by neutron... [Pg.541]

Nuclear wastes are classified according to the level of radioactivity. Low level wastes (LLW) from reactors arise primarily from the cooling water, either because of leakage from fuel or activation of impurities by neutron absorption. Most LLW will be disposed of in near-surface faciHties at various locations around the United States. Mixed wastes are those having both a ha2ardous and a radioactive component. Transuranic (TRU) waste containing plutonium comes from chemical processes related to nuclear weapons production. These are to be placed in underground salt deposits in New Mexico (see... [Pg.181]

Historically, ferrous sulfamate, Fe(NH2S02)2, was added to the HNO scmbbing solution in sufficient excess to ensure the destmction of nitrite ions and the resulting reduction of the Pu to the less extractable Pu . However, the sulfate ion is undesirable because sulfate complexes with the plutonium to compHcate the subsequent plutonium purification step, adds to corrosion problems, and as SO2 is an off-gas pollutant during any subsequent high temperature waste solidification operations. The associated ferric ion contributes significantly to the solidified waste volume. [Pg.205]

Plutonium Purification. The aqueous feed for the second plutonium cycle is typically prepared by adding HNO and an excess of sodium nitrite, NaN02, to destroy the excess reductant and oxidize the Pu to the more extractable Pu . An alternative approach which reduces the amount of salt in the Hquid waste involves absorbing nitrogen tetroxide, N2O4, as a substitute for the NaN02 ... [Pg.206]

By-Products. The PUREX process is efficient at separating uranium and plutonium from everything else in the spent fuel. Within the high level waste stream are a number of components which have, from time to time, been sufficiendy interesting to warrant their recovery. The decision to recover a particular isotope is usually based on a combination of market incentives and desired waste reduction. [Pg.206]

Chemical processing or reprocessing (39) of the fuel to extract the plutonium and uranium left a residue of radioactive waste, which was stored in underground tanks. By 1945, the reactors had produced enough plutonium for two nuclear weapons. One was tested at Alamogordo, New Mexico, in July 1945 the other was dropped at Nagasaki in August 1945. [Pg.212]

The Natural Reactor. Some two biUion years ago, uranium had a much higher (ca 3%) fraction of U than that of modem times (0.7%). There is a difference in half-hves of the two principal uranium isotopes, U having a half-life of 7.08 x 10 yr and U 4.43 x 10 yr. A natural reactor existed, long before the dinosaurs were extinct and before humans appeared on the earth, in the African state of Gabon, near Oklo. Conditions were favorable for a neutron chain reaction involving only uranium and water. Evidence that this process continued intermittently over thousands of years is provided by concentration measurements of fission products and plutonium isotopes. Usehil information about retention or migration of radioactive wastes can be gleaned from studies of this natural reactor and its products (12). [Pg.222]

Weapons materials from production reactors were accumulated during the Cold War period as a part of the U.S. defense program. Prominent were tritium, ie, hydrogen-3, having a of 12.3 yr, and plutonium-239, 1/2 = 2.4 X lO" yr. The latter constitutes a waste both as a by-product of weapons fabrication in a waste material called transuranic waste (TRU), and as an excess fissionable material if not used for power production in a reactor. [Pg.228]

The geologic aspects of waste disposal (24—26), proceedings of an annual conference on high level waste management (27), and one from an annual conference on all types of radioactive waste (28) are available. An alternative to burial is to store the spent fuel against a long-term future energy demand. Uranium and plutonium contained in the fuel would be readily extracted as needed. [Pg.230]

Transuranic Waste. Transuranic wastes (TRU) contain significant amounts (>3,700 Bq/g (100 nCi/g)) of plutonium. These wastes have accumulated from nuclear weapons production at sites such as Rocky Flats, Colorado. Experimental test of TRU disposal is planned for the Waste Isolation Pilot Plant (WIPP) site near Carlsbad, New Mexico. The geologic medium is rock salt, which has the abiUty to flow under pressure around waste containers, thus sealing them from water. Studies center on the stabiUty of stmctures and effects of small amounts of water within the repository. [Pg.232]

The primary issue is to prevent groundwater from becoming radioactively contaminated. Thus, the property of concern of the long-lived radioactive species is their solubility in water. The long-lived actinides such as plutonium are metallic and insoluble even if water were to penetrate into the repository. Certain fission-product isotopes such as iodine-129 and technicium-99 are soluble, however, and therefore represent the principal although very low level hazard. Studies of Yucca Mountain, Nevada, tentatively chosen as the site for the spent fuel and high level waste repository, are underway (44). [Pg.242]

The plutonium extracted by the Purex process usually has been in the form of a concentrated nitrate solution or symp, which must be converted to anhydrous PuF [13842-83-6] or PuF, which are charge materials for metal production. The nitrate solution is sufficientiy pure for the processing to be conducted in gloveboxes without P- or y-shielding (130). The Pu is first precipitated as plutonium(IV) peroxide [12412-68-9], plutonium(Ill) oxalate [56609-10-0], plutonium(IV) oxalate [13278-81-4], or plutonium(Ill) fluoride. These precipitates are converted to anhydrous PuF or PuF. The precipitation process used depends on numerous factors, eg, derived purity of product, safety considerations, ease of recovering wastes, and required process equipment. The peroxide precipitation yields the purest product and generally is the preferred route (131). The peroxide precipitate is converted to PuF by HF—O2 gas or to PuF by HF—H2 gas (31,132). [Pg.201]

Nuclear Waste Reprocessing. Liquid waste remaining from processing of spent reactor fuel for military plutonium production is typically acidic and contains substantial transuranic residues. The cleanup of such waste in 1996 is a higher priority than military plutonium processing. Cleanup requires removal of long-Hved actinides from nitric or hydrochloric acid solutions. The transuranium extraction (Tmex) process has been developed for... [Pg.201]


See other pages where Waste plutonium is mentioned: [Pg.964]    [Pg.65]    [Pg.352]    [Pg.12]    [Pg.703]    [Pg.1264]    [Pg.964]    [Pg.65]    [Pg.352]    [Pg.12]    [Pg.703]    [Pg.1264]    [Pg.199]    [Pg.201]    [Pg.202]    [Pg.202]    [Pg.202]    [Pg.205]    [Pg.229]    [Pg.229]    [Pg.229]    [Pg.241]    [Pg.242]    [Pg.201]    [Pg.202]    [Pg.439]   
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