Plutonium process

The wastes from uranium and plutonium processing of the reactor fuel usually contain the neptunium. Precipitation, solvent extraction, ion exchange, and volatihty procedures (see Diffusion separation methods) can be used to isolate and purify the neptunium. 

Nuclear Waste Reprocessing. Liquid waste remaining from processing of spent reactor fuel for military plutonium production is typically acidic and contains substantial transuranic residues. The cleanup of such waste in 1996 is a higher priority than military plutonium processing. Cleanup requires removal of long-Hved actinides from nitric or hydrochloric acid solutions. The transuranium extraction (Tmex) process has been developed for... 

J. A. Leary and L. J. Mullins, Practical Applications of Thermodynamics to Plutonium Process Reactions at High Temperature, Vol. 1, Thermodynamics, STl/PUB/162, IAEA, Vienna, 1967, pp. 459-471. 

Present Status and Future Directions of Plutonium Process Chemistry... 

An overview is given of plutonium process chemistry used at the U. S. Department of Energy Hanford, Los Alamos National Laboratory, Rocky Flats, and Savannah River sites, with particular emphasis on solution chemistry involved in recovery, purification, and waste treatment operations. By extrapolating from the present system of processes, this paper also attempts to chart the future direction of plutonium process development and operation. Areas where a better understanding of basic plutonium chemistry will contribute to development of improved processing are indicated. 

Figure 3 shows a flowsheet for plutonium processing at Rocky Flats. Impure plutonium metal is sent through a molten salt extraction (MSE) process to remove americium. The purified plutonium metal is sent to the foundry. Plutonium metal that does not meet foundry requirements is processed further, either through an aqueous or electrorefining process. The waste chloride salt from MSE is dissolved then the actinides are precipitated with carbonate and redissolved in 7f1 HN03 and finally, the plutonium is recovered by an anion exchange process. 

Waste Handling for Unirradiated Plutonium Processing. Higher capacity, better-performing, and more radiation-resistant separation materials such as new ion exchange resins(21) and solvent extractants, similar to dihexyl-N,N-di ethyl carbamoyl methylphosphonate,(22) are needed to selectively recover actinides from acidic wastes. The application of membranes and other new techniques should be explored. 

Christensen, E. L. Maraman, W. J. Plutonium Processing at the Los Alamos Scientific Laboratory, U.S. AEC Report LA-3542, Los Alamos Scientific Laboratory, Los Alamos, N.M., April 1969. 

An overview is presented of plutonium process chemistry at Rocky Flats and of research in progress to improve plutonium processing operations or to develop new processes. Both pyrochemical and aqueous methods are used to process plutonium metal scrap, oxide, and other residues. The pyrochemical processes currently in production include electrorefining, fluorination, hydriding, molten salt extraction, calcination, and reduction operations. Aqueous processing and waste treatment methods involve nitric acid dissolution, ion exchange, solvent extraction, and precipitation techniques. 

The Chemistry Research and Development group has a large variety of plutonium process chemistry projects underway. The work will certainly add to our understanding of plutonium chemistry and will result in plutonium process improvements. 

I am not going to comment on plutonium process chemistry or process R E needs since I had done all that in my paper on Tuesday. 

Am-Cm Recovery from Plutonium Process Waste. Trans. Amer. Nucl. Soc. 

Hanford, Washington, 1973, plutonium processing waste pond ... 

WATER, VARIOUS LOCATIONS Hanford, Washington plutonium processing waste ponds ... 

AQUATIC PLANTS Algae, decomposing Hanford, Washington, 1973 plutonium processing pond 241 Am 9472 DW 15... 

The fission product and encapsulation plant (FPCE) to be built by Isochem, Inc.y in Washington state will produce fully encapsulated fission products for the commercial market. Among these, all of which are extractable from Hanford s plutonium process residues, is cesium-137, a 600-kv. gamma emitter of interest to the process irradiation industry. Isochem will offer cesium in large production quantities and low cost to irradiators of foods, woods, chemicals, etc. Its 30-year half-life promises economies in source array replenishment to compensate for decay. Cesium thus becomes an economic contender for current and planned irradiation applications. 

In April of 1955, a facility utilizing the Recuplex solvent extraction process(2j was installed in the 234-5Z Building at Hanford. This facility provided the capability of recovering plutonium from unirradiated plutonium scrap from Hanford plutonium processing operations. By 1960, the Recuplex facility was inadequate with respect to contemplated production loads, shielding requirements, and criticality prevention safety. A project was authorized in March 1961 to provide a new facility for the adequate reclamation of plutonium from both wet and dry plutonium scrap generated from both on and offsite operations. This facility, the 236-Z Building, was completed in June 1964 and is referred to as the PRF. Details on the new plant were first published in 1967.(2)... 

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