Pipeline transport

The alternative for hydrogen transport over short or medium distances is pipelines, with the viable distances being determined by ease and cost of establishing pipelines, usually over land but conceivably also in some cases off-shore. Again, the technology is basically already developed for natural gas transport, and only modest alterations are believed to be required in order to contain the smaller hydrogen molecules with acceptable leakage rates. 

Current polymer pipes used for transportation of natural gas at pressures under 0.4 MPa have sufficient strength to carry hydrogen, and diffusion losses arising mainly from pipe connectors have been estimated at three times higher for hydrogen than for natural gas (Sorensen et al, 2001). Transmission of natural gas at pressures up to 8 MPa uses steel pipes with welded connections. Most metals can develop brittleness after absorption of 

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Crude oil and gas from offshore platforms are evacuated by pipeline or alternatively, in the case of oil, by tanker. Pipeline transport is the most common means of evacuating hydrocarbons, particularly where large volumes are concerned. Although a pipeline may seem a fairly basic piece of equipment, failure to design a line for the appropriate capacity, or to withstand operating conditions over the field life time, can prove very costly in terms of deferred oil production. 

In the coal-mining industry, more than 300 mines are operated in three coal-mining regions Ukraine produces only 5 5 million tons of its own oil, but the ramified network of oil pipelines supports the operation of 10 petroleum plants. The Ukrainian gas pipelines transport the Russian gas to Central and Western Europe. 

The reason for the popularity of anhydrous ammonia is its economy. No further processing is needed and it has a very high (82.2%) nitrogen content. Additionally if held under pressure or refrigerated, ammonia is a Hquid. Being a Hquid, pipeline transport is practical and economical. A network of overland pipelines (Fig. 4) is in operation in the United States to move anhydrous ammonia economically from points of production near natural gas sources to points of utilization in farming areas (see Pipelines). 

Shale oil contains large quantities of olefinic hydrocarbons (see Table 8), which cause gumming and constitute an increased hydrogen requirement for upgrading. Properties for cmde shale oil are compared with petroleum cmde in Table 10. High pour points prevent pipeline transportation of the cmde shale oil (see Pipelines). Arsenic and iron can cause catalyst poisoning. 

Pipeline transport involves the appHcation of force to the material being moved, either through the use of pumps to transport Hquids, compressors to move gases, or flowing water to move soHds. In some appHcations, vacuum may create the pressure differential. 

The largest pipeline transport of gas, by far, is the movement of methane (natural gas). Natural gas can be Hquefted, but it is not pipelined in Hquid form because of cost and safety considerations. For overseas transport, it is shipped as Hquefted natural gas (LNG) in insulated tankers, unloaded at special unloading faciHties, vaporized, and then transported over land in pipelines as a gas. 

The appHcation that has led to increased interest in carbon dioxide pipeline transport is enhanced oil recovery (see Petroleum). Carbon dioxide flooding is used to Hberate oil remaining in nearly depleted petroleum formations and transfer it to the gathering system. An early carbon dioxide pipeline carried by-product CO2 96 km from a chemical plant in Louisiana to a field in Arkansas, and two other pipelines have shipped CO2 from Colorado to western Texas since the 1980s. EeasibiHty depends on cmde oil prices. 

The main technical difference between Hquid and gas pipeline transport is the compressibiUty of the fluid being moved and the use of pumps, rather than compressors, to supply the pressure needed for transport. The primary use for Hquids pipelines is the transport of cmde oil and petroleum products. 

Pipelines to transport soHds are called freight pipelines, of which three different types exist pneumatic pipelines, the use of which is known as pneumotransport or pneumatic conveying slurry pipelines, which may also be called hydrotransport or hydrauHc conveying and capsule pipelines. When air or inert gas is used to move the soHds in the pipeline, the system is called a pneumatic pipeline and often involves a wheeled vehicle inside the pipeline, propelled by air moving through the pipe (25). Slurry pipelines involve the transport of soHd particles suspended in water or another inert Hquid. HydrauHc capsule pipelines transport soHd material within cylindrical containers, using water flow through the pipeline for propulsion. 

Data compiled by the U.S. DOT iadicate that pipeline transport is the safest materials transport mode, particularly over long distances. In 1990, fataUties attributed to oil and gas pipelines were significantly lower (8 out of 4679) for all materials transporters ia the United States, compared with 599 for rail transport and 3281 for motor transport (tmcks) (53). 

Ak ammonia piping should be standard (Schedule 40) or extra heavy (Schedule 80) steel having welded or screwed joints, respectively. Galvanized piping or brazed joints should never be used. Ammonia accepted for pipeline transportation must meet the fokowing specifications NH, 99.5 vol % min dissolved inerts, 0.16% max, ok, 5 ppm max and water, in the form of steam condensate, 0.2% min, or distiked water, 0.5% max. 

Pipelines. The feasibility of pipeline transportation depends on the availability of very large quantities of compatible materials between locations with sufficient storage facilities. Thus, pipeline transportation is predominantly, but not exclusively, limited to the movement of hydrocarbons, many of which are raw materials in the production of petrochemicals. Although proprietary pipelines (qv), generally of short distances, ate not unusual, commercial petroleum pipelines are considered to be common carriers available to serve all customers who can tender sufficient quantities of acceptable liquids for transportation between terminals. 

According to Ref. 6, 70 incidents of corrosion damage for 1000 km of buried steel pipeline transporting gas were reported on average each year in Germany. For 1000 km of pipeline on lines operating at pressures up to 4 bar, 100 incidents of... 

The following analysis enables one to calculate the diameter of a pipeline transporting any compressible fluid. The required inputs are volumetric flow rate, the specific gravity of the gas relative to air, flow conditions, compressibility factor Z where Z is defined by nZRT = PV, the pressure at the point of origin and the destination, the pipe length, and pipe constants such as effective roughness. The working equations have been obtained from the literature. Since the friction factor... 

In the United States, pipeline transport is regulated by the Department of TransporUition (DOT) through the Natural Gas Pipeline Safety Act of 1968 and... 

Charles, M. E. and CHARLES, R. A. Paper A12, Advances in Solid-Liquid Flow in Pipes and its Application, Zandi. 1, (ed.), Pergamon Press (1971). The use of heavy media in the pipeline transport of particulate... 

Duckworth, R. A., Pullum, L., Addie, G. R. and Lockyear, C. F. Hydrotransporl 10 (BHRA Fluid Engineering, Innsbruck, Austria) (October 1986). Paper C2. The pipeline transport of coarse materials in a non-Newtonian carrier fluid. 

The most relevant parameters in pipeline transportation of heavy crude oil are velocity, viscosity, temperature, density, and pour point [691]. Heavy crude... 

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