Permitted pollution

Federal regulations (40 CFR 261) classify acrylonitrile as a hazardous waste and it is Hsted as Hazardous Waste Number U009. Disposal must be in accordance with federal (40 CFR 262, 263, 264), state, and local regulations only at properly permitted faciUties. It is Hsted as a toxic pollutant (40 CFR 122.21) and introduction into process streams, storm water, or waste water systems is in violation of federal law. Strict guidelines exist for clean-up and notification of leaks and spills. Federal notification regulations require that spills or leaks in excess of 100 lb (45.5 kg) be reported to the National Response Center. Substantial criminal and civil penalties can result from failure to report such discharges into the environment. 

The most common method of converting iron ore to metallic iron utilizes a blast furnace wherein the material is melted to form hot metal (pig iron). Approximately 96% of the world s iron is produced this way (see Iron). However, in the blast furnace process energy costs are relatively high, pollution problems of associated equipment are quite severe, and capital investment requirements are often prohibitively expensive. In comparison to the blast furnace method, direct reduction permits a wider choice of fuels, is environmentally clean, and requires a much lower capital investment. 

Nickel Carbonyl The extremely toxic gas nickel carbonyl can be detected at 0.01 ppb by measuring its chemiluminescent reaction with ozone in the presence of carbon monoxide. The reaction produces excited nickel(II) oxide by a chain process which generates many photons from each pollutant molecule to permit high sensitivity (315). 

Tide V of the Clean Air Act Amendments of 1990 covers federally approved state operating permits for manufacturing faciUties. One requirement of this regulation is that manufacturers must report emissions information of identified ha2ardous air pollutants specific to thein operation from a list of 189 named in the Clean Air Act Amendments. Rubber and tine manufacturers had to meet this requirement by the end of 1995. The Rubber Manufacturers Association has begun an industrywide project to develop accurate and reliable emissions data to aid manufacturers to comply with these requinements (44). 

The National Pollutant Discharge Elimination System (NPDES) is a cornerstone of the federal efforts to control water pollution (21). It determines what can be discharged to a pubHcly owned treatment plant. Indirect discharges may not be required to obtain an NPDES permit but must meet pretreatment effluent limitations and conditions of the NPDES permit of the treatment plant caimot be exceeded. 

From the standpoint of collector design and performance, the most important size-related property of a dust particfe is its dynamic behavior. Particles larger than 100 [Lm are readily collectible by simple inertial or gravitational methods. For particles under 100 Im, the range of principal difficulty in dust collection, the resistance to motion in a gas is viscous (see Sec. 6, Thud and Particle Mechanics ), and for such particles, the most useful size specification is commonly the Stokes settling diameter, which is the diameter of the spherical particle of the same density that has the same terminal velocity in viscous flow as the particle in question. It is yet more convenient in many circumstances to use the aerodynamic diameter, which is the diameter of the particle of unit density (1 g/cm ) that has the same terminal settling velocity. Use of the aerodynamic diameter permits direct comparisons of the dynamic behavior of particles that are actually of different sizes, shapes, and densities [Raabe, J. Air Pollut. Control As.soc., 26, 856 (1976)]. 

Sources Subject to Prevention of Significant Deterioration (PSD) Sources subject to PSD regulations (40 CFR, Sec. 52.21, Aug. 7, 1980) are major stationary sources and major modifications located in attainment areas and unclassified areas. A major stationaiy source was defined as any source hsted in Table 25-4 with the potential to emit 100 tons per year or more of any pollutant regulated under the Clean Air Act (CAA) or any other source with the potential to emit 250 tons per year or more of any CAA pollutant. The potential to emit is defined as the maximum capacity to emit the pollutant under apphcable emission standards and permit conditions (after apphcation of any air pollution control equipment) excluding secondaiy emissions. A major modification is defined as any physical or operational change of a major stationaiy source producing a significant net emissions increase of any CAA pollutant (see Table 25-5). 

Initially, all major sources of air pollution are required to obtain an operating permit. However, any state permitting authority may extend the apphcability of the operating permit to minor sources as... 

Recychng (or reuse) refers to the use (or reuse) of materials that would otherwise be disposed of or treated as a waste product. A good example is a rechargeable battery. Wastes that cannot be directly reused may often be recovered on-site through methods such as distillation. When on-site recoveiy or reuse is not feasible due to quality specifications or the inability to perform recoveiy on-site, off-site recoveiy at a permitted commerci recoveiy facihty is often a possibility. Such management techniqiies are considered secondaiy to source reduc tion and should only oe used when pollution cannot be prevented. 

Adsorption-Control Equipment If a gas stream must be treated for a short period, nsnally only one adsorption unit is necessary, provided, of course, that a sufficient time interval is available between adsorption cycles to permit regeneration. However, this is usually not the case. Since an nninternipted flow of treated gas is often required, it is necessary to employ one or more units capable of operating in this fashion. The units are designed to handle gas flows without interruption and are charac terized by their mode of contact, either staged or continuous. By far the most common type of adsorption system used to remove an objectionable pollutant from a gas stream consists of a number of fixed-bed units operating in such a sequence that the gas flow remains nninternipted. A two- or three-bed system is nsn ly... 

The process of evaluating air emission permit apphcations for large sources which are subject to federal permitting requirements is called New Source Review (NSR) and can be quite complicated, taking from six mouths to four years to complete. An NSR application would be required for a new source which could emit 100 tons per year or more of any criteria pollutant, after accounting for any air pollution control equipment. 

The permitting reqiiirements and procedures for a proposed NSR source are quite different, if the source is to be located in a nonattaiu-ment area for any of its major emitted pollutants, than if it is to be located in an attainment area. This usually increases the complexity of the permit application for such a source. 

Federal Permitting in Nonattainment Areas If the source sub-jec t to NSR is to be located in an area which is nonattaiumeut for any of the major pollutants that the source will emit, it will need to follow the federally approved state permitting requirements for nonattain-ment areas of that pollutant. In most such cases, offsetting emission reductions at the same or other source locations in the area so as to be at least equivalent to the allowed emission, increases at the proposed source must be provided. 

---